<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Lee, Yeol-Lim</style></author><author><style face="normal" font="default" size="100%">Jha, Ajay</style></author><author><style face="normal" font="default" size="100%">Jang, Won-Jun</style></author><author><style face="normal" font="default" size="100%">Shim, Jae-Oh</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Jeon, Byong-Hun</style></author><author><style face="normal" font="default" size="100%">Bae, Jong Wook</style></author><author><style face="normal" font="default" size="100%">Roh, Hyun-Seog</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Effect of alkali and alkaline earth metal on Co/CeO2 catalyst for the water gas shift reaction of waste derived synthesis gas</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Catalysis A-General</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Alkaline earth metal</style></keyword><keyword><style  face="normal" font="default" size="100%">Co/CeO2</style></keyword><keyword><style  face="normal" font="default" size="100%">High temperature water-gas shift</style></keyword><keyword><style  face="normal" font="default" size="100%">Sintering resistance</style></keyword><keyword><style  face="normal" font="default" size="100%">stability</style></keyword><keyword><style  face="normal" font="default" size="100%">Waste derived synthesis gas</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2018</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">551</style></volume><pages><style face="normal" font="default" size="100%">63-70</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;We prepared a series of alkali (Na and K) and alkaline earth metal (Ca and Ba) promoted Co/CeO2 catalysts to investigate the effect of the promoter on the catalytic performance of the catalyst in the high-temperature water gas shift (WGS) reaction of waste derived synthesis gas. Interestingly, alkali metal promoted catalysts deactivated rapidly compared to alkaline earth metal promoted catalysts. Alkaline earth metal promoted catalysts showed relatively higher stability (&amp;gt;50 h) even at a very high gas hourly space velocity of 143,000 h(-1). X-ray diffraction (XRD) and transmission electron microscopy (TEM) results reveal that the higher stability of the alkaline earth metal promoted catalysts was due to the strong resistance to sintering, showing a relatively small crystallite size of metallic cobalt compared to the alkali metal promoted catalysts after WGS reaction.&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.339</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Na, Hyun-Suk</style></author><author><style face="normal" font="default" size="100%">Shim, Jae-Oh</style></author><author><style face="normal" font="default" size="100%">Jang, Won-Jun</style></author><author><style face="normal" font="default" size="100%">Jeon, Kyung-Won</style></author><author><style face="normal" font="default" size="100%">Kim, Hak-Min</style></author><author><style face="normal" font="default" size="100%">Lee, Yeol-Lim</style></author><author><style face="normal" font="default" size="100%">Lee, Da-We</style></author><author><style face="normal" font="default" size="100%">Yoo, Seong-Yeun</style></author><author><style face="normal" font="default" size="100%">Bae, Jong Wook</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Roh, Hyun-Seog</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Effect of titration time on the catalytic performance of Cu/CeO2 catalysts for water-gas shift reaction</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Today</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2018</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">309</style></volume><pages><style face="normal" font="default" size="100%">83-88</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">We herein report the preparation of ceria (CeO2) via a simple precipitation method for use as a catalyst support in the water-gas shift (WGS) reaction. More specifically, we optimized the titration time required to obtain highly active CeO2-supported catalysts for the WGS reaction. As such, Cu was employed as the active metal coupled with the CeO2 support. Notably, the CeO2-0 supported Cu catalyst (where the precipitant was immediately injected into a cerium nitrate solution) exhibited the highest CO conversion at a gas hourly space velocity of 36,050 h(-1). This high catalytic activity of the Cu/CeO2-0 catalyst was mainly due to its high Brunauer-Emmett-Teller (BET) surface area, enhanced Cu dispersion, high number of oxygen vacancies, and enhanced reducibility.</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.636</style></custom4></record></records></xml>