<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Chauhan, Inderjeet</style></author><author><style face="normal" font="default" size="100%">Vijay, Pothoppurathu M.</style></author><author><style face="normal" font="default" size="100%">Ranjan, Ravi</style></author><author><style face="normal" font="default" size="100%">Patra, Kshirodra Kumar</style></author><author><style face="normal" font="default" size="100%">Gopinath, Chinnakonda S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Electrocatalytic and selective oxidation of glycerol to formate on 2D 3d-metal phosphate nanosheets and carbon-negative hydrogen generation</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Materials Au</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">4</style></volume><pages><style face="normal" font="default" size="100%">500-511</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;In the landscape of green hydrogen production, alkaline water electrolysis is a well-established, yet not-so-cost-effective, technique due to the high overpotential requirement for the oxygen evolution reaction (OER). A low-voltage approach is proposed to overcome not only the OER challenge by favorably oxidizing abundant feedstock molecules with an earth-abundant catalyst but also to reduce the energy input required for hydrogen production. This alternative process not only generates carbon-negative green H&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;but also yields concurrent value-added products (VAPs), thereby maximizing economic advantages and transforming waste into valuable resources. The essence of this study lies in a novel electrocatalyst material. In the present study, unique and two-dimensional (2D) ultrathin nanosheet phosphates featuring first-row transition metals are synthesized by a one-step solvothermal method, and evaluated for the electrocatalytic glycerol oxidation reaction (GLYOR) in an alkaline medium and simultaneous H&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;production. Co&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;(PO&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;4&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;)&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;(CoP), Cu&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;(PO&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;4&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;)&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;(CuP), and Ni&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;(PO&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;4&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;)&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;(NiP) exhibit 2D sheet morphologies, while FePO&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;4&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;(FeP) displays an entirely different snowflake-like morphology. The 2D nanosheet morphology provides a large surface area and a high density of active sites. As a GLYOR catalyst, CoP ultrathin (∼5 nm) nanosheets exhibit remarkably low onset potential at 1.12 V (vs RHE), outperforming that of NiP, FeP, and CuP around 1.25 V (vs RHE). CoP displays 82% selective formate production, indicating a superior capacity for C–C cleavage and concurrent oxidation; this property could be utilized to valorize larger molecules. CoP also exhibits highly sustainable electrochemical stability for a continuous 200 h GLYOR operation, yielding 6.5 L of H&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;production with a 4 cm&lt;/span&gt;&lt;span style=&quot;box-sizing: border-box; outline: none; line-height: 0; position: relative; vertical-align: baseline; top: -0.5em; color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgb(21, 21, 21); font-family: Roboto, arial, sans-serif; font-size: 16px;&quot;&gt;&amp;nbsp;electrode and 98 ± 0.5% Faradaic efficiency. The present study advances our understanding of efficient GLYOR catalysts and underscores the potential of sustainable and economically viable green hydrogen production methodologies.&lt;/span&gt;&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	5.7&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Chauhan, Inderjeet</style></author><author><style face="normal" font="default" size="100%">Bajpai, Himanshu</style></author><author><style face="normal" font="default" size="100%">Ray, Bishakha</style></author><author><style face="normal" font="default" size="100%">Kolekar, Sadhu K.