<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pagar, Nitin S.</style></author><author><style face="normal" font="default" size="100%">Deshpande, Raj M.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetics of hydroformylation of 1-decene using carbon-supported ossified HRh(CO)(TPPTS)(3) catalyst</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Chemical Kinetics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">1-decene</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydroformylation</style></keyword><keyword><style  face="normal" font="default" size="100%">kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">ossification</style></keyword><keyword><style  face="normal" font="default" size="100%">supported ossified</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">51</style></volume><pages><style face="normal" font="default" size="100%">112-122</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The kinetics of hydroformylation of 1-decene has been investigated using a carbon-supported ossified HRh(CO)(TPPTS)(3)/Ba catalyst in a temperature range of 343-363 K. The effect of concentration of 1-decene, catalyst loading, partial pressure of H-2 and CO, and stirring speed on the reaction rate has been investigated. A first-order dependence was observed for catalyst concentration and hydrogen partial pressure. The rate showed a typical case of substrate inhibition for high 1-decene concentration. The rate varied with a linear dependence on P-CO up to a CO partial pressure of 5-6 MPa in contrast to the general trends; for most of the rhodium-phosphine catalyzed hydroformylation reactions, severe inhibition of rate is observed with an increase in CO pressure. A rate equation has been proposed, which was found to be in good agreement with the observed rate data within the limit of experimental errors. The kinetic parameters and activation energy values have been reported.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">1.416</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pagar, Nitin S.</style></author><author><style face="normal" font="default" size="100%">Rajurkar, Kalpendra B.</style></author><author><style face="normal" font="default" size="100%">Deshpande, Raj M.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetics of hydroformylation of camphene using rhodium-phosphite catalyst</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Chemical Kinetics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">camphene</style></keyword><keyword><style  face="normal" font="default" size="100%">homogeneous</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydroformylation</style></keyword><keyword><style  face="normal" font="default" size="100%">kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">rhodium-phosphite</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">52</style></volume><pages><style face="normal" font="default" size="100%">485-495</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Kinetics of hydroformylation of camphene was investigated in the presence of [Rh(CO)(2)(acac)]/P(OPh)(3) catalyst in a temperature range of 363-383 K. The influence of parameters such as stirring speed, camphene, catalyst, ligand concentrations, and partial pressures of H-2 and CO on the activity and selectivity of the catalyst has been studied. The rate showed a first-order dependence with respect to catalyst and camphene concentrations. The effect of partial pressure of hydrogen showed fractional order dependence. The plots of rate versus excess ligand, that is, (P(OPh)(3)) concentration and rate versus CO partial pressure passed through maxima and showed typical substrate/ligand inhibited kinetics. An empirical rate equation has been proposed and found to be in good agreement with the observed rate data. The kinetic parameters and activation energy were also evaluated.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;1.531&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pagar, Nitin S.</style></author><author><style face="normal" font="default" size="100%">Deshpande, Raj M.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetics of 1-decene hydroformylation in an aqueous biphasic medium using a water-soluble Rh-sulfoxantphos catalyst in the presence of a cosolvent</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Chemical Kinetics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">1&amp;\#8208</style></keyword><keyword><style  face="normal" font="default" size="100%">aqueous&amp;\#8208</style></keyword><keyword><style  face="normal" font="default" size="100%">biphasic</style></keyword><keyword><style  face="normal" font="default" size="100%">cosolvent</style></keyword><keyword><style  face="normal" font="default" size="100%">decene</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydroformylation</style></keyword><keyword><style  face="normal" font="default" size="100%">kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">rh&amp;\#8208</style></keyword><keyword><style  face="normal" font="default" size="100%">sulfoxantphos</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">53</style></volume><pages><style face="normal" font="default" size="100%">333-344</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The kinetics of hydroformylation of 1-decene has been studied in an aqueous biphasic medium using a water-soluble Rh-sulfoxantphos catalyst in the presence of N-methyl pyrrolidone as a cosolvent at 383-403 K. The rate was found to be first order, with concentrations of catalyst and olefin and partial order, with concentrations of hydrogen in the liquid phase. The plot of rate versus excess ligand and CO concentrations passed through maxima, indicating negative order dependence at higher concentrations. These trends have been interpreted based on the established hydroformylation mechanism. High selectivity towards the linear aldehyde was maintained (n: iso ratio &amp;gt; 30). An empirical rate equation has been proposed which was found to be in good agreement with the observed rate data within the experimental error. The activation energy was evaluated to be 74.76 kJ/mol.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign (Early Access Date : 2020)&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">1.462
