<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Awasthi, Amardeep</style></author><author><style face="normal" font="default" size="100%">Mukherjee, Anagh</style></author><author><style face="normal" font="default" size="100%">Singh, Mandeep</style></author><author><style face="normal" font="default" size="100%">Rathee, Garima</style></author><author><style face="normal" font="default" size="100%">Vanka, Kumar</style></author><author><style face="normal" font="default" size="100%">Chandra, Ramesh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Highly efficient chemoselective N-tert butoxycarbonylation of aliphatic/aromatic/heterocyclic amines using diphenylglycoluril as organocatalyst</style></title><secondary-title><style face="normal" font="default" size="100%">Tetrahedron</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">DFT studies</style></keyword><keyword><style  face="normal" font="default" size="100%">Diphenylglycouril</style></keyword><keyword><style  face="normal" font="default" size="100%">N-tert butoxycarbonylation</style></keyword><keyword><style  face="normal" font="default" size="100%">organocatalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">Proton shuttle mechanism</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">76</style></volume><pages><style face="normal" font="default" size="100%">131223</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;An efficient approach for the Chemoselective N-tert-butoxycarbonylation of a variety of amines using diphenylglycoluril as organocatalyst has been described. For the first time, a plausible mechanism for the N-tert-butoxycarbonylation has been proposed using density functional theory (DFT) calculations supported by NMR studies. The reusability of the organocatalyst and observation of the desired N-Boc protected amines being formed without the formation of side products like urea, oxazolidinone, isocyanate, and N, N-di-Boc derivatives makes the present protocol desirable. (C) 2020 Elsevier Ltd. All rights reserved.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">23</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;2.233&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Agrawal, Nisha K.</style></author><author><style face="normal" font="default" size="100%">Gayathridevi, S.</style></author><author><style face="normal" font="default" size="100%">Dash, Soumya R.</style></author><author><style face="normal" font="default" size="100%">Vanka, Kumar</style></author><author><style face="normal" font="default" size="100%">Jagirdar, Balaji R.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">H-atom site exchange in an iridium trans-dihydrogen/hydride complex, trans-[Ir(H)(?2-H2)(iPr)4(POCOP)(DMAP)]+</style></title><secondary-title><style face="normal" font="default" size="100%">Dalton Transactions</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">52</style></volume><pages><style face="normal" font="default" size="100%">13858-13863</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Treatment of trans-[Ir(H)(N)(2)((iPr)4)(POCOP)(DMAP)][BAr4f] (2) with H-2 (1 bar) under ambient conditions (298 K) results in the formation of a trans-[Ir(H)(?(2)-H-2)((iPr)4)(POCOP)(DMAP)][BAr4f] (3) complex. Complex 3 exhibits H-atom site exchange between the bound H-2 and the hydride ligands which are mutually trans to one another. A plausible mechanism of this exchange involves metal-ligand cooperativity as studied by computations.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">39</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	4&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pradhan, Mitarani</style></author><author><style face="normal" font="default" size="100%">Surati, Zeel Y.</style></author><author><style face="normal" font="default" size="100%">Pal, Apurba Kumar</style></author><author><style face="normal" font="default" size="100%">Vanka, Kumar</style></author><author><style face="normal" font="default" size="100%">Jagirdar, Balaji R.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Heterolytic cleavage of the B–H bond in H3B·L (L = THF, NMe2H) by an electrophilic Ir(iii) pincer complex [Ir(H)(PMe3)(tBu4POCOP)][BAr F4]</style></title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">55</style></volume><pages><style face="normal" font="default" size="100%">476-491</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;div class=&quot;abstract author&quot; id=&quot;aep-abstract-id6&quot; style=&quot;box-sizing: border-box; margin: 0px 0px 8px; padding: 0px; color: rgb(31, 31, 31); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, Times, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif, sans-serif; font-size: 16px;&quot;&gt;
	&lt;div id=&quot;aep-abstract-sec-id7&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px;&quot;&gt;
		&lt;div class=&quot;u-margin-s-bottom&quot; style=&quot;box-sizing: border-box; margin-top: 0px; margin-right: 0px; margin-bottom: 16px !important; margin-left: 0px; padding: 0px;&quot;&gt;
			&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;Six- and five-coordinate iridium complexes, [Ir(H)Cl(PMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;)(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP)] (&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;) (&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP = κ&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-C&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;6&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-2,6-(OP&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;Bu&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;) and [Ir(H)(PMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;)(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP)][BAr&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;F&lt;/span&gt;&lt;/small&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;] (&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;), respectively, have been synthesized and characterized. The reactivity of the electrophilic 16-electron iridium(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;III&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;) complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;with H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;, H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·THF, H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;H, and H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;was investigated. The reaction of complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;with H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;resulted in the formation of&amp;nbsp;&lt;/span&gt;&lt;em style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;trans&lt;/em&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-[Ir(H)(η&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;)(PMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;)(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP)][BAr&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;F&lt;/span&gt;&lt;/small&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;] complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;5&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;. Complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;was