<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bangar, Pronnoy G.</style></author><author><style face="normal" font="default" size="100%">Jawalkar, Priyanka R.</style></author><author><style face="normal" font="default" size="100%">Dumbre, Swapnil</style></author><author><style face="normal" font="default" size="100%">Patil, Dharmaraj</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Silver sequestration of halides for the activation of Pd(OAc) 2 catalyzed Mizoroki-Heck reaction of 1,1 and 1,2 - Disubstituted alkenes: Ag Sequestration for Pd catalyzed Heck reaction- disubstituted alkenes</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Organometallic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">1</style></keyword><keyword><style  face="normal" font="default" size="100%">1-disubstituted alkenes</style></keyword><keyword><style  face="normal" font="default" size="100%">2-disubstituted alkenes</style></keyword><keyword><style  face="normal" font="default" size="100%">AgBF4</style></keyword><keyword><style  face="normal" font="default" size="100%">AgOAc</style></keyword><keyword><style  face="normal" font="default" size="100%">Mizoroki-Heck reaction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">32</style></volume><pages><style face="normal" font="default" size="100%">e4159</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">A ligand free catalytic system consisting of Pd(OAc)2 (cat) and stoichiometric quantities of silver salts, AgOAc or AgBF4, exhibit high efficiency in the Mizoroki-Heck arylation, transforming aryl iodides and 1,1 as well as 1,2 disubstituted alkenes into 1,1,2 – trisubstituted aryl alkenes in excellent yields in very short reaction times.</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.319</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bangar, Pronnoy G.</style></author><author><style face="normal" font="default" size="100%">Jawalkar, Priyanka R.</style></author><author><style face="normal" font="default" size="100%">Dumbre, Swapnil R.</style></author><author><style face="normal" font="default" size="100%">Raut, Pallavi K.</style></author><author><style face="normal" font="default" size="100%">Patil, Dharmaraj J.</style></author><author><style face="normal" font="default" size="100%">Tv, Neethu</style></author><author><style face="normal" font="default" size="100%">Sudhakaran, Shana</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Mizoroki-Heck reaction of 1,2-disubstituted aryl alkenes: variables of synthesis, solvent and ligand modulation of reactivity</style></title><secondary-title><style face="normal" font="default" size="100%">Synthetic Communications</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">12-Disubstituted aryl alkenes</style></keyword><keyword><style  face="normal" font="default" size="100%">400</style></keyword><keyword><style  face="normal" font="default" size="100%">ligand effect</style></keyword><keyword><style  face="normal" font="default" size="100%">Mizoroki-Heck reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">PEG 200</style></keyword><keyword><style  face="normal" font="default" size="100%">TBABr</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">50</style></volume><pages><style face="normal" font="default" size="100%">3796-3803</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Reaction of aryl iodides with 1,2-disubstituted aryl alkenes in the presence of TBABr/TBACl gave high yields of the Mizoroki-Heck product. Phosphine ligands were used for the modulation of reactivity and stereoselectivity, for the reaction of 4-iodoanisole with cinnamaldehyde. tert-Bu3P.HBF(4)gave the highest E:Z ratio of 1:0.08. The use of PEG-200 and PEG-400 as solvent could activate the reaction of aryl iodides with various 1,2-disubstituetd aryl alkenes.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">24</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;1.796&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Patil, Vijay P.</style></author><author><style face="normal" font="default" size="100%">Kashid, Abhijit A.</style></author><author><style face="normal" font="default" size="100%">Solanki, Bhanupratap S.</style></author><author><style face="normal" font="default" size="100%">Kharul, Ulhas K.</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bimetallic nano alloy architecture on a special polymer: Ni or Cu merged with Pd for the promotion of the Mizoroki-Heck reaction and the Suzuki-Miyaura coupling</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Chemical Sciences</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Bimetallic nano alloys</style></keyword><keyword><style  face="normal" font="default" size="100%">Cu-Pd-ABPBI</style></keyword><keyword><style  face="normal" font="default" size="100%">Mizoroki-Heck reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">Ni-Pd-ABPBI</style></keyword><keyword><style  face="normal" font="default" size="100%">Suzuki coupling</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">133</style></volume><pages><style face="normal" font="default" size="100%">8</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Novel Ni-Pd and Cu-Pd bimetallic nano alloys was designed and heterogenized on the highly robust ABPBI [poly(2,5-benzimidazole)] polymer in high yields using NaBH4 as reducing agent. These were versatile ligand free catalysts for the Mizoroki-Heck reaction and Suzuki-Miyaura coupling. The bimetallic Ni-Pd-ABPBI catalyst for the Mizoroki-Heck reaction of 4-iodo anisole could be recycled 5 times with high yields. Aryl bromides could also be activated for the Mizoroki-Heck reaction using Cu-Pd-ABPBI NP catalysts, with moderate yields. Graphic abstractSynopsis Novel bimetallic Ni-Pd and Cu-Pd nano alloys, heterogenized on the robust ABPBI [poly(2,5-benzimidazole)] polymer using NaBH4 as reducing agent, is described. These were versatile ligand free, noble metal conservative catalysts, for the Mizoroki-Heck reaction and the Suzuki-Miyaura coupling. Aryl bromides were activated for the Mizoroki-Heck reaction using the Cu-Pd-ABPBI catalyst.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Indian&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">1.573
