<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bankar, Shubham R.</style></author><author><style face="normal" font="default" size="100%">Kirdant, Swapnali P.</style></author><author><style face="normal" font="default" size="100%">Jadhav, Vrushali H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Cobalt-immobilized carbon-based nano-catalyst for Csingle bondN cross coupling reaction</style></title><secondary-title><style face="normal" font="default" size="100%">Results in Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">4</style></volume><pages><style face="normal" font="default" size="100%">100682</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	&lt;span style=&quot;color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;C&lt;/span&gt;&lt;img alt=&quot;single bond&quot; src=&quot;https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; border-style: none; width: auto; max-width: 100%; height: auto; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px; vertical-align: middle;&quot; /&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px;&quot;&gt;N&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/cross-coupling-reaction&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about cross coupling reaction from ScienceDirect's AI-generated Topic Pages&quot;&gt;cross coupling reaction&lt;/a&gt;&amp;nbsp;is very important in synthesis of pharmaceuticals,&amp;nbsp;&lt;/span&gt;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/occurrence-in-nature&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about natural products from ScienceDirect's AI-generated Topic Pages&quot;&gt;natural products&lt;/a&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px;&quot;&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px;&quot;&gt;,&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/agrochemical&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about agrochemicals from ScienceDirect's AI-generated Topic Pages&quot;&gt;agrochemicals&lt;/a&gt;, fine chemicals and functional materials. Traditionally,&amp;nbsp;&lt;/span&gt;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/palladium&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about palladium from ScienceDirect's AI-generated Topic Pages&quot;&gt;palladium&lt;/a&gt;&amp;nbsp;or copper metals are used for C&lt;/span&gt;&lt;/span&gt;&lt;img alt=&quot;single bond&quot; src=&quot;https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; border-style: none; width: auto; max-width: 100%; height: auto; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px; vertical-align: middle;&quot; /&gt;&lt;span style=&quot;color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;N coupling reaction. As palladium is expensive, we developed cobalt immobilized carbon-based nano-catalyst Co@CC for C&lt;/span&gt;&lt;img alt=&quot;single bond&quot; src=&quot;https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; border-style: none; width: auto; max-width: 100%; height: auto; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px; vertical-align: middle;&quot; /&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;N coupling. In this work, we synthesized non-noble metal-based Co@CC nano-catalyst by&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/carbonization&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about carbonization from ScienceDirect's AI-generated Topic Pages&quot;&gt;carbonization&lt;/a&gt;&amp;nbsp;of glucose, it’s functionalization followed by immobilization of cobalt on the surface of the catalyst. The catalyst was well characterized. The C&lt;/span&gt;&lt;img alt=&quot;single bond&quot; src=&quot;https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; border-style: none; width: auto; max-width: 100%; height: auto; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px; vertical-align: middle;&quot; /&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;N cross coupling reaction of various aryl&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/halide&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about halides from ScienceDirect's AI-generated Topic Pages&quot;&gt;halides&lt;/a&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px;&quot;&gt;&amp;nbsp;&amp;amp; amines using Co@CC nano-catalyst was optimized for solvent, reaction temperature &amp;amp; catalyst&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/concentration-condition&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about concentration conditions from ScienceDirect's AI-generated Topic Pages&quot;&gt;concentration conditions&lt;/a&gt;. The catalyst showed high catalytic activity for C&lt;/span&gt;&lt;/span&gt;&lt;img alt=&quot;single bond&quot; src=&quot;https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; border-style: none; width: auto; max-width: 100%; height: auto; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px; vertical-align: middle;&quot; /&gt;&lt;span style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;N coupling of various aryl halides &amp;amp; amines to form aryl amines in good to excellent yield up to 