found to activate the B–H bonds in H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·THF and H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;H (DMAB) in a heterolytic fashion. The reaction of complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;with H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·THF at 298 K afforded&amp;nbsp;&lt;/span&gt;&lt;em style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;trans&lt;/em&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-[Ir(H)&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;PMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP)] complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;6&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;and a boronium compound, [H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B(THF)&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;][BAr&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;F&lt;/span&gt;&lt;/small&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;]. Monitoring the reaction from 179 to 298 K by NMR spectroscopy revealed the formation of a σ-borane intermediate,&amp;nbsp;&lt;/span&gt;&lt;em style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;trans&lt;/em&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-[Ir(H)(η&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;1&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-HBH&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;·THF)PMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP)][BAr&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;F&lt;/span&gt;&lt;/small&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;] (&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3a-Int&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;),&amp;nbsp;&lt;/span&gt;&lt;em style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;en route&lt;/em&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;to the final products observed at 298 K. The formation of this intermediate species was also investigated by density functional theory (DFT) calculations. The reaction of complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;with H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;H at 298 K yielded a mixture of complexes&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;and&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;5&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;and a cyclic diborazane [H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;BNMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;]&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;. The reaction was found to proceed&amp;nbsp;&lt;/span&gt;&lt;em style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;via&lt;/em&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;intermediates, a σ-borane complex,&amp;nbsp;&lt;/span&gt;&lt;em style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;trans&lt;/em&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-[Ir(H)(η&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;1&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;-HBH&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;·NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;H)PMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;(&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&lt;em&gt;t&lt;/em&gt;Bu4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;POCOP)][BAr&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;F&lt;/span&gt;&lt;/small&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;] (&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3b&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;), complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;6&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;, [(NHMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;BH&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;][BAr&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;F&lt;/span&gt;&lt;/small&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;4&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;], and H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B&lt;/span&gt;&lt;img alt=&quot;[double bond, length as m-dash]&quot; border=&quot;0&quot; src=&quot;https://www.rsc.org/images/entities/char_e001.gif&quot; style=&quot;border: none; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot; /&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;2&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;. Complex&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;font-weight: 700; color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;3&lt;/span&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&amp;nbsp;exhibited no reactivity with H&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;B·NMe&lt;/span&gt;&lt;small style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;3&lt;/span&gt;&lt;/small&gt;&lt;span style=&quot;color: rgba(0, 0, 0, 0.79); font-family: &amp;quot;Source Sans Pro&amp;quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif;&quot;&gt;.&lt;/span&gt;&lt;/div&gt;
	&lt;/div&gt;
&lt;/div&gt;
&lt;p&gt;
	&amp;nbsp;&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	3.3&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ajithkumar, V. S.</style></author><author><style face="normal" font="default" size="100%">Bisai, Milan Kumar</style></author><author><style face="normal" font="default" size="100%">Ghanwat, Pratiksha B.</style></author><author><style face="normal" font="default" size="100%">Raj, K. Vipin</style></author><author><style face="normal" font="default" size="100%">Singh, Geetika</style></author><author><style face="normal" font="default" size="100%">Vanka, Kumar</style></author><author><style face="normal" font="default" size="100%">Sen, Sakya S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hypersilylsilylene-supported Ni(0) toluene and Ni(II) complexes with catalytic application</style></title><secondary-title><style face="normal" font="default" size="100%">Organometallics</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">44</style></volume><pages><style face="normal" font="default" size="100%">2646-2653</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	The reaction of Ni(COD)2 with [PhC(NtBu)2SiSi(SiMe3)3] (1) in toluene results in the formation of an 18-electron silylene-Ni(0) toluene complex (2). The analogous reaction with 1,3-DFB instead of toluene affords the C-H activation followed by ring walking leading to the allylic cyclooctene adduct, the (eta 3-C8H13)Ni(II) complex (3). DFT calculations were carried out to elucidate the mechanism as well as to gain insight into why 1,3-DFB undergoes C-H bond activation instead of C-F bond activation. The use of NiCl2DME permits access to 16-electron (tetrylene)2NiCl2 (Si(4) and Ge(5)) species, and 4 was later used as a catalyst for the C-N coupling reaction.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">22</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	2.7&lt;/p&gt;
</style></custom4></record></records></xml>