<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sekhar, Anandakumari Chandrasekharan Sunil</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Gold incorporated mesoporous silica thin film model surface as a robust SERS and catalytically active substrate</style></title><secondary-title><style face="normal" font="default" size="100%">Molecules</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">gold nanoparticles</style></keyword><keyword><style  face="normal" font="default" size="100%">model catalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">SERS</style></keyword><keyword><style  face="normal" font="default" size="100%">Thin films</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">5</style></number><publisher><style face="normal" font="default" size="100%">MDPI AG</style></publisher><pub-location><style face="normal" font="default" size="100%">ST ALBAN-ANLAGE 66, CH-4052 BASEL, SWITZERLAND</style></pub-location><volume><style face="normal" font="default" size="100%">21</style></volume><pages><style face="normal" font="default" size="100%">667</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Ultra-small gold nanoparticles incorporated in mesoporous silica thin films with accessible pore channels perpendicular to the substrate are prepared by a modified sol-gel method. The simple and easy spin coating technique is applied here to make homogeneous thin films. The surface characterization using FESEM shows crack-free films with a perpendicular pore arrangement. The applicability of these thin films as catalysts as well as a robust SERS active substrate for model catalysis study is tested. Compared to bare silica film our gold incorporated silica, GSM-23F gave an enhancement factor of 10(3) for RhB with a laser source 633 nm. The reduction reaction of p-nitrophenol with sodium borohydride from our thin films shows a decrease in peak intensity corresponding to -NO2 group as time proceeds, confirming the catalytic activity. Such model surfaces can potentially bridge the material gap between a real catalytic system and surface science studies.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">2.465</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bhosale, Reshma</style></author><author><style face="normal" font="default" size="100%">Jain, Srashti</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Kumar, Santosh</style></author><author><style face="normal" font="default" size="100%">Ogale, Satishchandra</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Direct Z-scheme g-C3N4/FeWO4 nanocomposite for enhanced and selective photocatalytic CO2 reduction under visible light</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">C3N4</style></keyword><keyword><style  face="normal" font="default" size="100%">CO2 reduction</style></keyword><keyword><style  face="normal" font="default" size="100%">FeWO4</style></keyword><keyword><style  face="normal" font="default" size="100%">Photocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">solar fuels</style></keyword><keyword><style  face="normal" font="default" size="100%">Z-scheme</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">11</style></volume><pages><style face="normal" font="default" size="100%">6174-6183</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Photocatalytic reduction of CO2 to renewable solar fuels is considered to be a promising strategy to simultaneously solve both global warming and energy crises. However, development of a superior photocatalytic system with high product selectivity for CO2 reduction under solar light is the prime requisite. Herein, a series of nature-inspired Z-scheme g C3N4/FeWO4 composites are prepared for higher performance and selective CO2 reduction to CO as solar fuel under solar light. The novel direct Z-scheme coupling of the visible light-active FeWO4 nanoparticles with C3N4 nanosheets is seen to exhibit excellent performance for CO production with a rate of 6 mu mol/g/h at an ambient temperature, almost 6 times higher compared to pristine C3N4 and 15 times higher than pristine FeWO4. More importantly, selectivity for CO is 100% over other carbon products from CO, reduction and more than 90% over. H-2 products from water splitting. Our results clearly demonstrate that the staggered band structure between FeWO4 and C3N4 reflecting the nature-inspired Z-scheme system not only favors superior spatial separation of the electron hole pair in g-C3N4/FeWO4 but also shows good reusability. The present work provides unprecedented insights for constructing the direct Z-scheme by mimicking the nature for high performance and selective photocatalytic CO2 reduction into solar fuels under solar light.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">6</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;8.456&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Begum, Shabbah</style></author><author><style face="normal" font="default" size="100%">Devendrachari, Mruthyunjayachar Chattanahalli</style></author><author><style face="normal" font="default" size="100%">Bhat, Zahid Manzoor</style></author><author><style face="normal" font="default" size="100%">Thimmappa, Ravikumar</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Geometrical isomerism directed electrochemical sensing</style></title><secondary-title><style face="normal" font="default" size="100%">Analytical Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">92</style></volume><pages><style face="normal" font="default" size="100%">4541-4547</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;We report the independent role of isomerism of secondary sphere substituents over their nature, a factor often overlooked in molecular electrocatalysis pertaining to electrochemical sensing, by establishing that isomerism redefines the electronic structure at the catalytic reaction center via geometrical factors. UV-vis spectroscopy and X-ray photoelectron spectroscopy suggest that a substituent's isomerism in molecular catalysts conjoins molecular planarity and catalytic activation through competing field effects and resonance effects. As a classical example, we demonstrate the influence of isomerism of the -NO2 substituents for the electrocatalytic multi electron oxidation of As(III), a potentially important electrochemical pathway for water remediation and arsenic detection. The isomerism dependent oxidative activation of catalytic center leads to a nonprecious molecular catalyst capable for direct As(III) oxidation with an experimental detection limit close to WHO guidelines. This work opens up an unusual approach in analytical chemistry for developing various sensing platforms for challenging chemical and electrochemical reactions.