<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gupta, Kriti</style></author><author><style face="normal" font="default" size="100%">Dadwal, Arun</style></author><author><style face="normal" font="default" size="100%">Rana, Shammi</style></author><author><style face="normal" font="default" size="100%">Jha, Plawan Kumar</style></author><author><style face="normal" font="default" size="100%">Jain, Anil</style></author><author><style face="normal" font="default" size="100%">Yusuf, S. M.</style></author><author><style face="normal" font="default" size="100%">Joy, Pattayil A.</style></author><author><style face="normal" font="default" size="100%">Ballav, Nirmalya</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Metamagnetism in nanosheets of Co-II-MOF with T-N at 26 K and a giant hysteretic effect at 5 K</style></title><secondary-title><style face="normal" font="default" size="100%">Inorganic Chemistry </style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2018</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">57</style></volume><pages><style face="normal" font="default" size="100%">15044-15047</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Herein, we have synthesized at room-temperature two-dimensional nanosheets of a MOF comprised of cobalt(II) ion with benzenedicarboxylic acid ligand, which exhibited unusual magnetic properties. Direct-current magnetic susceptibility revealed an anti-ferromagnetic (AFM) transition at 26 K (Neel temperature, T-N) followed by a canting of the spin moments along with the concomitant appearance of a sigmoidal-shaped magnetization versus field (M-H) curve at 15 K. Such a canted AFM ordering led to nonzero remnant magnetization with a remarkably high coercive field of similar to 10 kOe at 5 K. Metamagnetism was further: substantiated by the alternating-current magnetic susceptibility measurements.</style></abstract><issue><style face="normal" font="default" size="100%">24</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.700</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>10</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gupta, Kriti</style></author><author><style face="normal" font="default" size="100%">Dadwal, Arun</style></author><author><style face="normal" font="default" size="100%">Joy, Pattayil</style></author><author><style face="normal" font="default" size="100%">Ballav, Nirmalya</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Magnetism in bimetallic NiII-CoII coordination polymer</style></title><secondary-title><style face="normal" font="default" size="100%">AIP Conference Proceedings</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">American Institute of Physics Inc.</style></publisher><volume><style face="normal" font="default" size="100%">2265</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span style=&quot;font-size:14px;&quot;&gt;&lt;span style=&quot;font-family:georgia,serif;&quot;&gt;&lt;span style=&quot;font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;Co-BDC ([Co&lt;/span&gt;&lt;span style=&quot;line-height: 0; position: relative; bottom: -0.25em; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;(OH)&lt;/span&gt;&lt;span style=&quot;line-height: 0; position: relative; bottom: -0.25em; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;BDC], H&lt;/span&gt;&lt;span style=&quot;line-height: 0; position: relative; bottom: -0.25em; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;BDC = 1,4-benzenedicarboxylic acid) is known to possess metamagnetism originating from the antiparallel spins and high magneto crystalline anisotropy of Co(II).&lt;/span&gt;&lt;span style=&quot;line-height: 0; position: relative; top: -0.5em; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;1&lt;/span&gt;&lt;span style=&quot;font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;&amp;nbsp;Herein, we have introduced a bimetallic concept by incorporating Ni(II) along with Co(II) in the same coordination polymer to modulate the magneto crystalline anisotropy in the lattice which in turn, affects the overall magnetic response of the coordination polymer. The Curie-Weiss equation fit suggested antiparallel arrangement of the spins (θ ≈ -62.5 K) of Ni(II) and Co(II) arranged in alternate fashion. The cusp in magnetization was observed at 7 K (T&lt;/span&gt;&lt;span style=&quot;line-height: 0; position: relative; bottom: -0.25em; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;c&lt;/span&gt;&lt;span style=&quot;font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;&quot;&gt;) with a significant coercive field of ∼750 Oe at 5 K.&lt;/span&gt;&lt;/span&gt;&lt;/span&gt;&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;NA&lt;/p&gt;</style></custom4></record></records></xml>