<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singh, Shivangi</style></author><author><style face="normal" font="default" size="100%">Marayathungal, Jumana Hasin</style></author><author><style face="normal" font="default" size="100%">Das, Deep Kumar</style></author><author><style face="normal" font="default" size="100%">Khan, Akram Aadil</style></author><author><style face="normal" font="default" size="100%">Bakthavatsalam, Rangarajan</style></author><author><style face="normal" font="default" size="100%">Hathwar, Venkatesha R.</style></author><author><style face="normal" font="default" size="100%">Kundu, Janardan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Rational design of zero-dimensional manganese(II) halide hybrids with suppressed melting temperatures</style></title><secondary-title><style face="normal" font="default" size="100%">JOURNAL OF PHYSICAL CHEMISTRY C</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">ORGANIC-INORGANIC PEROVSKITES</style></keyword><keyword><style  face="normal" font="default" size="100%">TRANSITION</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">128</style></volume><pages><style face="normal" font="default" size="100%">14849-14859</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">35</style></issue><work-type><style face="normal" font="default" size="100%">Journal Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;3.7&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kumar Das, Deep</style></author><author><style face="normal" font="default" size="100%">Marayathungal, Jumana Hasin</style></author><author><style face="normal" font="default" size="100%">Palakkolil, Athira</style></author><author><style face="normal" font="default" size="100%">Sarma, Dhritismita</style></author><author><style face="normal" font="default" size="100%">Khan, Akram Aadil</style></author><author><style face="normal" font="default" size="100%">Kumar, M. Praveen</style></author><author><style face="normal" font="default" size="100%">Kudlu, Ashwath</style></author><author><style face="normal" font="default" size="100%">Choudhary, Mahendra</style></author><author><style face="normal" font="default" size="100%">Hathwar, Venkatesha R.</style></author><author><style face="normal" font="default" size="100%">Pujala, Ravi Kumar</style></author><author><style face="normal" font="default" size="100%">Mahata, Arup</style></author><author><style face="normal" font="default" size="100%">Kundu, Janardan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Supercooled liquid phases of luminescent zero dimensional metal halide hybrids</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Physical Chemistry Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">16</style></volume><pages><style face="normal" font="default" size="100%">9391-9400</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Chemical design of metal halide hybrids (MHHs) with suppressed melting point (T-m) allows access to glassy phases from their liquid-melts. Thermal phase change (crystal-melt-glass) properties of glassy MHHs (with glass transition temperature T-g &amp;gt; room temperature) have been exploited for device applications. However, room temperature stable supercooled liquid (SCL) MHHs (with T-g &amp;lt; room temperature), originating from glass-SCL phase change, remain inaccessible. Here, a molecular design strategy is reported to access ambient stable, melt-processable, SCL multimetallic bromide hybrids (Mn2+,Cd2+; Mn2+,Zn2+; Benzyltributylammonium) with low T-g (15-16 degrees C), low T-m (90-100 degrees C), green luminescence, and high optical transparency. Structural, optical, thermal, and computational analyses highlight chemical design principles and support dopant (Mn2+) based luminescence. Rheological measurements confirm the SCL phase that shows thermal hysteresis and estimate relaxation time scales. This work provides a new material platform showcasing enhanced melt-processability for fabrication of moldable devices, unravelling chemical makeup-property correlation and expanding the material phase types of MHHs.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">36</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	5.1&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kumar Das, Deep</style></author><author><style face="normal" font="default" size="100%">Sarma, Dhritismita</style></author><author><style face="normal" font="default" size="100%">Kumar, M. Praveen</style></author><author><style face="normal" font="default" size="100%">Khan, Akram Aadil</style></author><author><style face="normal" font="default" size="100%">Madhusoodhananan, Mahesh</style></author><author><style face="normal" font="default" size="100%">Kudlu, Ashwath</style></author><author><style face="normal" font="default" size="100%">Ajithkumar, Thalasseril Govindankuttykaimal</style></author><author><style face="normal" font="default" size="100%">Pujala, Ravi Kumar</style></author><author><style face="normal" font="default" size="100%">Mahata, Arup</style></author><author><style face="normal" font="default" size="100%">Kundu, Janardan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bright dual-phase organic luminescence from zero-dimensional lead halide hybrids via sensitized thermally activated delayed fluorescence for multifunctional applications</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry of Materials</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">38</style></volume><pages><style face="normal" font="default" size="100%">4668-4681</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Metal halide hybrids have long celebrated their halometallate moieties as the luminescent center, leaving organic cations behind. Although the thermally activated delayed fluorescence (TADF) strategy has enabled efficient solid-state organic emitters, the complex molecular design required for TADF emitters has limited their facile integration into metal halide hybrid architectures. Here, we demonstrate a versatile strategy wherein a nonemissive organic moiety (benzyltributylammonium) is incorporated into a zero-dimensional disphenoidal Pb-halide hybrid, [(C19H34N)2PbCl4], resulting in efficient TADF-based dual-phase organic emission sensitized by halometallate units in the solid state (crystalline; amorphous). These materials exhibit strong PLQY (similar to 85%) and tunable organic luminescence (blue emission in crystalline phase; cyan emission in amorphous phase) modulated by the packing extent of organic moiety. [PbX4]2- units act as absorptive centers that sensitize organic cations showing TADF-based strong emission. Ground and excited state density functional theory calculations reveal the unique origin of sensitized TADF organic luminescence. Rheological measurements characterize relaxation dynamics of glass &amp;lt;-&amp;gt; supercooled liquid transitions, establishing correlations between molecular packing, phase, and emission characteristics. This first demonstration of dual-phase, sensitized TADF-based organic luminescence in lead halide hybrids establishes a new design paradigm that bridges molecular and solid-state photophysics, opening avenues for multifunctional applications in LEDs, optical thermometry, and security technologies.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">9</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	7.5&lt;/p&gt;
</style></custom4></record></records></xml>