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">6</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;6.785&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sarma, Saurav Ch.</style></author><author><style face="normal" font="default" size="100%">Kaja, Sai Manoj</style></author><author><style face="normal" font="default" size="100%">Mishra, Vidyanshu</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Peter, Sebastian C.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Tweaking palladium electronic structure to attain oxygen reduction activity superior to platinum/C</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Energy Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">d-band center</style></keyword><keyword><style  face="normal" font="default" size="100%">DFT calculation</style></keyword><keyword><style  face="normal" font="default" size="100%">durability</style></keyword><keyword><style  face="normal" font="default" size="100%">EuPd</style></keyword><keyword><style  face="normal" font="default" size="100%">oxygen reduction reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">YbPd</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">3</style></volume><pages><style face="normal" font="default" size="100%">6127-6132</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Enhancing oxygen reduction (ORR) activity through alloying is crucial to improve the performance of a fuel-cell catalysts. In this work, we have studied the alloying effects of 4f rare-earth (RE) metals with palladium. The modified catalyst exhibits better activity (E-onset = 1 V and E-1/2 = 0.88 V) and higher selectivity toward H2O (similar to 97%) compared to the state-of-the-art catalysts due to complete dissociation of O-2. Hirshfeld charge analysis and 2D-electron localization function reveal improved adsorbate-adsorbent interaction on the catalyst surface. This work paves a strategy to design highly selective non-Pt-based catalysts for the ORR by controlling electronic structures and surface oxide formation.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;4.473&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Begum, Shabbah</style></author><author><style face="normal" font="default" size="100%">Nazrulla, Mohammed Azeezulla</style></author><author><style face="normal" font="default" size="100%">Dargily, Neethu Christudas</style></author><author><style face="normal" font="default" size="100%">Devendrachari, Mruthyunjayachari Chattanahalli</style></author><author><style face="normal" font="default" size="100%">Bhat, Zahid Manzoor</style></author><author><style face="normal" font="default" size="100%">Thimmappa, Ravikumar</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Unprecedented isomerism-activity relation in molecular electrocatalysis</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Physical Chemistry Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">11</style></volume><pages><style face="normal" font="default" size="100%">263-271</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The role of electrocatalysts in energy storage/conversion, biomedical and environmental sectors, green chemistry, and much more has generated enormous interest in comprehending their structure-activity relations. While targeting the surface-to-volume ratio, exposing reactive crystal planes and interfacial modifications are time-tested considerations for activating metallic catalysts; it is primarily by substitution in molecular electrocatalysts. This account draws the distinction between a substituent's chemical identity and isomerism, when regioisomerism of the -NO2 substituent is conferred at the ``alpha'' and ``beta'' positions on the macrocycle of cobalt phthalocyanines. Spectroscopic analysis and theoretical calculations establish that the beta isomer accumulates catalytically active intermediates via a cumulative influence of inductive and resonance effects. However, the field effect in the alpha isomer restricts this activation due to a vanishing resonance effect. The demonstration of the distinct role of isomerism in substituted molecular electrocatalysts for reactions ranging from energy conversion to biosensing highlights that isomerism of the substituents makes an independent contribution to electrocatalysis over its chemical identity.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;6.710&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kushwaha, Rinku</style></author><author><style face="normal" font="default" size="100%">Haldar, Sattwick</style></author><author><style face="normal" font="default" size="100%">Shekhar, Pragalbh</style></author><author><style face="normal" font="default" size="100%">Krishnan, Akshara</style></author><author><style face="normal" font="default" size="100%">Saha, Jayeeta</style></author><author><style face="normal" font="default" size="100%">Hui, Pramiti</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Subramaniam, Chandramouli</style></author><author><style face="normal" font="default" size="100%">Vaidhyanathan, Ramanathan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Exceptional capacitance enhancement of a non-conducting COF through potential-driven chemical modulation by redox electrolyte</style></title><secondary-title><style face="normal" font="default" size="100%">Advanced Energy Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">covalent organic frameworks</style></keyword><keyword><style  face="normal" font="default" size="100%">polyiodide</style></keyword><keyword><style  face="normal" font="default" size="100%">redox electrolytes</style></keyword><keyword><style  face="normal" font="default" size="100%">solid&amp;\#8208</style></keyword><keyword><style  face="normal" font="default" size="100%">state capacitors</style></keyword><keyword><style  face="normal" font="default" size="100%">Supercapacitors</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">11</style></volume><pages><style