<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singh, Thangjam Ibomcha</style></author><author><style face="normal" font="default" size="100%">Maibam, Ashakiran</style></author><author><style face="normal" font="default" size="100%">Cha, Dun Chan</style></author><author><style face="normal" font="default" size="100%">Yoo, Sunghoon</style></author><author><style face="normal" font="default" size="100%">BabaRao, Ravichandar</style></author><author><style face="normal" font="default" size="100%">Lee, Sang Uck</style></author><author><style face="normal" font="default" size="100%">Lee, Seunghyun</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">High-alkaline water-splitting activity of mesoporous 3D heterostructures: an amorphous-shell@crystalline-core nano-assembly of Co-Ni-phosphate ultrathin-nanosheets and V- doped cobalt-nitride nanowires</style></title><secondary-title><style face="normal" font="default" size="100%">Advanced Science</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">core-shell</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrogen productions</style></keyword><keyword><style  face="normal" font="default" size="100%">metal nitrides</style></keyword><keyword><style  face="normal" font="default" size="100%">metal phosphates</style></keyword><keyword><style  face="normal" font="default" size="100%">synergistic effect</style></keyword><keyword><style  face="normal" font="default" size="100%">water-splitting</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">9</style></volume><pages><style face="normal" font="default" size="100%">2201311</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Introducing amorphous and ultrathin nanosheets of transition bimetal phosphate arrays that are highly active in the oxygen evolution reaction (OER) as shells over an electronically modulated crystalline core with low hydrogen absorption energy for an excellent hydrogen evolution reaction (HER) can boost the sluggish kinetics of the OER and HER in alkaline electrolytes. Therefore, in this study, ultrathin and amorphous cobalt-nickel-phosphate (CoNiPOx) nanosheet arrays are deposited over vanadium (V)-doped cobalt-nitride (V-3%-Co4N) crystalline core nanowires to obtain amorphous-shell@crystalline-core mesoporous 3D-heterostructures (CoNiPOx@V-Co4N/NF) as bifunctional electrocatalysts. The optimized electrocatalyst shows extremely low HER and OER overpotentials of 53 and 270 mV at 10 mA cm(-2), respectively. The CoNiPOx@V-3%-Co4N/NF (+/-) electrolyzer utilizing the electrocatalyst as both anode and cathode demonstrates remarkable overall water-splitting activity, requiring a cell potential of only 1.52 V at 10 mA cm(-2), 30 mV lower than that of the RuO2/NF (+)/20%-Pt/C/NF (-) electrolyzer. Such impressive bifunctional activities can be attributed to abundant active sites, adjusted electronic structure, lower charge-transfer resistance, enhanced electrochemically active surface area (ECSA), and surface- and volume-confined electrocatalysis resulting from the synergistic effects of the crystalline V-3%-Co4N core and amorphous CoNiPOx shells boosting water splitting in alkaline media.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">23</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	&lt;span style=&quot;font-family:arial,helvetica,sans-serif;&quot;&gt;Foreign&lt;/span&gt;&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	17.521&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Patrike, Apurva</style></author><author><style face="normal" font="default" size="100%">Karbhal, Indrapal</style></author><author><style face="normal" font="default" size="100%">Wasnik, Kundan</style></author><author><style face="normal" font="default" size="100%">Torris, Arun</style></author><author><style face="normal" font="default" size="100%">Maibam, Ashakiran</style></author><author><style face="normal" font="default" size="100%">Krishnamurty, Sailaja</style></author><author><style face="normal" font="default" size="100%">Shelke, V, Manjusha</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">High rate, high temperature, dendrite free plating/stripping of Li in 3-dimensional honeycomb boron carbon nitride to realize an ultrastable lithium metal anode</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Energy Storage</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Boron carbon nitride</style></keyword><keyword><style  face="normal" font="default" size="100%">Dendrite-free Li metal anode</style></keyword><keyword><style  face="normal" font="default" size="100%">Functional scaffold</style></keyword><keyword><style  face="normal" font="default" size="100%">High temperature plating/stripping of Li</style></keyword><keyword><style  face="normal" font="default" size="100%">Molecular planarity parameter</style></keyword><keyword><style  face="normal" font="default" size="100%">X-ray