<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ajithkumar, V. S.</style></author><author><style face="normal" font="default" size="100%">Bisai, Milan Kumar</style></author><author><style face="normal" font="default" size="100%">Yuvaraj, K.</style></author><author><style face="normal" font="default" size="100%">Gonnade, Rajesh G.</style></author><author><style face="normal" font="default" size="100%">Sen, Sakya S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Sila[1]ferrocenophanes with Bulky Substituents</style></title><secondary-title><style face="normal" font="default" size="100%">European Journal of Inorganic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">ansa-bridges</style></keyword><keyword><style  face="normal" font="default" size="100%">ferrocenophanes</style></keyword><keyword><style  face="normal" font="default" size="100%">hypersilyls</style></keyword><keyword><style  face="normal" font="default" size="100%">Mashima reagents</style></keyword><keyword><style  face="normal" font="default" size="100%">N-heterocyclic imines</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">28</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	In this study, sila[1]ferrocenophanes with sterically bulky groups such as tris(trimethylsilyl) or N-heterocyclic iminato located at the bridging silicon atom are synthesized. The reactions of silicon-bound chloride in Fe(eta 5-C5H4)2SiCl2 (1) with K[Si(SiMe3)3] and silylated N-heterocyclic imine result in sila[1]ferrocenophanes 2 and 3 with bulky silicon- and nitrogen-based substituents at the ansa-bridge via elimination of KCl and Me3SiCl. Subsequently, the reduction of 1 is attempted using 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-dihydropyrazine (popularly known as Mashima reagent), which leads to the elimination of Me3SiCl and generation of 1,4-dihydropyrazine-spanned sila[1]ferrocenophanes (4). All the compounds are structurally characterized.&lt;/p&gt;
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	Foreign&lt;/p&gt;
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	2&lt;/p&gt;
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