face="normal" font="default" size="100%">2003626</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Capacitors are the most practical high-storage and rapid charge-release devices. The number of ions stored per unit area and their interaction strength with the electrode dictates capacitor-performance. Microporous materials provide a high storage surface and optimal interactions. Adsorbing electron-rich and easily polarizable molecules into microporous electrodes is expected to boost Faradaic pseudo-activity. If such electrode-electrolyte interactions can be made as a potential-driven reversible process, the resulting capacitors would be adaptable and device-friendly. A composite covalent organic framework (COF)-carbon electrode with redox-active KI is combined in an H2SO4 electrolyte for the first time. This composite electrode benefits from the redox-functionality of COF and electronic conductivity of carbon, leading to superior capacitative activity. Operando spectro-electrochemical measurements reveal the existence of multiple polyiodide species, although the I-3(-) is the predominantly electroactive species adsorbing on the microporous triazine-phenol COF electrode. A systematic fabrication of the flexible solid-state devices using the COF-redox-electrolyte reveals a high areal capacitance of 270 +/- 11 mF cm(-2) and gravimetric capacitance of 57 +/- 8 F g(-1). The inclusion of KI in H2SO4 (electrolyte) yields an approximately eight-fold enhancement in solid-state gravimetric specific capacitance. The imine-COF retains 89% of its capacity even after 10 000 cycles.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">13</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">29.368</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Haldar, Sattwick</style></author><author><style face="normal" font="default" size="100%">Rase, Deepak</style></author><author><style face="normal" font="default" size="100%">Shekhar, Pragalbh</style></author><author><style face="normal" font="default" size="100%">Jain, Chitvan</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Zhang, En</style></author><author><style face="normal" font="default" size="100%">Shupletsov, Leonid</style></author><author><style face="normal" font="default" size="100%">Kaskel, Stefan</style></author><author><style face="normal" font="default" size="100%">Vaidhyanathan, Ramanathan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Incorporating conducting polypyrrole into a polyimide COF for carbon-free ultra-high energy supercapacitor</style></title><secondary-title><style face="normal" font="default" size="100%">Advanced Energy Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">carbon free capacitors</style></keyword><keyword><style  face="normal" font="default" size="100%">cation-anion co-storage</style></keyword><keyword><style  face="normal" font="default" size="100%">conductivity</style></keyword><keyword><style  face="normal" font="default" size="100%">high energy capacitors</style></keyword><keyword><style  face="normal" font="default" size="100%">polypyrrole doped COFs</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">12</style></volume><pages><style face="normal" font="default" size="100%">2200754</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Redox-active covalent organic frameworks (COFs) store charges but possess inadequate electronic conductivity. Their capacitive action works by storing H+ ions in an acidic electrolyte and is typically confined to a small voltage window (0-1 V). Increasing this window means higher energy and power density, but this risks COF stability. Advantageously, COF's large pores allow the storage of polarizable bulky ions under a wider voltage thus reaching higher energy density. Here, a COF-electrode-electrolyte system operating at a high voltage regime without any conducting carbon or redox active oxides is presented. Conducting polypyrrole (Ppy) chains are synthesized within a polyimide COF to gain electronic conductivity (approximate to 10 000-fold). A carbon-free quasi-solid-state capacitor assembled using this composite showcases high pseudo-capacitance (358 mF cm(-2)@1 mA cm(-2)) in an aqueous gel electrolyte. The synergy among the redox-active polyimide COF, polypyrrole and organic electrolytes allows a wide-voltage window (0-2.5 V) leading to high energy (145 mu Wh cm(-2)) and power densities (4509 mu W cm(-2)). Amalgamating the polyimide-COF and the polypyrrole as one material minimizes the charge and mass transport resistances. Computation and experiments reveal that even a partial translation of the modules/monomers intrinsic electronics to the COF imparts excellent electrochemical activity. The findings unveil COF-confined polymers as carbon-free energy storage materials.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">34</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	29.698&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mukhopadhyay, Sanchayita</style></author><author><style face="normal" font="default" size="100%">Devendrachari, Mruthyunjayachari Chattanahalli</style></author><author><style face="normal" font="default" size="100%">Kanade, Sandeep C.</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Regio-isomerism directed electrocatalysis for energy efficient zinc-air battery</style></title><secondary-title><style face="normal" font="default" size="100%">iScience</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">25</style></volume><pages><style face="normal" font="default" size="100%">105179</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	We have investigated the role of ligand isomerism in modulating the mechanisms and kinetics associated with charge/ discharge chemistry of an aqueous metal-air battery. The dominant electron-withdrawing inductive effect (-I effect) and the diminished electron-withdrawing resonance effect (-R effect) in the alpha-NO2 isomer noticeably diminishes the rate of oxygen reduction (ORR) and oxygen evolution reactions (OER) on the catalytic Co-center. In their beta-counterpart, the cumulative -I and -R effects noticeably enhance the OER and ORR kinetics on the same catalytic Co-center. Therefore, the regioisomerism of the -NO2 functionality amplifies the kinetics of ORR/OER without influencing their mechanistic pathways. When isomeric electrocatalysts are integrated to aid the charge chemistry of a Zn-air battery, the overpotential could be decreased by similar to 250mV with beta-NO2 isomer leading to a round-trip efficiency as high as 60%. This work contributes to the design of novel molecular platforms to target the overall round-trip efficiency of energy storage and conversion devices.