<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Darandale, Nutan R.</style></author><author><style face="normal" font="default" size="100%">John, Morgan E.</style></author><author><style face="normal" font="default" size="100%">Moggach, Stephen A.</style></author><author><style face="normal" font="default" size="100%">Sawant, Dinesh N.</style></author><author><style face="normal" font="default" size="100%">Koutsantonis, George A.</style></author><author><style face="normal" font="default" size="100%">Dorta, Reto</style></author><author><style face="normal" font="default" size="100%">Stewart, Scott G.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">NHC/Phosphite Nickel(II) Precatalysts for the C-N Cross-Coupling of (Hetero)Aryl Chlorides under Mild Conditions</style></title><secondary-title><style face="normal" font="default" size="100%">ORGANIC LETTERS</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">27</style></volume><pages><style face="normal" font="default" size="100%">10526-10531</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	We report the synthesis of three nickel complexes based on Ni(NHC)[P(OR)3](Ar)Cl and their application in C(sp 2)-N cross-coupling reactions. Reactions involving secondary amines proceeded at room temperature, while anilines and primary alkyl amines coupled under mild heating. The reported complexes are air-stable as solids, operate at low catalytic loading, and do not require an exogenous ligand. Mechanistic studies suggest both free and Ni-bound phosphite are present during the reaction and that an isolated [Ni(NHC)(amine)(Ar)Cl] complex could be an on-cycle, catalytically active species.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">37</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;4.6&lt;/p&gt;
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