<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ho, Leong Chuan</style></author><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">HBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane</style></title><secondary-title><style face="normal" font="default" size="100%">Energy</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Cyclopentane</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas separation</style></keyword><keyword><style  face="normal" font="default" size="100%">Pre-combustion</style></keyword><keyword><style  face="normal" font="default" size="100%">Unstirred reactor</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">63</style></volume><pages><style face="normal" font="default" size="100%">252-259</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The effect of CP (cyclopentane) as a promoter/additive, in the HBGS (hydrate based gas separation) process for pre-combustion gas mixture was investigated by employing an unstirred reactor configuration. Gas uptake measurements were performed at two different temperatures (275.7 K and 285.7 K) and at an experimental pressure of 6.0 MPa to determine the kinetics of hydrate formation. Experiments were conducted with three different volumes (7.5, 15 and 22 ml) of CP and based on induction time and the rate of hydrate growth, 15 ml of CP was determined to be the optimal volume for carbon dioxide capture at 6.0 MPa and 275.7 K. In addition, the effect of a kinetic promoter, SDS (sodium dodecyl sulfate), was investigated. Surprisingly, no improvement in kinetic performance was observed at 6.0 MPa and 275.7 K in the presence of SDS and CP. From the study, it was found that at the optimal 15 ml CP (CP layer thickness of 1.8 mm), the average composition of carbon dioxide in the hydrate phase was 90.36 mol% with a separation factor of 17.82. Furthermore, the unstirred reactor also yielded better kinetic performance over the stirred tank reactor with the unstirred reactor having a 2.28 times higher average gas uptake. (C) 2013 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.159
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Yang, Ting</style></author><author><style face="normal" font="default" size="100%">Veluswamy, Hari Prakash</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hydrate phase equilibrium of ternary gas mixtures containing carbon dioxide, hydrogen and propane</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Chemical Thermodynamics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Global warming</style></keyword><keyword><style  face="normal" font="default" size="100%">Phase equilibrium</style></keyword><keyword><style  face="normal" font="default" size="100%">Pre-combustion</style></keyword><keyword><style  face="normal" font="default" size="100%">Thermodynamics</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">24-28 OVAL RD, LONDON NW1 7DX, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">61</style></volume><pages><style face="normal" font="default" size="100%">58-63</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrate phase equilibrium of the ternary guest mixtures containing carbon dioxide, hydrogen and propane at two different compositions were determined. Addition of mole composition of 2.5% propane to the fuel gas (CO2 (40%)/H-2 (60%)) mixture reduces the hydrate formation conditions by 66% at the temperature of 278.4 K. A Clausius-Clapeyron plot for the experimental results was plotted and from the slope, the enthalpy of hydrate dissociation was calculated. The enthalpy of dissociation of the mixed hydrate formed from a ternary gas mixture containing mole composition 38.1% CO2, 59.4% H-2 and 2.5% C3H8 was found to be 110 kJ.mol(-1) and hence it was concluded that the mixed hydrate formed structure II (sII) hydrates. Whereas for the ternary gas mixture containing mole composition 80.0% CO2, 18.8% H-2, and 1.2% C3H8, the enthalpy of dissociation of the mixed hydrate was found to be 78 kJ.mol(-1) and hence we believe the mixed hydrate formed structure I (sI) hydrate. (C) 2013 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.423
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Medium pressure hydrate based gas separation (HBGS) process for pre-combustion capture of carbon dioxide employing a novel fixed bed reactor</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Greenhouse Gas Control</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Global warming</style></keyword><keyword><style  face="normal" font="default" size="100%">Pre-combustion</style></keyword><keyword><style  face="normal" font="default" size="100%">Separation</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ELSEVIER SCI LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">17</style></volume><pages><style face="normal" font="default" size="100%">206-214</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;This work presents an effective medium pressure hydrate based gas separation (HBGS) process for pre-combustion carbon dioxide capture in a novel fixed bed column. 2.5 mol% propane was added to the fuel gas mixture as an additive to decrease the operating pressure of the HBGS process. Hydrate formation kinetics was investigated at three different pressures (4.5, 5.5 and 6.0 MPa respectively) and at 274.15 K. The performance of silica sand and silica gel as a medium was evaluated. In silica sand bed, multiple nucleation events were observed. In silica gel bed, the gas uptake and water conversion to hydrates was significantly low at any given driving force than that obtained in silica sand bed. Experiments at different water saturation levels (50, 75 and 100%) in silica sand bed were investigated at 6.0 MPa and 274.15 K. It was found that at 50% water saturation, gas consumed for hydrate formation and water conversion to hydrates was almost three times that at 100% saturation. Water to hydrate conversions of up to 64.3% was achieved after 4 h of hydrate formation for the 50% water saturated silica sand bed. Our study presents an opportunity to scale up the HBGS process for CO2 capture with enhanced kinetics by employing a fixed bed reactor configuration. Decomposition experiments at a driving force of Delta T of 10 K and 23K were carried out to recover the gas consumed for hydrate formation and it was found that Delta T of 23 K was sufficient to recover the hydrated gas. (C) 2013 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">3.821