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">10</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	6.107&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Devulapalli, Venkata Swaroopa Datta</style></author><author><style face="normal" font="default" size="100%">Kushwaha, Rinku</style></author><author><style face="normal" font="default" size="100%">Ovalle, Edwin</style></author><author><style face="normal" font="default" size="100%">Singh, Himan Dev</style></author><author><style face="normal" font="default" size="100%">Shekhar, Pragalbh</style></author><author><style face="normal" font="default" size="100%">Chakraborty, Debanjan</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Vaidhyanathan, Ramanathan</style></author><author><style face="normal" font="default" size="100%">Borguet, Eric</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synergistic electronic effects in AuCo nanoparticles stabilized in a triazine-based covalent organic framework: a catalyst for methyl orange and methylene blue reduction</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Nano Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">AuCoCOF</style></keyword><keyword><style  face="normal" font="default" size="100%">band gaps</style></keyword><keyword><style  face="normal" font="default" size="100%">Covalent organic framework</style></keyword><keyword><style  face="normal" font="default" size="100%">methyl orange reduction</style></keyword><keyword><style  face="normal" font="default" size="100%">Nanoparticles</style></keyword><keyword><style  face="normal" font="default" size="100%">UV-vis spectroscopy</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">5</style></volume><pages><style face="normal" font="default" size="100%">4744-4753</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Developing stable active catalysts for reducing water-soluble pollutants is a desirable target. In this pursuit, we have functionalized covalent organic frameworks (COFs) with gold (Au) and cobalt (Co) nanoparticles via a one-step aqueous synthesis process, and their catalytic activity in reducing methyl orange and methylene blue is examined. Operando absorbance measurements of methyl orange (anionic dye) reduction revealed AuCoCOF (1.3 Au/1.0 Co) to have superior kinetics over many other catalysts, which typically require additional external stimuli (e.g., photons) and higher catalyst loadings. After confirming the homogeneous dispersion of the nanoparticles on the COF support using three-dimensional (3D) tomography and material stability through powder X-ray diffraction (PXRD), infrared (IR), and thermal studies, we investigated their redox activity. Cyclic voltammetry (CV) confirmed the involvement of both metals in the redox process, while spectroelectrochemical measurements show that their activity and kinetics remain unaltered by an applied potential. Solid-state UV measurements reveal that the neat COF is a semiconductor with a large band gap (2.8 eV), which is substantially lowered when loaded with cobalt nanoparticles (2.2 eV for CoCOF). The electronic synergy between Au and Co nanoparticles further reduces the band gap of AuCoCOF (1.9 eV). Thus, there is a definite advantage in doping non-noble metal nanoparticles into a noble metal lattice and nanoconfining them into a porous COF support. Our study highlights the significance of bimetallic COF-supported nanocatalysts, wherein one can engage each component toward targeted applications that demand redox activity with favorable kinetics.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">4</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	6.140&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kushwaha, Rinku</style></author><author><style face="normal" font="default" size="100%">Jain, Chitvan</style></author><author><style face="normal" font="default" size="100%">Shekhar, Pragalbh</style></author><author><style face="normal" font="default" size="100%">Rase, Deepak</style></author><author><style face="normal" font="default" size="100%">Illathvalappil, Rajith</style></author><author><style face="normal" font="default" size="100%">Mekan, Deep</style></author><author><style face="normal" font="default" size="100%">Camellus, Augastus</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Vaidhyanathan, Ramanathan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Made to measure squaramide COF cathode for zinc dual-ion battery with enriched storage via redox electrolyte</style></title><secondary-title><style face="normal" font="default" size="100%">Advanced Energy Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">covalent organic frameworks</style></keyword><keyword><style  face="normal" font="default" size="100%">flexible batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">polyiodide</style></keyword><keyword><style  face="normal" font="default" size="100%">redox electrolytes</style></keyword><keyword><style  face="normal" font="default" size="100%">Zn ion batteries</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">13</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Aqueous rechargeable batteries are promising grid-scale energy storage devices because of their affordability, operational safety, and environmental benignity. Among these, Zn-ion batteries (ZIBs) have unfolded new horizons. Designing superior cathodes for ZIBs is crucial. Covalent organic frameworks (COFs) can be made redox active with a high storage surface. Here, for the first time, a chelating COF with redox-active ZnI2 in a ZnSO4(aq) electrolyte is combined. Including iodide harvests an approximately threefold enhancement in capacity from 208 to 690 mAh g(-1) at 1.5 A g(-1), the highest among all the COF-derived ZIBs. Remarkably, a charge-discharge curve at 1.3 V exhibits very limited dropout voltage and super-flat platform, with a remarkable capacity of 600 mAh g(-1) at 5 A g(-1) stable up to 6000 cycles, confirming that the polyiodide generation and storage are sustainable. The COF's dual-ion storage (Zn2+ and polyidode) delivers a ZIB with the highest energy density. Spectro-electrochemical measurements coupled with X-ray photoelectron spectroscopy unambiguously unveil the existence of multiple polyiodide species, with I-3(-) and IO3- ions as the prominent species. The latter gets reduced at the COF electrode under an applied potential, leaving I-3(-) as the major species stored on the COF. The prospect of COF-polyiodide((aq)) is a windfall for metal-ion batteries.