<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Cherevotan, Arjun</style></author><author><style face="normal" font="default" size="100%">Ray, Bitan</style></author><author><style face="normal" font="default" size="100%">Yadav, Anish</style></author><author><style face="normal" font="default" size="100%">Bagchi, Debabrata</style></author><author><style face="normal" font="default" size="100%">Singh, Ashutosh Kumar</style></author><author><style face="normal" font="default" size="100%">Riyaz, Mohd</style></author><author><style face="normal" font="default" size="100%">Churipard, Sathyapal R.</style></author><author><style face="normal" font="default" size="100%">Naral, Vinay</style></author><author><style face="normal" font="default" size="100%">Kaur, Komalpreet</style></author><author><style face="normal" font="default" size="100%">Gautam, Ujjal K.</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath P.</style></author><author><style face="normal" font="default" size="100%">Peter, Sebastian C.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Tuning the hybridization and charge polarization in metal nanoparticles dispersed over Schiff base functionalized SBA-15 enhances CO2 capture and conversion to formic acid</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Materials Chemistry A</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">10</style></volume><pages><style face="normal" font="default" size="100%">18354-18362</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Different Schiff base functionalized SBA-15 materials were synthesized through condensation reactions between 3-aminopropyltriethoxysilane (APTES) and different aldehydes (glutaraldehyde and butyraldehyde) over a mesoporous silica, SBA-15 (APTES-GLU/SBA-15 and APTES-BUT/SBA-15). Both static and dynamic experiments have been used for testing the CO2 capture efficiency of these materials. The hybridization of the N atom in APTES has been tuned from sp(3) to sp(2) upon condensation facilitating optimum CO2 capture in the direct synthesis of APTES-GLU/SBA-15. The undesirable oxides of nitrogen have been removed during the synthesis process to improve the CO2 capture efficiency. These materials were employed as supports for Pd-Ag and Pd-Ni bimetallic systems for the selective conversion of the captured CO2 to formic acid (FA) in 0.5 M KHCO3 solution. The Pd-Ni catalyst system exhibited enhanced CO2 to FA conversion activity compared to other heterogeneous systems, which is similar to 4 times better than that of the Pd-Ag system in this study. The X-ray absorption studies over the catalyst material confirmed that the relatively electron-deficient Ni in Pd-Ni compared to Ag in Pd-Ag favoured higher charge polarization between the metals in the Pd-Ni system enhancing the CO2 to FA conversion. The experimental observations are well supported by the DFT calculations.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">35</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
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	14.511&lt;/p&gt;
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