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kashid, Abhijit A.</style></author><author><style face="normal" font="default" size="100%">Patil, Dharmaraj J.</style></author><author><style face="normal" font="default" size="100%">Mali, Ramling D.</style></author><author><style face="normal" font="default" size="100%">Patil, Vijay P.</style></author><author><style face="normal" font="default" size="100%">Neethu, T. V.</style></author><author><style face="normal" font="default" size="100%">Meroliya, Heena K.</style></author><author><style face="normal" font="default" size="100%">Waghmode, Shobha A.</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bimetallic Ni-Pd synergism-mixed metal catalysis of the mizoroki-heck reaction and the suzuki-miyaura coupling of aryl bromides</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Letters</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Bimetallic catalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Mizoroki-Heck</style></keyword><keyword><style  face="normal" font="default" size="100%">Nickel complexes</style></keyword><keyword><style  face="normal" font="default" size="100%">Pd(OAc)2</style></keyword><keyword><style  face="normal" font="default" size="100%">Suzuki coupling</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">151</style></volume><pages><style face="normal" font="default" size="100%">353-358</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling. [GRAPHICS] .&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">3.186
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kashid, Abhijit A.</style></author><author><style face="normal" font="default" size="100%">Patil, Dharmaraj J.</style></author><author><style face="normal" font="default" size="100%">Mali, Ramling D.</style></author><author><style face="normal" font="default" size="100%">Patil, Vijay P.</style></author><author><style face="normal" font="default" size="100%">Neethu, T. V.</style></author><author><style face="normal" font="default" size="100%">Meroliya, Heena K.</style></author><author><style face="normal" font="default" size="100%">Waghmode, Shobha A.</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bimetallic Ni–Pd synergism—mixed metal catalysis of the mizoroki-heck reaction and the suzuki–miyaura coupling of aryl bromides</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Letters</style></secondary-title><short-title><style face="normal" font="default" size="100%">Catalysis Letters</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">151</style></volume><pages><style face="normal" font="default" size="100%">353 - 358</style></pages><isbn><style face="normal" font="default" size="100%">1572-879X</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling.</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">3.186</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bangar, Pronnoy G.</style></author><author><style face="normal" font="default" size="100%">Nahide, Pradip D.</style></author><author><style face="normal" font="default" size="100%">Meroliya, Heena K.</style></author><author><style face="normal" font="default" size="100%">Waghmode, Shobha A.</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Oxime ligands for Pd catalysis of the mizoroki-heck reaction, suzuki-miyaura coupling &amp; annulation reactions</style></title><secondary-title><style face="normal" font="default" size="100%">Synthetic Communications</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Isocoumarin</style></keyword><keyword><style  face="normal" font="default" size="100%">LaRock annulation</style></keyword><keyword><style  face="normal" font="default" size="100%">Mizoroki-Heck reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">oximes</style></keyword><keyword><style  face="normal" font="default" size="100%">Suzuki coupling</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">51</style></volume><pages><style face="normal" font="default" size="100%">308-316</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Monodentate and bidentate chelating oximes are readily available ligands for the Pd catalysis of the Mizoroki-Heck reaction and the Suzuki coupling. High yields were obtained in the Suzuki coupling in aqueous dioxane with TBABr as additive. The oximes can be easily synthesized from the corresponding ketones or aldehydes and thus provide a very large number of nitrogen-based ligands. They have the advantage of not undergoing oxidative degradation, common for phosphine ligands. Chelating oximes with Pd(OAc)(2), activate aryl iodides to give high yields of the substitution products in the Mizoroki-Heck reactions as well as the Suzuki coupling. Acetophenone oxime ligand with Pd(OAc)(2), catalyzed the reaction of aryl iodides with 1,2-disubstituted alkenes in moderate to high yields. As a test example, the LaRock indole annulation and synthesis of isocoumarin were achieved with acetophenone oxime ligand and Pd(OAc)(2)in high yields.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">2.007