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tonde, Sunil S.</style></author><author><style face="normal" font="default" size="100%">Rajurkar, Kalpendra B.</style></author><author><style face="normal" font="default" size="100%">Pagar, Nitin S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetic investigation on palladium-catalyzed carbonylation of allyl alcohol</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Chemical Kinetics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">allyl alcohol</style></keyword><keyword><style  face="normal" font="default" size="100%">Carbonylation</style></keyword><keyword><style  face="normal" font="default" size="100%">halide promoters</style></keyword><keyword><style  face="normal" font="default" size="100%">kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">Mechanism</style></keyword><keyword><style  face="normal" font="default" size="100%">Palladium</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">57</style></volume><pages><style face="normal" font="default" size="100%">153-163</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Palladium-catalyzed carbonylation of allyl alcohol to 3-butenoic acid has been investigated. A significant effect of halide promoters, p-tolylsulfonic acid (TsOH), water, solvents, and PPh3 concentration activity and selectivity has been studied. Detailed kinetics of this reaction was investigated in a temperature range of 363-383 K. The influence of parameters such as stirring speed, allyl alcohol, catalyst, benzyltriethylammonium chloride (BTEAC), TsOH concentrations, and CO partial pressures on the activity and selectivity has been studied. An empirical rate equation was suggested and found to be fairly consistent with observed rate data. In addition, the activation energy and kinetic parameters were evaluated.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	1.5&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tonde, Sunil S.</style></author><author><style face="normal" font="default" size="100%">Rajurkar, Kalpendra B.</style></author><author><style face="normal" font="default" size="100%">Pagar, Nitin S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetics of palladium catalyzed methoxycarbonylation of vinyl acetate to methyl-2-acetoxypropionate for the synthesis of lactic acid</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Chemical Kinetics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Hydrolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">Lactic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Methoxycarbonylation</style></keyword><keyword><style  face="normal" font="default" size="100%">methyl lactate</style></keyword><keyword><style  face="normal" font="default" size="100%">methyl-2-acetoxypropionate</style></keyword><keyword><style  face="normal" font="default" size="100%">palladium catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">VAM</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">58</style></volume><pages><style face="normal" font="default" size="100%">627-636</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Lactic acid is crucial for food production and energy generation in body. It also has been a key monomer of poly lactic acid, biodegradable plastic. As methoxy carbonylation of vinyl acetate (VAM) produces methyl-2-acetoxypropionate, and methyl lactate as intermediates for lactic acid, its kinetic investigations are important to understand the reaction behavior. In this paper a study was conducted on the kinetics of methoxyarbonylation for vinyl acetate in a semi-batch slurry reactor across a temperature range of 363-383K, utilizing [PdCl2(PPh3)2] catalyst. The effect of catalyst, methanol, vinyl acetate monomer (VAM) concentration and partial pressure of carbon monoxide (CO) on the reactants and products concentration was investigated with respect to time. Catalytic methoxycarbonylation of VAM produces methyl acetoxy propionate which further forms methyl lactate and methyl acetate through consecutive reaction. Methyl acetoxy propionate and methyl lactate thus formed can be converted to lactic acid through hydrolysis. The methoxycarbonylation conditions produce byproducts dimethyl acetate and methyl acetate through parallel reaction. Based on the initial rate data of formations of lactic acid precursors through methoxycarbonylation and consecutive reaction byproducts through parallel reaction, and trend behavior of initial rates with concentrations of reactants, different empirical rate equations were evaluated. The integral concentration-time data was fitted to evaluate the kinetic parameters at various temperatures. General elimination method and thermodynamic principles were used to suggest an appropriate empirical rate equation as shown below.r1, r2, and r3 are rates of methoxycarbonylation reaction (methyl-2-acetoxypropionate formation), consecutive reaction (methyl lactate formation) and parallel reaction (dimethyl acetal formation) respectively. k1, k2, and k3 are equilibrium constants for the reactions r1, r2, and r3 respectively. KB and KC are equilibrium constants for VAM and methanol CA, CB, CC, CD and CW are concentration of dissolved CO in the liquid phase, VAM, methanol, methyl-2-acetoxypropionate and catalyst respectively. For catalyst and CO, the methoxycarbonylation reaction rate was observed to be first order, while for VAM and methanol, it was first order with a tendency to zero order. Energy of activation needed for the catalytic reaction was 81.62 kJ/mol. For a catalytic reaction, selectivity towards the required product is desirable. Kinetic investigations can be utilized to achieve maximum selectivity towards the desired products at optimum reaction rate. The proposed model suggests that 95%-97% selectivity towards the combined carbonylated products (methyl-2-acetoxypropionate and methyl lactate) can be achieved.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">9</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	1.7&lt;/p&gt;
</style></custom4></record></records></xml>