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Lim, Yu-An</style></author><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Morphology of carbon dioxide-hydrogen-cyclopentane hydrates with or without sodium dodecyl sulfate</style></title><secondary-title><style face="normal" font="default" size="100%">Crystal Growth &amp; Design</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">5</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">13</style></volume><pages><style face="normal" font="default" size="100%">2047-2059</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In this study, effects of cyclopentane (CP) and sodium dodecyl sulfate (SDS) on the hydrate formation morphology were investigated. A gas mixture of 40.0 mol % carbon dioxide and 60.0 mol % hydrogen was used in an unstirred system with subcooling as the driving force. Experimental pressure is at 6.0 MPa and experimental temperatures used are at 275.65 and 277.65 K (Delta T = 15.15 and 13.15 K). Formation of hydrates started at the cyclopentane-liquid water interface. Cloud-like, equiaxed skewed dendritic, equiaxed orthogonal dendritic, long dendritic, and cactus-like crystals could be observed for the experiments in the absence of surfactants. Rapid hydrate formation was observed for the experiments with 0.9 mL CP with or without the presence of surfactants compared to the experiments with 0.45 mL CP system at the same experimental conditions. The addition of SDS had led to a change in the hydrate crystal morphology, forming fiber-like crystals from the hydrate layer. Hydrates had also shown affinity to metal surfaces and tend to grow rapidly because of better heat transfer capacity. Gas uptake measurements were found to correlate well with the morphological observations. On the basis of the morphological observations, the mechanism of the CO2-H-2-CP system in an unstirred system is presented.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.558
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">New porous material to enhance the kinetics of clathrate process: application to precombustion carbon dioxide capture</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental Science &amp; Technology</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">22</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">47</style></volume><pages><style face="normal" font="default" size="100%">13191-13198</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In this work, the performance of a new porous medium, polyurethane (PU) foam in a fixed bed reactor for carbon dioxide separation from fuel gas mixture using the hydrate based gas separation process is evaluated. The kinetics of hydrate formation in the presence of 2.5 mol % propane as thermodynamic promoter was investigated at 4.5, 5.5, and 6.0 MPa and 274.2 K. Significantly higher gas consumption and water conversion to hydrate was achieved when PU foam was employed. PU foam as a porous medium can help convert 54% of water to hydrate in two hours of hydrate formation. In addition the induction times were very low (&amp;lt;3.67 min at 6.0 MPa). A normalized rate of hydrate formation of 64.48 (+/- 3.82) mol.min(-1).m(-3) was obtained at 6.0 MPa and 274.2 K. Based on a morphological study, the mechanism of hydrate formation from water dispersed in interstitial pore space of the porous medium is presented. Finally, we propose a four step operation of the hydrate based gas separation process to scale up.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">22</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">5.481
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Pre-combustion capture of carbon dioxide in a fixed bed reactor using the clathrate hydrate process</style></title><secondary-title><style face="normal" font="default" size="100%">Energy</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Clathrate hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas separation</style></keyword><keyword><style  face="normal" font="default" size="100%">Global warming</style></keyword><keyword><style  face="normal" font="default" size="100%">Pre-combustion</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">50</style></volume><pages><style face="normal" font="default" size="100%">364-373</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrate based gas separation (HBGS) process with silica sand and silica gel as contact medium was employed to capture CO2 from fuel gas mixture. Gas uptake measurement at three different pressures (7.5, 8.5 and 9.0 MPa) and 274.15 K were conducted for hydrate formation kinetics and overall conversion of water to hydrate, rate of hydrate formation were determined. Water conversion of up to 36% was achieved with silica sand bed compared to 13% conversion in the silica gel bed. Effect of driving force on the rate of hydrate formation and gas consumption was significant in silica sand bed whereas it was found to be insignificant in silica gel bed. Hydrate dissociation experiments by thermal stimulation (at constant pressure) alone and a combination of depressurization and thermal stimulation were carried out for complete recovery of the hydrated gas. A driving force of 23 K was found to be sufficient to recover all the hydrated gas within 1 h. This study indicates that silica sand can be an effective porous media for separation of CO2 from fuel gas when compared to silica gel. (C) 2012 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.159
