<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ahire, Milind M.</style></author><author><style face="normal" font="default" size="100%">Pol, Mahesh D.</style></author><author><style face="normal" font="default" size="100%">Kavale, Dattatry S</style></author><author><style face="normal" font="default" size="100%">Gonnade, Rajesh G.</style></author><author><style face="normal" font="default" size="100%">Mhaske, Santosh B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Stereoselective construction of deoxy-cruciferane alkaloids by NHC-catalyzed intramolecular annulation of homoenolate with quinazolinone</style></title><secondary-title><style face="normal" font="default" size="100%">Organic &amp; Biomolecular Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">17</style></volume><pages><style face="normal" font="default" size="100%">7135-7139</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Chiral N-heterocyclic carbene (&lt;span class=&quot;hitHilite&quot;&gt;NHC)-catalyzed&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;intramolecular&lt;/span&gt; [3 + 2] &lt;span class=&quot;hitHilite&quot;&gt;annulation&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; enals &lt;span class=&quot;hitHilite&quot;&gt;with&lt;/span&gt; an unactivated imine moiety &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;quinazolinone&lt;/span&gt; via formal &lt;span class=&quot;hitHilite&quot;&gt;homoenolate&lt;/span&gt; cycloaddition has been demonstrated. It is an excellent approach &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;stereoselective&lt;/span&gt; syntheses &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;deoxy-cruciferane&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;alkaloids&lt;/span&gt; comprising a biologically important pyrroloindoline scaffold. Notably, this is the first report on the &lt;span class=&quot;hitHilite&quot;&gt;NHC-catalyzed&lt;/span&gt; asymmetric &lt;span class=&quot;hitHilite&quot;&gt;intramolecular&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;homoenolate&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;annulation&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;with&lt;/span&gt; cyclic N-acyl amidine.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">30</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;h1 class=&quot;page-head__title page-head__vcenter&quot;&gt;
	&lt;span class=&quot;page-head__context&quot;&gt;&lt;span class=&quot;no-wrap text--dark&quot;&gt;&lt;strong class=&quot;text--dark&quot;&gt;3.49&lt;/strong&gt;&lt;/span&gt; &lt;/span&gt;&lt;/h1&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Halder, Priyanka</style></author><author><style face="normal" font="default" size="100%">Pol, Mahesh D.</style></author><author><style face="normal" font="default" size="100%">Ahire, Milind M.</style></author><author><style face="normal" font="default" size="100%">Mhaske, Santosh B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Construction of unique SCF3-containing building blocks via allylic alkylation of Morita-Baylis-Hillman adducts</style></title><secondary-title><style face="normal" font="default" size="100%">Organic &amp; Biomolecular Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">18</style></volume><pages><style face="normal" font="default" size="100%">2085-2093</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Lewis base-catalyzed allylic alkylation of Morita-Baylis-Hillman adducts with alpha-SCF3 ketones has been demonstrated. The developed strategy provides efficient access to a series of highly functionalized scaffolds featuring trifluoromethanesufinyl motif on a stereogenic carbon.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">11</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;3.412&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Viveki, Amol B.</style></author><author><style face="normal" font="default" size="100%">Pol, Mahesh D.</style></author><author><style face="normal" font="default" size="100%">Halder, Priyanka</style></author><author><style face="normal" font="default" size="100%">Sonavane, Sameer R.</style></author><author><style face="normal" font="default" size="100%">Mhaske, Santosh B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Annulation of enals with carbamoylpropiolates via NHC-catalyzed enolate pathway: access to functionalized maleimides/iso-maleimides and synthesis of aspergillus FH-X-213</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Organic Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">86</style></volume><pages><style face="normal" font="default" size="100%">9466-9477</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Herein we report the N-heterocyclic carbene (NHC)-catalyzed [3 + 2] annulation of alpha,beta-unsaturated aldehydes with carbamoylpropiolates via an unusual enolate pathway leading to the construction of highly functionalized maleimides or isomaleimides. The electronic effect imposed by the alkyl/aryl group present on the amide nitrogen of carbamoylpropiolates plays a crucial role in the selective formation of these important five-membered heterocyclic building blocks. The developed protocol is mild and tolerates a wide range of substituents on both substrates. The application of this protocol in the synthesis of the antibacterial natural product Aspergillus FH-X-213 has also been demonstrated.</style></abstract><issue><style face="normal" font="default" size="100%">14</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.354</style></custom4></record></records></xml>