<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singh, Sandeep K.</style></author><author><style face="normal" font="default" size="100%">Srivastava, Ashish Kumar</style></author><author><style face="normal" font="default" size="100%">Srivastava, Krishna</style></author><author><style face="normal" font="default" size="100%">Banerjee, Rahul</style></author><author><style face="normal" font="default" size="100%">Prasad, Jagdish</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synthesis, characterization and electrochemical investigations of mixed-ligand copper(II)-organic supramolecular frameworks</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Molecular Structure</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">2 '-bipyridine</style></keyword><keyword><style  face="normal" font="default" size="100%">3</style></keyword><keyword><style  face="normal" font="default" size="100%">5</style></keyword><keyword><style  face="normal" font="default" size="100%">5 '-dimethyl-2</style></keyword><keyword><style  face="normal" font="default" size="100%">5-Tricarboxylic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Benzene-1</style></keyword><keyword><style  face="normal" font="default" size="100%">classification</style></keyword><keyword><style  face="normal" font="default" size="100%">Co-ordination-Compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">Crystal-structures</style></keyword><keyword><style  face="normal" font="default" size="100%">cyclic voltammetry</style></keyword><keyword><style  face="normal" font="default" size="100%">magnetic properties</style></keyword><keyword><style  face="normal" font="default" size="100%">metal organic framework</style></keyword><keyword><style  face="normal" font="default" size="100%">Mixed-ligand complex</style></keyword><keyword><style  face="normal" font="default" size="100%">pi-pi stacking interaction</style></keyword><keyword><style  face="normal" font="default" size="100%">Polymers</style></keyword><keyword><style  face="normal" font="default" size="100%">Secondery Building Unit</style></keyword><keyword><style  face="normal" font="default" size="100%">Structural data</style></keyword><keyword><style  face="normal" font="default" size="100%">Supramolecular framework</style></keyword><keyword><style  face="normal" font="default" size="100%">Ternare Komplexe</style></keyword><keyword><style  face="normal" font="default" size="100%">X-ray diffraction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">1147</style></volume><pages><style face="normal" font="default" size="100%">549-557</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span style=&quot;color: rgb(51, 51, 51); font-family: arial, helvetica, sans-serif; font-size: 13px; background-color: rgb(248, 248, 248);&quot;&gt;Two mixed-ligand copper(II)-organic coordination compounds with 5,5'-dimethyl-2,2'-bipyridine (5,5'-Me(2)bpy) as a primary ligand while aliphatic malonate (Hmal) and aromatic 2-hydroxynicotinate (2-OHNA) as secondary ligands, were synthesized. These complexes are formulated as: [Cu(Hmal)(5,5'-Me(2)bPY)(H2O)](ClO4) 1 and [Cu-2(2-OHNA)(2)(5,5'-Me(2)bpy)(2)(NO3)KNO3) 2. These two complexes were structurally characterized by single crystal X-ray diffraction analysis. Characterization was further supported by powder X-ray diffraction analysis, elemental analyses, FT-IR, FAB-MASS and TGA, DSC studies. Cyclic voltammetric and UV-visible spectral studies of these two complexes have also been done. The electrochemical studies of complex 1 in DMSO and DMF have shown that this complex undergoes quasi reversible diffusion-controlled one-electron transfer reaction without any chemical complication while complex 2 in DMSO undergoes quasi-reversible diffusion-controlled one electron transfer reaction, following EC mechanism. The electrochemical behaviour of complex 2 in DMF is complicated probably due to presence of more than one species in solution phase. (C) 2017 Elsevier B.V. All rights reserved.&lt;/span&gt;&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">1.78</style></custom4></record></records></xml>