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Ho, Chie Yin</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture</style></title><secondary-title><style face="normal" font="default" size="100%">Energy</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Clathrate process</style></keyword><keyword><style  face="normal" font="default" size="100%">Fixed bed reactor</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Pre-combustion capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Promoters</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">70</style></volume><pages><style face="normal" font="default" size="100%">664-673</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In this work, we present enhanced kinetics of hydrate formation for the clathrate process in the presence of two liquid promoters namely THF (tetrahydrofuran) and TBAB (tetra-n-butyl ammonium bromide) in a FBR (fixed bed reactor) for pre-combustion capture of CO2. Silica sand was used as a medium to capture CO2 from CO2/H-2 gas mixture by hydrate crystallisation. Experiments were performed at different temperatures (274.2 K and 279.2 K) and 6.0 MPa to determine the total gas uptake, induction time and rate of hydrate formation. The observed trends indicated that higher driving force resulted in higher gas consumption and significantly reduced induction time. For the same driving force, higher gas consumption and shorter induction time was achieved by THF as compared to TBAB. 5.53 mol% THF attained higher gas consumption than 1.0 mol% THF whereas 3.0 mol% TBAB attained lower gas consumption than 0.3 mol% TBAB. A highest gas uptake of 51.95 (+/- 5.183) mmol of gas/mol of water and a highest rate of 51.21(+/- 8.91) mol.min(-1).m(-3) were obtained for 5.53 mol% THF at 6.0 MPa and 279.2 K. Overall, this study indicated better hydrate formation kinetics with the use of THF in an FBR configuration for CO2 capture from a fuel gas mixture. (C) 2014 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;br&gt;&amp;nbsp;&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;5.00&lt;br&gt;&amp;nbsp;&lt;/p&gt;</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Datta, Stuti</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Impact of experimental pressure and temperature on semiclathrate hydrate formation for pre-combustion capture of CO2 using tetra-n-butyl ammonium nitrate</style></title><secondary-title><style face="normal" font="default" size="100%">Energy</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Clathrate process</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Semi-clathrates</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">SI</style></number><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">78</style></volume><pages><style face="normal" font="default" size="100%">458-464</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;TBANO(3) (tetra-n-butyl ammonium nitrate) is a promising liquid phase promoter for capturing CO2 via HBGS (hydrate based gas separation) technology. In this study, the impact of experimental pressure and temperature on formation of mixed CO2-H-2-TBANO(3) semiclathrate hydrate for the optimum 1.0 mol% TBANO(3) reported by Babu et al. [1] was investigated. Experimental pressures of 3.0, 4.5 and 6.0 MPa and temperatures of 274.2, 276.2 and 278.2 K were employed. Irrespective of the experimental pressure, shorter induction time was observed for experiments conducted at 274.2 K when compared to the experiments at other temperatures. At a given pressure, the total gas uptake increased with increase in experimental temperature. Similarly at a given temperature, the total gas uptake increases with an increase in pressure. Higher rate of hydrate formation was observed at experimental pressure of 6.0 MPa than at 3.0 and 4.5 MPa irrespective of the experimental temperature. The CO2 composition in hydrate was between 87.5 and 93.2 mol%. Finally, the gas consumption for 1.0 mol% TBANO(3) as promoter was much higher than other promoters of quaternary salts like tetra-n-butyl ammonium bromide and tetra-n-butyl ammonium fluoride at comparable concentration and driving force. (C) 2014 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">5.00
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>47</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Chin, Weng Inn</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors><secondary-authors><author><style face="normal" font="default" size="100%">Yan, J.</style></author><author><style face="normal" font="default" size="100%">Lee, D. J.</style></author><author><style face="normal" font="default" size="100%">Chou, S. K.</style></author><author><style face="normal" font="default" size="100%">Desideri, U.</style></author><author><style face="normal" font="default" size="100%">Li, H.</style></author></secondary-authors></contributors><titles><title><style face="normal" font="default" size="100%">Impact of pressure and temperature on tetra-n-butyl ammonium bromide semi-clathrate process for carbon dioxide capture</style></title><secondary-title><style face="normal" font="default" size="100%">International Conference on Applied Energy, ICAE2014</style></secondary-title><tertiary-title><style face="normal" font="default" size="100%">Energy Procedia</style></tertiary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Clathrate process</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas separation</style></keyword><keyword><style  face="normal" font="default" size="100%">Promoters</style></keyword><keyword><style  face="normal" font="default" size="100%">tetra-n-butyl ammonium bromide</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">Elsevier Science BV</style></publisher><pub-location><style face="normal" font="default" size="100%">Sara Burgerhartstraat 25, Po Box 211, 1000 AE Amsterdam, Netherlands</style></pub-location><volume><style