91&amp;nbsp;% in&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/chemistry/sulfolane&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about sulfolane from ScienceDirect's AI-generated Topic Pages&quot;&gt;sulfolane&lt;/a&gt;&amp;nbsp;as a solvent at 150&amp;nbsp;°C. The catalyst showed recyclability up to 5 times. The method developed for C&lt;/span&gt;&lt;img alt=&quot;single bond&quot; src=&quot;https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; border-style: none; width: auto; max-width: 100%; height: auto; color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px; vertical-align: middle;&quot; /&gt;&lt;span style=&quot;color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif; font-size: 16px;&quot;&gt;N coupling reaction was noble metal free, ligand free, recyclable, sustainable, economical &amp;amp; environmentally friendly.&lt;/span&gt;&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	2.021&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tamboli, Asma T. Biradar</style></author><author><style face="normal" font="default" size="100%">Kirdant, Swapnali P.</style></author><author><style face="normal" font="default" size="100%">Jadhav, Vrushali H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Metal-free approach towards efficient synthesis of FDCA using a p-toluene sulfonic acid (p-TSA)-derived heterogeneous solid acid catalyst and oxone over two steps from HMF, fructose and glucose</style></title><secondary-title><style face="normal" font="default" size="100%">New Journal of Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">46</style></volume><pages><style face="normal" font="default" size="100%">10272-10279</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	In this work, a metal-free approach towards the synthesis of 2,5-furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF), fructose and glucose is reported over two steps using a p-toluene sulfonic acid (p-TSA)-derived heterogeneous solid acid catalyst (p-TSA-POM) in the first step and oxone as an oxidant in the second step. HMF, fructose and glucose were converted to 2,5-diformylfuran (DFF) using the p-TSA-POM catalyst followed by oxidation of DFF to FDCA using oxone. To the best of our knowledge, this is the first metal-free approach for the synthesis of FDCA directly from glucose. DFF was obtained from HMF in 91% yield, whereas it was obtained in 85% and 61% yields from fructose &amp;amp; glucose, respectively. DFF was further converted to FDCA using oxone as an oxidant. FDCA was obtained in an overall yield of 84%, 78% and 56% from HMF, fructose &amp;amp; glucose, respectively.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">21</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	3.925&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kirdant, Swapnali P.</style></author><author><style face="normal" font="default" size="100%">Tamboli, Asma T. Biradar</style></author><author><style face="normal" font="default" size="100%">Jadhav, Vrushali H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Recent developments in the applications of biomass-derived sulfonated carbonaceous solid acid catalysts</style></title><secondary-title><style face="normal" font="default" size="100%">Helvetica Chimica Acta</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Biodiesel</style></keyword><keyword><style  face="normal" font="default" size="100%">Biomass</style></keyword><keyword><style  face="normal" font="default" size="100%">cellulose</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">sulfonated carbonaceous solid acid catalyst</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">105</style></volume><pages><style face="normal" font="default" size="100%">e202200032</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Recently, carbon-based materials are gaining a lot of attraction. It is considered as an emerging area of research and has gained significant importance as an efficient catalyst/material in various fields. Biomass is abundantly available, cheap and a renewable carbon resource. Sulfonated carbonaceous solid acid catalyst can be derived by sulfonation of various sources of biomass such as sugars, lignin, fruit waste, agro-waste, bio-char, etc. Sulfonated carbonaceous solid acid catalysts can be used as a substitute to liquid acids. These catalysts possess a stable carbon skeleton and are insoluble in almost all organic solvents as well as under acidic/basic conditions. This review covers details about biomass-derived sulfonated carbonaceous solid acid catalysts and its catalytic activities in many important transformations such as hydrolysis of cellulose, synthesis of biodiesel, synthesis of various important chemicals and for various organic transformations.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">8</style></issue><work-type><style face="normal" font="default" size="100%">Review</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	2.201&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kirdant, Swapnali P.</style></author><author><style face="normal" font="default" size="100%">Bankar, Shubham R.