<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tawade, Anita K.</style></author><author><style face="normal" font="default" size="100%">Kumar, Praveen</style></author><author><style face="normal" font="default" size="100%">Tayade, Shivaji N.</style></author><author><style face="normal" font="default" size="100%">Sharma, Geetarani K.</style></author><author><style face="normal" font="default" size="100%">Luwang, Meitram Niraj</style></author><author><style face="normal" font="default" size="100%">Sharma, Kiran Kumar K.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Liquid crystalline nanoconfined growth of PANI on rGO for enhanced electrochemical glucose sensing</style></title><secondary-title><style face="normal" font="default" size="100%">Nanoscale</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">18</style></volume><pages><style face="normal" font="default" size="100%">5531-5543</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	We report here a new strategy for the successful synthesis of a hybrid 2D nanocomposite via the in situ functionalization of graphene oxide (GO) with aniline monomers in a bi-solvent swollen liquid crystalline lamellar mesophase (SLCLM) nanoreactor. The synthesized nanocomposite product revealed possible simultaneous reactions at the edge and basal plane of GO. A mechanism for the transformation via simultaneous nucleophilic attack and spontaneous polymerization, forming a reduced graphene oxide-polyaniline (rGO-PANI) nanocomposite, is proposed. The multistep plausible reaction mechanism for the functionalization of the GO edge -COOH group is achieved by successful synthesis, followed by isolation and characterization of the N-phenyl anthranilic acid derivative as an intermediate product. Furthermore, the detection of CO2 evolution as a by-product during the reaction complements the plausible mechanism for the incorporation of (-C Xi C-) graphyne-type edges and formation of new -C-N- and O-H bonds in the rGO-PANI nanocomposite. These results are supported by FT-IR, Raman, XPS, SAXS, and C-13 NMR spectroscopy analyses. A reduced graphene oxide-polyaniline (rGO-PANI) modified glassy carbon electrode was developed for glucose sensing, exhibiting a wide linear range (0.554-10 &amp;amp; micro;M), low detection limit (50 pM), and high sensitivity (372 660 &amp;amp; micro;A mM(-1) cm(-2)). The sensor demonstrated excellent selectivity against common interferents (ascorbic acid, uric acid, and dopamine), reproducibility (RSD &amp;lt; 5%), and stability over 10 000 s with minimal signal loss. The detection of glucose from human metabolites, such as urine and sweat, achieved 98-100% recoveries for spiked glucose, confirming its practical applicability. These results establish rGO-PANI as a robust platform for sensitive and selective glucose detection.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">10</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	5.1&lt;/p&gt;
</style></custom4></record></records></xml>