micro-tomography</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">68</style></volume><pages><style face="normal" font="default" size="100%">107547</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Lithium (Li) metal could be the anode of choice for energy dense Li-batteries owing to its high theoretical specific capacity. However, low coulombic efficiency and poor safety on account of the occurrence of the Li-dendrites during charging-discharging pose a bottleneck for practical applications. In this work, we report a high-rate plating and stripping of Li through host engineering to realize ultrastable Li metal anode (LMA). Benchmark plating/stripping efficiency could be achieved via uniquely structured, highly ordered honeycomb boron carbon nitride (HBCN) as a functional scaffold. Boron and nitrogen doping, large surface area and ordered mesoporous structure induce homogeneous solid electrolyte interface (SEI) layer formation and provide numerous nucleation sites with subsequent dendrite-free growth with 99.98 % coulombic efficiency at 8 mA cm(-2) high current and 10 mAh cm(-2) capacity over 3000 cycles. Via post-cycling advanced characterizations techniques of Ex-situ XPS, 3D X-ray micro-tomography analyses and FESEM, we demonstrate the formation of a stable SEI layer and morphological changes that occurred during Li plating cycles in the HBCN structure. Computational studies validate the high lithium plating-stripping efficacy of HBCN to its highly ordered porous nature, exothermic Li-binding and upshift in the Fermi levels. When tested at elevated temperature (50 degrees C), a stable Li plating-stripping in HBCN is realised at 4 mA cm(-2) current and 10 mAh cm(-2) capacity values with similar to 100 % C.E. Furthermore, we report the results of testing a Li metal cell comprised of Li deposited HBCN anode and LiFePO4 (LFP) cathode.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	9.4&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Chhetri, Ashis</style></author><author><style face="normal" font="default" size="100%">Maibam, Ashakiran</style></author><author><style face="normal" font="default" size="100%">Maniam, Subashani</style></author><author><style face="normal" font="default" size="100%">BabaRao, Ravichandar</style></author><author><style face="normal" font="default" size="100%">Wilson, Karen</style></author><author><style face="normal" font="default" size="100%">Lee, Adam F.</style></author><author><style face="normal" font="default" size="100%">Mitra, Joyee</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Heterogeneous acid-base organocatalyst for cascade deacetalisation-knoevenagel condensations</style></title><secondary-title><style face="normal" font="default" size="100%">ChemSusChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Antagonistic acid-base sites</style></keyword><keyword><style  face="normal" font="default" size="100%">Charge-assisted hydrogen bonding</style></keyword><keyword><style  face="normal" font="default" size="100%">Chemical cascade</style></keyword><keyword><style  face="normal" font="default" size="100%">organocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Sustainable catalysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">17</style></volume><pages><style face="normal" font="default" size="100%">e202400866</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Multifunctional heterogeneous catalysts are an effective strategy to drive chemical cascades, with attendant time, resource and cost efficiencies by eliminating unit operations arising in normal multistep processes. Despite advances in the design of such catalysts, the fabrication of proximate, chemically antagonistic active sites remains a challenge for inorganic materials science. Hydrogen-bonded organocatalysts offer new opportunities for the molecular level design of multifunctional structures capable of stabilising antagonistic active sites. We report the catalytic application of a charge-assisted, hydrogen-bonded crystalline material, bis(melaminium)adipate (BMA), synthesised from melamine and adipic acid, which possesses proximate acid-base sites. BMA exhibits high activity for the cascade deacetalisation-Knoevenagel condensation of dimethyl acetals to form benzylidenemalononitriles under mild conditions in water; BMA is amenable to large-scale manufacture and recycling with minimal deactivation. Computational modelling of the melaminium cation in protonated BMA explains the observed catalytic reactivity, and identifies the first demethoxylation step as rate-limiting, which is in good agreement with time-dependent 1H NMR and kinetic experiments. A broad substrate scope for the cascade transformation of aromatic dimethyl acetals is demonstrated.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">24</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	7.5&lt;/p&gt;
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