</style></author><author><style face="normal" font="default" size="100%">Jadhav, Vrushali H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Direct oxidation of alcohols to carboxylic acids using simple and economical Pd@Glu-HTC catalyst: practical and scalable approach towards biomass based value added chemicals</style></title><secondary-title><style face="normal" font="default" size="100%">Biomass &amp; Bioenergy</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Bio-based chemicals</style></keyword><keyword><style  face="normal" font="default" size="100%">Carbonaceous catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">Carboxylic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Oxidation</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">187</style></volume><pages><style face="normal" font="default" size="100%">107290</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Sustainable catalytic transformation of bio-based alcohols to high value-added fine chemicals is an important topic of research. This work described preparation of simple and economical Pd@Glu-HTC catalyst from biomass derived low cost D-glucose. Hydrothermal carbonization of glucose was carried out in first step to synthesize GluHTC support in a simpler, greener, economical and efficient manner followed by incorporation of palladium metal on surface of the catalyst in second step. The catalyst was characterized using techniques such as Fourier Transform Infrared Spectroscopy (FT-IR), Solid-state Cross-Polarization Magic Angle Spinning Carbon-13 (13C CPMAS), Energy-dispersive X-ray spectroscopy (EDAX), Powder X-ray diffraction (P-XRD), X-ray photoelectron spectroscopy (XPS), Thermogravimetric/Differential Thermal Analyzer (TG-DTA), Field emission scanning electron microscopy (FE-SEM) and High-resolution transmission electron microscopy (HR-TEM). The catalyst was evaluated for direct oxidation of alcohols to yield carboxylic acids and exhibited very good catalytic activity for wider substrate scope. Oxidation of alcohols was carried out using milder base, molecular oxygen and water as a solvent to achieve 92-99 % excellent yields. The practical utility of current strategy was also studied for gram scale synthesis of bio-based value added industrially important chemicals such as furoic acid (flavouring agent and preservative in industry), 2, 5-furan-dicarboxylic acid (monomer to 100 % fossil-free, recyclable polymer polyethylene furanoate (PEF), tetrahydro-2-furoic acid (production of many drugs) and vanillin (important product of flavor and fragrance industry). Pd@Glu-HTC catalyst was found to be reusable for four recycles and the catalytic performance was retained without any loss in its activity after four cycles.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	6&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kirdant, Swapnali P.</style></author><author><style face="normal" font="default" size="100%">Ghadge, Sambhaji S.</style></author><author><style face="normal" font="default" size="100%">Jadhav, Vrushali H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Graphitic-C3N4/γ-Al2O3 composite catalyst for synthesis of 5-(Hydroxymethyl) furfural from d-Glucose</style></title><secondary-title><style face="normal" font="default" size="100%">Energy &amp; Fuels</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">39</style></volume><pages><style face="normal" font="default" size="100%">8529-8539</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Currently, the synthesis of 5-hydroxymethylfurfural (5-HMF), with high yields and selectivity from different renewable sources, is an important focus in the biomass conversion area. In the present study, a g-C3N4/gamma-Al2O3(1:1) composite catalyst was prepared using graphitic carbon nitride (g-C3N4) and acidic gamma-alumina (gamma-Al2O3), which was evaluated for its catalytic activity in converting sugars, mainly glucose, to 5-HMF. In the g-C3N4/gamma-Al2O3(1:1) catalyst, N-containing groups on g-C3N4 provided basicity and gamma-Al2O3 provided Lewis acidity to the catalyst. The g-C3N4/gamma-Al2O3(1:1) composite catalyst showed superior activity for 5-HMF synthesis compared to gamma-Al2O3 and g-C3N4 alone. The increased acidic and basic properties of the g-C3N4/gamma-Al2O3(1:1) catalyst significantly influenced both glucose-to-fructose isomerization and dehydration of fructose to HMF by increasing the yield of 5-HMF. In addition, the solvent DMSO:water also played an important role in the one-pot conversion of glucose to HMF by minimizing side reactions, which significantly improved the 5-HMF yield. The reaction was optimized for various solvents, temperatures, and catalyst concentrations to get a maximum yield of 91% from glucose with &amp;gt;99% selectivity of crude 5-HMF. Other sugars like fructose, sucrose, and lactose also provided good yields of 5-HMF. The g-C3N4/gamma-Al2O3(1:1) catalyst was stable and was effectively reused for up to four cycles.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">18</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
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	4.5&lt;/p&gt;
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