<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Nuralieva, Guzal</style></author><author><style face="normal" font="default" size="100%">Umirzakova, Oydinoy</style></author><author><style face="normal" font="default" size="100%">Torambetov, Batirbay</style></author><author><style face="normal" font="default" size="100%">Rasulov, Abdusamat</style></author><author><style face="normal" font="default" size="100%">Ashurov, Jamshid</style></author><author><style face="normal" font="default" size="100%">Kadirova, Shakhnoza</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synthesis, crystal structure and Hirshfeld analysis of a novel supra­molecular compound [Co(tsc)3]2[Co(cit)2](NO3)4·4H2O</style></title><secondary-title><style face="normal" font="default" size="100%">Acta Crystallographica Section E-Crystallographic Communications</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">81</style></volume><pages><style face="normal" font="default" size="100%">248-251</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;A new cobalt complex, bis­[tris­(amino­thio­urea)cobalt(III)] bis­[2-(carb­oxy­methyl)-2-hy­droxy­butane­dioato]cobalt(II) tetra­nitrate tetra­hydrate, [Co(CH&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;5&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;N&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;S)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;][Co(C&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;6&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;H&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;6&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;O&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;7&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;]&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;0.5&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;(NO&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;·2H&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;O, designated as [Co(tsc)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;]&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;[Co(cit)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;](NO&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;4&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;·4H&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;O, was synthesized. Two crystallographically independent cobalt centers are present. In the first, the central metal atom is chelated by three thio­semicarbazide ligands in a bidentate fashion whereas the second, positioned on a crystallographic inversion center, is hexa­coordinated by two citrate anions in a distorted octa­hedral geometry. Additionally, two water mol­ecules and two nitrate anions are present in the&amp;nbsp;&lt;/span&gt;&lt;a class=&quot;ref_lookup_yellow hideyellow&quot; href=&quot;https://dictionary.iucr.org/Asymmetric_unit&quot; style=&quot;text-decoration-line: none; color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot; target=&quot;Navigator&quot;&gt;asymmetric unit.&lt;/a&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&amp;nbsp;Hirshfeld surface analysis revealed that the presence of numerous donor and acceptor groups in the complex, which facilitate hydrogen-bonding inter­actions that contribute significantly to the overall cohesion of the crystal structure.&lt;/span&gt;&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
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