<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Shabade, Anand B.</style></author><author><style face="normal" font="default" size="100%">Singh, Rahul K.</style></author><author><style face="normal" font="default" size="100%">Gonnade, Rajesh G.</style></author><author><style face="normal" font="default" size="100%">Punji, Benudhar</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Manganese-catalyzed chemoselective direct hydrogenation of α,β-epoxy ketones and α-ketoamides at room temperature</style></title><secondary-title><style face="normal" font="default" size="100%">Advanced Synthesis &amp; Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">alpha</style></keyword><keyword><style  face="normal" font="default" size="100%">beta-epoxy ketones</style></keyword><keyword><style  face="normal" font="default" size="100%">chemoselectivity</style></keyword><keyword><style  face="normal" font="default" size="100%">direct hydrogenation</style></keyword><keyword><style  face="normal" font="default" size="100%">manganese</style></keyword><keyword><style  face="normal" font="default" size="100%">Metal-ligand cooperation</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">366</style></volume><pages><style face="normal" font="default" size="100%">3338-3345</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Chemoselective hydrogenation of alpha,beta-epoxy ketones and alpha-ketoamides is achieved at room temperature (25 degrees C) using 2.0 bar H-2 and a pincer-ligated Mn(I) catalyst that provides synthetically valuable alpha-hydroxy epoxides and alpha-hydroxy amides. This protocol applies to a wide range of alkyl- and aryl-substituted alpha,beta-epoxy ketones, including terpenes (alpha-ionone, nootkatone, and R-carvone)- and steroids (testosterone and progesterone)-derived epoxy ketones, and tolerates H-2 sensitive functionalities, such as halides, acetyl, nitrile, nitro, epoxide, alkenyl and alkynyl groups. Additionally, alpha-ketoamides bearing reducible functional groups, including acetyl and diazo benzene, were untouched under this protocol and selectively converted to alpha-hydroxy amides. A preliminary mechanistic study highlighted the metal-ligand cooperative H-2 activation process.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">15</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
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	5.4&lt;/p&gt;
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