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">34</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	27.8&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Jain, Chitvan</style></author><author><style face="normal" font="default" size="100%">Kushwaha, Rinku</style></author><author><style face="normal" font="default" size="100%">Rase, Deepak</style></author><author><style face="normal" font="default" size="100%">Shekhar, Pragalbh</style></author><author><style face="normal" font="default" size="100%">Shelke, Ankita</style></author><author><style face="normal" font="default" size="100%">Sonwani, Disha</style></author><author><style face="normal" font="default" size="100%">Ajithkumar, Thalasseril G.</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Vaidhyanathan, Ramanathan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Tailoring COFs: transforming nonconducting 2D layered COF into a conducting quasi-3D architecture via interlayer knitting with polypyrrole</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of the American Chemical Society</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">covalent organic frameworks</style></keyword><keyword><style  face="normal" font="default" size="100%">Electrical conductivity</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">146</style></volume><pages><style face="normal" font="default" size="100%">487-499</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Improving the electronic conductivity and the structural robustness of covalent organic frameworks (COFs) is paramount. Here, we covalently cross-link a 2D COF with polypyrrole (Ppy) chains to form a quasi-3D COF. The 3D COF shows well-defined reflections in the SAED patterns distinctly indexed to its modeled crystal structure. This knitting of 2D COF layers with conjugated polypyrrole units improves electronic conductivity from 10(-9) to 10(-2 )S m(-1). This conductivity boost is affirmed by the presence of density of states near the Fermi level in the 3D COF, and this elevates the COF's valence band maximum by 0.52 eV with respect to the parent 2D pyrrole-functionalized COF, which agrees well with the opto-electro band gaps. The extent of HOMO elevation suggests the predominant existence of a polaron state (radical cation), giving rise to a strong EPR signal, most likely sourced from the cross-linking polypyrrole chains. A supercapacitor devised with COF20-Ppy records a high areal capacitance of 377.6 mF cm(-2), higher than that of the COF loaded with noncovalently linked polypyrrole chains. Thus, the polypyrrole acts as a ``conjugation bridge'' across the layers, lowering the band gap and providing polarons and additional conduction pathways. This marks a far-reaching approach to converting many 2D COFs into highly ordered and conducting 3D ones.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Journal Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;15&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Deebansok, Siraprapha</style></author><author><style face="normal" font="default" size="100%">Deng, Jie</style></author><author><style face="normal" font="default" size="100%">Nazrulla, Mohammed Azeezulla</style></author><author><style face="normal" font="default" size="100%">Zhu, Yachao</style></author><author><style face="normal" font="default" size="100%">Bhat, Zahid Manzoor</style></author><author><style face="normal" font="default" size="100%">Devendrachari, Mruthyunjayachari Chattanahalli</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Fontaine, Olivier</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Unprecedented energy storage in metal-organic complexes via constitutional isomerism</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Science</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">6383-6392</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	The essence of any electrochemical system is engraved in its electrical double layer (EDL), and we report its unprecedented reorganization by the structural isomerism of molecules, with a direct consequence on their energy storage capability. Electrochemical and spectroscopic analyses in combination with computational and modelling studies demonstrate that an attractive field-effect due to the molecule's structural-isomerism, in contrast to a repulsive field-effect, spatially screens the ion-ion coulombic repulsions in the EDL and reconfigures the local density of anions. In a laboratory-level prototype supercapacitor, those with beta-structural isomerism exhibit nearly 6-times elevated energy storage compared to the state-of-the-art electrodes, by delivering similar to 535 F g(-1) at 1 A g(-1) while maintaining high performance metrics even at a rate as high as 50 A g(-1). The elucidation of the decisive role of structural isomerism in reconfiguring the electrified interface represents a major step forward in understanding the electrodics of molecular platforms.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">23</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	8.4&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mukhopadhyay, Sanchayita</style></author><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Chame, Pallavi Vyankuram</style></author><author><style face="normal" font="default" size="100%">Ghosh, Prasenjit</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Makri Nimbegondi Kotresh, Harish</style></author><author><style face="normal" font="default" size="100%">Kanade, Sandeep C.