</style></author><author><style face="normal" font="default" size="100%">Datar, Suwarna</style></author><author><style face="normal" font="default" size="100%">Patra, Kshirodra Kumar</style></author><author><style face="normal" font="default" size="100%">Gopinath, Chinnakonda S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Electrocatalytic glycerol conversion: a low-voltage pathway to efficient carbon-negative green hydrogen and value-added chemical production</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials and Interfaces </style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">electrocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Glycerol</style></keyword><keyword><style  face="normal" font="default" size="100%">green hydrogen</style></keyword><keyword><style  face="normal" font="default" size="100%">nanocube</style></keyword><keyword><style  face="normal" font="default" size="100%">Palladium</style></keyword><keyword><style  face="normal" font="default" size="100%">SDG</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">16</style></volume><pages><style face="normal" font="default" size="100%">26130-26141</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Electrochemical glycerol oxidation reaction (GLYOR) could be a promising way to use the abundantly available glycerol for production of value-added chemicals and fuels. Completely avoiding the oxygen evolution reaction (OER) with GLYOR is an evolving strategy to reduce the overall cell potential and generate value-added chemicals and fuels on both the anode and cathode. We demonstrate the morphology-controlled palladium nanocrystals, afforded by colloidal chemistry, and their established morphology-dependent GLYOR performance. Although it is known that controlling the morphology of an electrocatalyst can modulate the activity and selectivity of the products, still it is a relatively underexplored area for many reactions, including GLYOR. Among nanocube (Pd-NC), truncated octahedron (Pd-TO), spherical and polycrystalline (Pd-PC) morphologies, the Pd-NC electrocatalyst deposited on a Ni foam exhibits the highest glycerol conversion (85%) along with 42% glyceric acid selectivity at a low applied potential of 0.6 V (vs reversible hydrogen electrode (RHE)) in 0.1 M glycerol and 1 M KOH at ambient temperature. Owing to the much favorable thermodynamics of GLYOR on the Pd-NC surface, the assembled electrolyzer requires an electricity input of only similar to 3.7 kWh/m(3) of H-2 at a current density of 100 mA/cm(2), in contrast to the requirement of &amp;gt;= 5 kWh/m(3) of H-2 with an alkaline/PEM electrolyzer. Sustainability has been successfully demonstrated at 10 and 50 mA/cm(2) and up to 120 h with GLYOR in water and simulated seawater.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">20</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	9.5&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pal, Santanu</style></author><author><style face="normal" font="default" size="100%">Sinha, Nibedita</style></author><author><style face="normal" font="default" size="100%">Das, Chandni</style></author><author><style face="normal" font="default" size="100%">Chauhan, Inderjeet</style></author><author><style face="normal" font="default" size="100%">Ahmed, Tanbir</style></author><author><style face="normal" font="default" size="100%">Roy, Poulomi</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Enhanced electrocatalytic performances of NiCr layered double hydroxides by oxalate intercalation in anion exchange membrane water electrolysis</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Anion exchange</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrogen production</style></keyword><keyword><style  face="normal" font="default" size="100%">interlayerspacing</style></keyword><keyword><style  face="normal" font="default" size="100%">Layered double hydroxide</style></keyword><keyword><style  face="normal" font="default" size="100%">Sustainable</style></keyword><keyword><style  face="normal" font="default" size="100%">water electrolyzer</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">17</style></volume><pages><style face="normal" font="default" size="100%">37863-37878</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Layered double hydroxides (LDHs) have attracted much attention these days in the field of water electrolysis due to easy modulation in their layered structure and properties. Herein, NiCr-LDH has been developed, and its interlayer spacing has been considerably increased by oxalate intercalation. Such increased interlayer spacing allows easy access of hydroxides to a large number of electroactive sites and thereby boosts the electrocatalytic performances both for oxygen and hydrogen evolution reactions. Being very active toward both the electrocatalytic reactions, the oxalate-intercalated NiCr-LDH was further explored in an alkaline anion exchange membrane water electrolyzer (AEMWE), achieving 800 mA cm-2 at 1.88 V cell voltage at an operating temperature of 60 degrees C. In fact, the electrolyzer efficiency has been determined to be as high as 69.66%, and the calculated H2 production cost was found to be \$0.97 per gasoline-gallon equivalent, which is well below the targeted cost by the Department of Energy, USA. The electrocatalyst was also examined in harsh alkaline media, like highly saline or seawater, which also indicated its ability to carry out sustainable seawater electrolysis, restricting chlorides to a great extent. Interestingly, post-electrolysis characterization reveals the fact that oxalate decomposition aided carbonate formation within interlayers of NiCr-LDH, and high affinity toward hydroxides is responsible for restricting chlorides during the electrolysis process, apart from the great electrocatalytic activity.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">26</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	8.5&lt;/p&gt;
</style></custom4></record></records></xml>