<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kirdant, Swapnali P. P.</style></author><author><style face="normal" font="default" size="100%">Bankar, Shubham R. R.</style></author><author><style face="normal" font="default" size="100%">Jadhav, Vrushali H. H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Efficient synthesis of a monomer for bioplastic-FDCA using glucose-HTC catalyst and pinnick oxidation from HMF &amp; fructose</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Letters</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">2</style></keyword><keyword><style  face="normal" font="default" size="100%">5-Diformyl furan (DFF)</style></keyword><keyword><style  face="normal" font="default" size="100%">5-Furandicarboxylic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Biomass</style></keyword><keyword><style  face="normal" font="default" size="100%">D-fructose</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">154</style></volume><pages><style face="normal" font="default" size="100%">718-724</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;An efficient solvent mediated &amp;amp; use of metal-free catalyst strategy was developed for synthesis of FDCA over two steps. A simple &amp;amp; economical glucose-hydrothermally carbonized (Glu-HTC) catalyst was prepared and evaluated for synthesis of 2,5-Diformyl furan (DFF) from fructose &amp;amp; 5-hydroxymethylfurfural (HMF) in the 1(st) step. DFF was then converted to FDCA using Pinnick oxidation in the 2(nd) step. DFF was obtained in 82% &amp;amp; 86% yields from fructose &amp;amp; HMF respectively whereas FDCA was obtained in 94-95% yield from DFF. FDCA was thus formed in an overall yield of 78% and 81% from fructose &amp;amp; HMF respectively. This strategy eliminated use of expensive noble metals for FDCA synthesis and also intermediates such as HMFCA &amp;amp; FFCA were not observed after the reaction as DFF was completely oxidized to FDCA.&lt;/p&gt;
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