</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Unusual ligand assistance in molecular electrocatalysis via interfacial proton charge assembly</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Physical Chemistry Letters </style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">5377-5385</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	We show that the ability of the ligand to reorganizethe electricdouble layer (EDL) often dominates the electrocatalysis contrary totheir inductive effect in the spectrochemical series, leading to counterintuitiveelectrocatalysis. With water oxidation and chlorine evolution as theprobe reactions, the same catalytic entity with carboxy functionalizedligand exhibited surprisingly higher electrochemical activity in comparisonto the aggressively electron-withdrawing nitro functionalized ligands,which is contrary to their actual location in the spectrochemicalseries. Spectroscopic and electrochemical analyses suggest the enrichmentof catalytically active species in the carboxy substituted ligandvia proton charge assembly in the EDL that in turn enhances the kineticsof the overall electrochemical process. This demonstration of lessobvious ligands becoming indispensable in electrocatalysis suggestsa blind designing of ligands solely based on their inductive effectshould be reconsidered as it will prevent the utilization of the maximumpotential of the molecule in electrocatalysis.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">23</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	5.7&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kharabe, Geeta Pandurang</style></author><author><style face="normal" font="default" size="100%">Barik, Sidharth</style></author><author><style face="normal" font="default" size="100%">Veeranmaril, Sudheesh Kumar</style></author><author><style face="normal" font="default" size="100%">Nair, Aathira</style></author><author><style face="normal" font="default" size="100%">Illathvalappil, Rajith</style></author><author><style face="normal" font="default" size="100%">Yoyakki, Athira</style></author><author><style face="normal" font="default" size="100%">Joshi, Kavita</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Kurungot, Sreekumar</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Aluminium, nitrogen-dual-doped reduced graphene oxide Co-existing with cobalt-encapsulated graphitic carbon nanotube as an activity modulated electrocatalyst for oxygen electrocatalyst for oxygen electrochemistry applications</style></title><secondary-title><style face="normal" font="default" size="100%">Small</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Al</style></keyword><keyword><style  face="normal" font="default" size="100%">Bifunctional catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">DFT study</style></keyword><keyword><style  face="normal" font="default" size="100%">encapsulated structure</style></keyword><keyword><style  face="normal" font="default" size="100%">N-dual doping</style></keyword><keyword><style  face="normal" font="default" size="100%">Oxygen Evolution Reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">oxygen reduction reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">rechargeable zinc-air battery</style></keyword><keyword><style  face="normal" font="default" size="100%">X-ray absorption spectroscopy</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">20</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	There is a rising need to create high-performing, affordable electrocatalysts in the new field of oxygen electrochemistry. Here, a cost-effective, activity-modulated electrocatalyst with the capacity to trigger both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) in an alkaline environment is presented. The catalyst (Al, Co/N-rGCNT) is made up of aluminium, nitrogen-dual-doped reduced graphene oxide sheets co-existing with cobalt-encapsulated carbon nanotube units. Based on X-ray Absorption Spectroscopy (XAS) studies, it is established that the superior reaction kinetics in Al, Co/N-rGCNT over their bulk counterparts can be attributed to their electronic regulation. The Al, Co/N-rGCNT performs as a versatile bifunctional electrocatalyst for zinc-air battery (ZAB), delivering an open circuit potential approximate to 1.35 V and peak power density of 106.3 mW cm-2, which are comparable to the system based on Pt/C. The Al, Co/N-rGCNT-based system showed a specific capacity of 737 mAh gZn-1 compared to 696 mAh gZn-1 delivered by the system based on Pt/C. The DFT calculations indicate that the adsorption of Co in the presence of Al doping in NGr improves the electronic properties favoring ORR. Thus, the Al, Co/N-rGCNT-based rechargeable ZAB (RZAB) emerges as a highly viable and affordable option for the development of RZAB for practical applications. This manuscript reports the development of a new bifunctional catalyst that exhibits high activity and stability under practical operating conditions. The catalyst (Al, Co/N-rGCNT) is made up of aluminium, nitrogen-dual-doped reduced graphene oxide sheets co-existing with the in situ formed cobalt-encapsulated CNT units is synthesized by a scalable pyrolysis method in an inert Ar atmosphere. The developed electrocatalyst achieved enhanced the oxygen reduction reaction (ORR) and the oxygen evolution reaction OER activity as a result of the favorable synergistic modulations and the system can serve as a process-friendly air-electrode for rechargeable zinc-air battery (RZAB). image&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">35</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	13.3&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mukhopadhyay, Sanchayita</style></author><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Devendrachari, Mruthyunjayachari Chattanahalli</style></author><author><style face="normal" font="default" size="100%">Mendhe, Rahul Mahadeo</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Electrochemical energy storage in an organic supercapacitor via a non-electrochemical proton charge assembly</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Science</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">15</style></volume><pages><style face="normal" font="default" size="100%">1726-1735</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Contrary to conventional beliefs, we show how a functional ligand that does not exhibit any redox activity elevates the charge storage capability of an electric double layer via a proton charge assembly. Compared to an unsubstituted ligand, a non-redox active carboxy ligand demonstrated nearly a 4-fold increase in charge storage, impressive capacitive retention even at a rate of 900C, and approximately a 2-fold decrease in leakage currents with an enhancement in energy density up to approximately 70% via a non-electrochemical route of proton charge assembly. Generalizability of these findings is presented with various non-redox active functional units that can undergo proton charge assembly in the ligand. This demonstration of non-redox active functional units enriching supercapacitive charge storage via proton charge assembly contributes to the rational design of ligands for energy storage applications.