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bangar, Pronnoy G.</style></author><author><style face="normal" font="default" size="100%">Nahide, Pradip D.</style></author><author><style face="normal" font="default" size="100%">Meroliya, Heena K.</style></author><author><style face="normal" font="default" size="100%">Waghmode, Shobha A.</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Oxime ligands for Pd catalysis of the mizoroki–heck reaction, Suzuki–Miyaura coupling &amp; annulation reactions</style></title><secondary-title><style face="normal" font="default" size="100%">Synthetic Communications</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">51</style></volume><pages><style face="normal" font="default" size="100%">308-316</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">AbstractMonodentate and bidentate chelating oximes are readily available ligands for the Pd catalysis of the Mizoroki–Heck reaction and the Suzuki coupling. High yields were obtained in the Suzuki coupling in aqueous dioxane with TBABr as additive. The oximes can be easily synthesized from the corresponding ketones or aldehydes and thus provide a very large number of nitrogen-based ligands. They have the advantage of not undergoing oxidative degradation, common for phosphine ligands. Chelating oximes with Pd(OAc)2, activate aryl iodides to give high yields of the substitution products in the Mizoroki–Heck reactions as well as the Suzuki coupling. Acetophenone oxime ligand with Pd(OAc)2, catalyzed the reaction of aryl iodides with 1,2-disubstituted alkenes in moderate to high yields. As a test example, the LaRock indole annulation and synthesis of isocoumarin were achieved with acetophenone oxime ligand and Pd(OAc)2 in high yields.</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.007</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Raut, Pallavi K.</style></author><author><style face="normal" font="default" size="100%">Meroliya, Heena K.</style></author><author><style face="normal" font="default" size="100%">Dumbre, Swapnil R.</style></author><author><style face="normal" font="default" size="100%">Patil, Vaishali N.</style></author><author><style face="normal" font="default" size="100%">Solanki, Bhanupratap S.</style></author><author><style face="normal" font="default" size="100%">Waghmode, Shobha A.</style></author><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bimetallic quantum dots (Cu-Pd, Ni-Pd) catalyzed reaction of bromo arenes with alkenes and aryl boronic acids</style></title><secondary-title><style face="normal" font="default" size="100%">Indian Journal of Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Aryl bromides</style></keyword><keyword><style  face="normal" font="default" size="100%">Bimetallic QDs catalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Cu-Pd</style></keyword><keyword><style  face="normal" font="default" size="100%">Mizoroki-Heck</style></keyword><keyword><style  face="normal" font="default" size="100%">Ni-Pd</style></keyword><keyword><style  face="normal" font="default" size="100%">Suzuki coupling</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">62</style></volume><pages><style face="normal" font="default" size="100%">843-848</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Bimetallic quantum dots (Cu-Pd and Ni-Pd) are active ligand-free catalysts for the alkenylation and arylation of aryl bromides. The catalysts are easy to synthesize by benign green protocols and characterized by various techniques. The bimetallic QD catalysts synthesized thus are superior to Pd(OAc)2 or other Pd NP catalysis of alkenylation reactions of aryl bromides with similar E-selectivity. The reaction of aryl bromide with aryl boronic acid is facile with high yields.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">8</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Indian&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	NA&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Iyer, Suresh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Oxime ligands: organometallic synthesis and catalysis</style></title><secondary-title><style face="normal" font="default" size="100%">SYNTHETIC COMMUNICATIONS</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">cobaloxime</style></keyword><keyword><style  face="normal" font="default" size="100%">Cross-coupling</style></keyword><keyword><style  face="normal" font="default" size="100%">oxime palladacycles</style></keyword><keyword><style  face="normal" font="default" size="100%">oximes</style></keyword><keyword><style  face="normal" font="default" size="100%">radical cyclization</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">54</style></volume><pages><style face="normal" font="default" size="100%">417-459</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Ligands are at the heart of coordination chemistry. They conjure the magic of transition metals expressed in organometallic catalysis. Phosphine or P-ligands have found vast utility in transition metal chemistry, though demanding tedious synthesis. Several N, S-based ligands also find application in organometallic chemistry. Oximes are easily derived from aldehydes and ketones by simple reactions with hydroxylamine. Thus, an extensive library of oximes is available with different structural and electronic variations essential for coordination chemistry and catalysis. Several compounds with complex structural features, unavailable for phosphorous ligands, can be readily converted into active oxime ligands in a single derivatization step. Oxime ligands and metal complexes are applied in synthesizing diverse organic molecules and thus versatile ligands in organotransition metal chemistry.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">6</style></issue><work-type><style face="normal" font="default" size="100%">Review</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	2.1&lt;/p&gt;
</style></custom4></record></records></xml>