face="normal" font="default" size="100%">61</style></volume><pages><style face="normal" font="default" size="100%">1780-1783</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The pre-combustion capture of CO2 in an IGCC power plant employing the hydrate based gas separation (HBGS) process is a novel method currently receiving attention around the world. Tetra-n-butyl ammonium bromide (TBAB) is a promoter that has been shown to improve the efficiency of hydrate formation. In this study, the effect of temperature and pressure on 0.3 mol% TBAB solution is investigated. The induction time for the experiments conducted at 6.0 MPa and 274.8 K was found to be lower, while nucleation became increasingly random as temperature is increased and pressure is reduced. Total gas uptake and normalized rate of hydrate formation (NR5) is also the highest for the experiments conducted at 6.0 MPa and 274.8 K. However, it was found that the hydrate phase CO2 composition remains relatively constant at both reduced temperatures and pressures. (C) 2014 The Authors. Published by Elsevier Ltd.&lt;/p&gt;</style></abstract><notes><style face="normal" font="default" size="100%">6th International Conference on Applied Energy (ICAE), Taipei, TAIWAN, MAY 30-JUN 02, 2014</style></notes></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Chin, Weng Inn</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Systematic evaluation of tetra-n-butyl ammonium bromide (TBAB) for carbon dioxide capture employing the clathrate process</style></title><secondary-title><style face="normal" font="default" size="100%">Industrial &amp; Engineering Chemistry Research</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">12</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">53</style></volume><pages><style face="normal" font="default" size="100%">4878-4887</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrate based gas separation (HBGS) process for the precombustion capture of CO2 from a fuel gas mixture is a novel method being investigated among the carbon capture and sequestration techniques to reduce CO2 emissions. The efficiency of the HGBS process can be improved by using promoters that reduce the formation pressure of mixed gas hydrates. In this study the effect of tetra-n-butyl ammonium bromide (TBAB) was systematically investigated at a constant temperature of 279.2 K and pressure of 6.0 MPa for different TBAB concentrations of 0.3, 1.0, 1.5, 2.0, and 3.0 mol %, respectively. The 0.3 mol % solutions had a relatively longer average induction time of 20.1 min but exhibited the highest total normalized gas uptake of 0.0104 (+/- 0.0004) mol of gas/mol of water and highest separation factor of 41.51 (+/- 6.391). On the other hand, the 1.0 mol % solution had very short average induction time (&amp;lt;0.5 min) and it had the highest hydrate growth rate of 60.8 (+/- 9.89) mol of gas. min(-1).m(-3), with the separation factor of 13.78 (+/- 3.30). Gas solubility measurements and microscopic images of the hydrate formation were also presented to provide greater insights into the effect of TBAB concentration on the gas uptake.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">12</style></issue><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">3.17</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Yao, Minghuang</style></author><author><style face="normal" font="default" size="100%">Datta, Stuti</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Thermodynamic and kinetic verification of tetra-n-butyl ammonium nitrate (TBANO(3)) as a promoter for the clathrate process applicable to precombustion carbon dioxide capture</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental Science &amp; Technology</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">6</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">48</style></volume><pages><style face="normal" font="default" size="100%">3550-3558</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In this study, tetra-n-butyl ammonium nitrate (TBANO(3)) is evaluated as a promoter for precombustion capture of CO2 via hydrate formation. New hydrate phase equilibrium data for fuel gas (CO2/H-2) mixture in presence of TBANO(3) of various concentrations of 0.5, 1.0, 2.0, 3.0, and 3.7 mol % was determined and presented. Heat of hydrate dissociation was calculated using Clausius-Clapeyron equation and as the concentration of TBANO(3) increases, the heat of hydrate dissociation also increases. Kinetic performance of TBANO(3) as a promoter at different concentrations was evaluated at 6.0 MPa and 274.2 K. Based on induction time, gas uptake, separation factor, hydrate phase CO2 composition, and rate of hydrate growth, 1.0 mol % TBANO(3) solution was found to be the optimum concentration at the experimental conditions of 6.0 MPa and 274.2 K for gas hydrate formation. A 93.0 mol % CO2 rich stream can be produced with a gas uptake of 0.0132 mol of gas/mol of water after one stage of hydrate formation in the presence of 1.0 mol % TBANO(3) solution. Solubility measurements and microscopic images of kinetic measurements provide further insights to understand the reason for 1.0 mol % TBANO(3) to be the optimum concentration.