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	8.4&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mendhe, Rahul Mahadeo</style></author><author><style face="normal" font="default" size="100%">Mondal, Ritwik</style></author><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Haridas, Akshay</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Thimmappa, Ravikumar</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Fuel from waste: electrosynthesizing ammonia directly from agricultural digestate through ligand isomerization</style></title><secondary-title><style face="normal" font="default" size="100%">Green Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">26</style></volume><pages><style face="normal" font="default" size="100%">6490-6500</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	We demonstrate that the catalytic metal centre for ammonia production can be selectively activated with only a slight alteration in ligand isomerization (alpha and beta isomers), making it practical and effective even for agricultural effluents. With almost 90% faradaic efficiency, the beta isomer generates approximately 0.64 mg h-1 cm-2 of ammonia. Energy-efficient ammonia recovery is made possible by the interfacial proton charge assembly that beta-isomerization creates, which attracts the reacting nitrate and repels the competing hydronium ions. With minimal energy consumption, this isomerization approach can interconvert agricultural effluents into ammonia fuel, reaching up to 84% of its theoretical yield and maintaining stability over 100 hours of continuous electrolysis. Ligand isomerization driven ammonia electrosynthesis from agricultural waste water.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">11</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	9.8&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pandya, Harmitkumar</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Rathod, Virendra</style></author><author><style face="normal" font="default" size="100%">Kantam, Mannepalli Lakshmi</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetic model of hydrogenation of glucose to sorbitol on a Ni/Bentonite catalyst</style></title><secondary-title><style face="normal" font="default" size="100%">Industrial and Engineering Chemistry Research</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">63</style></volume><pages><style face="normal" font="default" size="100%">4771-4781</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	In the present work, we studied the hydrogenation of glucose to sorbitol using a nickel/bentonite catalyst. The Ni/bentonite catalyst was prepared by the wet impregnation method and characterized by different methods to understand the catalyst surface morphology, surface area, metal content, pore size, etc. Different reaction parameters such as temperature, hydrogen pressure, metal loading, catalyst loading, and agitation speed were studied to achieve a glucose conversion of 96.8% and a sorbitol selectivity of 95.3%. The reusability test was performed to examine the stability of the catalyst. The kinetic models such as the Eley-Rideal and Langmuir-Hinshelwood-Hougen-Watson models were used to study the hydrogenation of glucose and activation energy required for the reaction.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">11</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	4.2&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kottaichamy, Alagar Raja</style></author><author><style face="normal" font="default" size="100%">Nazrulla, Mohammed Azeezulla</style></author><author><style face="normal" font="default" size="100%">Parmar, Muskan</style></author><author><style face="normal" font="default" size="100%">Thimmappa, Ravikumar</style></author><author><style face="normal" font="default" size="100%">Devendrachari, Mruthyunjayachari Chattanahalli</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Volokh, Michael</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Shalom, Menny</style></author><author><style face="normal" font="default" size="100%">Thotiyl, Musthafa Ottakam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Ligand isomerization driven electrocatalytic switching</style></title><secondary-title><style face="normal" font="default" size="100%">ANGEWANDTE CHEMIE-INTERNATIONAL EDITION</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Catalysts</style></keyword><keyword><style  face="normal" font="default" size="100%">CO2 reduction</style></keyword><keyword><style  face="normal" font="default" size="100%">O-2 REDUCTION</style></keyword><keyword><style  face="normal" font="default" size="100%">oxygen reduction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">63</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">30</style></issue><work-type><style face="normal" font="default" size="100%">Journal Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;16.6&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Shekhar, Pragalbh</style></author><author><style face="normal" font="default" size="100%">Kosugi, Kento</style></author><author><style face="normal" font="default" size="100%">Singh, Himan Dev</style></author><author><style face="normal" font="default" size="100%">Kushwaha, Rinku</style></author><author><style face="normal" font="default" size="100%">Rase, Deepak</style></author><author><style face="normal" font="default" size="100%">Matsuzaki, Takumi</style></author><author><style face="normal" font="default" size="100%">Jain, Chitvan</style></author><author><style face="normal" font="default" size="100%">Singh, Piyush</style></author><author><style face="normal" font="default" size="100%">Singh, Yashraj</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Kondo, Mio</style></author><author><style face="normal" font="default" size="100%">Masaoka, Shigeyuki</style></author><author><style face="normal" font="default" size="100%">Vaidhyanathan, Ramanathan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Resorcinol-Azodianiline Covalent Organic Framework Supported FeOOH Quantum Dot-Catalyzed Electrochemical Ammonia Synthesis under Ambient Conditions</style></title><secondary-title><style face="normal" font="default" size="100%">CHEMISTRY OF MATERIALS</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">conversion</style></keyword><keyword><style  face="normal" font="default" size="100%">nitrogen</style></keyword><keyword><style  face="normal" font="default" size="100%">Recent Progress</style></keyword><keyword><style  face="normal" font="default" size="100%">reduction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">36</style></volume><pages><style face="normal" font="default" size="100%">8229-8238</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><work-type><style face="normal" font="default" size="100%">Journal Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;8.6&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Parmar, Muskan</style></author><author><style face="normal" font="default" size="100%">Mukhopadhyay, Sanchayita</style></author><author><style face="normal" font="default" size="100%">Mondal, Ritwik</style></author><author><style face="normal" font="default" size="100%">Nayak, Bhojkumar</style></author><author><style face="normal" font="default" size="100%">Dargily, Neethu Christudas</style></author><author><style face="normal" font="default" size="100%">Kotresh, Harish Makri Nimbegondi</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Ottakam Thotiyl, Musthafa</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synergistic effects of the substrate-ligand interaction in metal-organic complexes on the de-electronation kinetics of a vitamin C fuel cell</style></title><secondary-title><style face="normal" font="default" size="100%">Dalton Transactions</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">53</style></volume><pages><style face="normal" font="default" size="100%">13384-13393</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	The rising demand for portable energy conversion devices has spurred the advancement of direct liquid fuel cells (DLFCs) employing fuels such as alcohol, ammonia, hydrazine, and vitamin C. In these devices, various precious metal platforms have been explored to increase the de-electronation kinetics and reduce catalyst poisoning, but with substantial cost implications. We demonstrate the crucial role of ligands in non-precious organometallic complexes in influencing the de-electronation kinetics of fuel molecules through a unique substrate-ligand synergistic interaction. This unique chemistry imparts electron deficiency at the catalytic metal center while simultaneously populating the ligand with an extensive proton charge assembly. This distinct substrate-ligand interaction enhances the DLFC performance by coulombically dragging the substrate with a distinct amplification in its de-electronation kinetics. By integrating this approach with a ferricyanide/ferrocyanide half-cell reaction, a precious metal-free vitamin C fuel cell is developed, which is capable of generating an open circuit voltage of similar to 950 mV, a peak power density of similar to 97 mW cm-2 at a peak current density of similar to 215 mA cm-2 with the performance metrics nearly 1.7 times higher than a precious metal based DLFC. This highlights the potential of the substrate-ligand synergy in the design of efficient molecular catalysts for energy conversion applications. A precious metal-free biomass fuel cell through substrate-ligand interactions.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">32</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	4&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Patil, Sneha</style></author><author><style face="normal" font="default" size="100%">Kamble, Paresh</style></author><author><style face="normal" font="default" size="100%">Vinod, Chathakudath Prabhakaran</style></author><author><style face="normal" font="default" size="100%">Rathod, Virendra</style></author><author><style face="normal" font="default" size="100%">Kantam, Mannepalli Lakshmi</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Aldol Condensation of Furfural with Acetone by Using Mg-Al-O-t-Bu HT Catalyst and Kinetic Studies</style></title><secondary-title><style face="normal" font="default" size="100%">Industrial &amp; Engineering Chemistry Research</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">64</style></volume><pages><style face="normal" font="default" size="100%">24938-24948</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	An environment-friendly method for producing jet fuel precursors involves the aldol condensation of biomass-derived chemicals. In this study, the condensation reaction between furfural and acetone was performed using a Mg-Al-O-t-Bu hydrotalcite (HT) catalyst, achieving a furfural conversion of 99% and a selectivity of 82% toward 4-(2-furyl)-3-buten-2-one (FAc). The kinetics of the process were evaluated using a Langmuir-Hinshelwood-Hougen-Watson (LHHW) model across a range of temperatures, and the model showed an excellent fit to the experimental data. The effect of different catalysts, reaction temperatures, catalyst loadings, molar ratios, and reaction times was systematically investigated. The Mg-Al-O-t-Bu HT catalyst was extensively analyzed through techniques such as XRD, XPS, FTIR, nitrogen adsorption-desorption measurements, and CO2-TPD. The catalyst exhibited excellent stability, maintaining its performance consistently across five successive reaction cycles with no notable decline in activity. These findings highlight the industrial relevance of Mg-Al-O-t-Bu HT as a robust and recyclable solid base catalyst for biomass upgrading, with strong potential for process scale-up in renewable fuel production.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">52</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	4.0&lt;/p&gt;
</style></custom4></record></records></xml>