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">6</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">5.33</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Unusual behavior of propane as a co-guest during hydrate formation in silica sand: potential application to seawater desalination and carbon dioxide capture</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Engineering Science</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Desalination</style></keyword><keyword><style  face="normal" font="default" size="100%">Enhanced kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Propane hydrate: pre-combusuon capture</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">117</style></volume><pages><style face="normal" font="default" size="100%">342-351</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;We report an unusual behavior of hydrate formation in silica sand with gas mixtures containing propane as a co-guest. Based on morphology study we observed that propane as a co-guest has the ability to draw water dispersed in silica sand to the hydrate formation region and showed a tendency to result in drastic hydrate growth due to the migration of water molecules to the gas phase region. Hydrate nucleation occurred in the interstitial pore space between the silica sand particles and hydrate growth occurred in the gas phase above the silica sand bed and to sustain the hydrate growth, dispersed water was drawn towards the hydrate growth front. In addition, we elucidated the effect of sand bed height to maximize the growth rates utilizing this behavior that results in enhanced kinetics. We propose conceptual designs for utilizing this behavior of propane as a co-guest in sand for seawater desalination and an innovative approach to simultaneously capture carbon dioxide and desalinate seawater. (C) 2014 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.85
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Englezos, Peter</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture</style></title><secondary-title><style face="normal" font="default" size="100%">Energy</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Carbon dioxide capture</style></keyword><keyword><style  face="normal" font="default" size="100%">Clathrate process</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas separation</style></keyword><keyword><style  face="normal" font="default" size="100%">IGCC plants</style></keyword><keyword><style  face="normal" font="default" size="100%">Pre-combustion capture</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">85</style></volume><pages><style face="normal" font="default" size="100%">261-279</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In this work, a systematic review of the literature work done so far on the use of hydrate crystallization as a basis to develop data for the hydrate based gas separation (HBGS) process for the capture of CO2 from fuel gas mixtures is presented. Such a gas mixture may arise in integrated gasification combined cycle (IGCC) power plants. A thorough assessment of the thermodynamic, kinetic factors and economic aspects of the HBGS process and critical comments are presented. Compared with competing technologies, high CO2 capacity and the use of water as a solvent are key advantages for the HBGS process for CO2 capture. Furthermore, in this review, a snapshot of the current state-of-the-art is presented and further research and development opportunities and pathways for commercializing the HBGS process for pre-combustion capture of CO2 from IGCC power plants are discussed. (C) 2015 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">4.292</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Veluswamy, Hari Prakash</style></author><author><style face="normal" font="default" size="100%">Wong, Alison Jia Hui</style></author><author><style face="normal" font="default" size="100%">Babu, Ponnivalavan</style></author><author><style face="normal" font="default" size="100%">Kumar, Rajnish</style></author><author><style face="normal" font="default" size="100%">Kulprathipanja, Santi</style></author><author><style face="normal" font="default" size="100%">Rangsunvigit, Pramoch</style></author><author><style face="normal" font="default" size="100%">Linga, Praveen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Rapid methane hydrate formation to develop a cost effective large scale energy storage system</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Engineering Journal</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Energy storage</style></keyword><keyword><style  face="normal" font="default" size="100%">Enhanced kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">Gas hydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Natural gas storage</style></keyword><keyword><style  face="normal" font="default" size="100%">Tetrahydrofuran</style></keyword><keyword><style  face="normal" font="default" size="100%">Unstirred tank reactor</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE SA</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 564, 1001 LAUSANNE, SWITZERLAND</style></pub-location><volume><style face="normal" font="default" size="100%">290</style></volume><pages><style face="normal" font="default" size="100%">161-173</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Natural gas (NG) is the cleanest burning fossil fuel and its usage can significantly reduce CO2 emissions from power plants. With its widespread use, there is an ever increasing need to develop technologies to store NG on a large scale. NG storage via clathrate hydrates is the best option for a large scale storage system because of its non-explosive nature, mild storage conditions, high volumetric capacity and being an environmentally benign process. In this work, we demonstrate a new method to achieve rapid methane hydrate formation in an unstirred tank reactor configuration (UTR) at moderate temperature and pressure conditions employing tetrahydrofuran (THF) as a promoter. For the first time, THF is reported to act both as a thermodynamic and an excellent kinetic promoter for methane hydrate formation. We demonstrate a multi-scale experimental validation of our method to a volumetric sample scale-up factor of 120 and internal reactor diameter scale-up factor of 10. Further, new insights on the dissociation behavior of the hydrates are reported. There is a competitive edge for storing NG via clathrate hydrates compared to compressed natural gas storage both in terms of cost and safety. (C) 2016 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">5.31</style></custom4></record></records></xml>