<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kashid, Somnath M.</style></author><author><style face="normal" font="default" size="100%">Singh, Reman K.</style></author><author><style face="normal" font="default" size="100%">Kwon, Hyejin</style></author><author><style face="normal" font="default" size="100%">Seol, Jin Gyu</style></author><author><style face="normal" font="default" size="100%">Kim, Yung Sam</style></author><author><style face="normal" font="default" size="100%">Mukherjee, Arnab</style></author><author><style face="normal" font="default" size="100%">Bagchi, Sayan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Reply to “comment on ‘arresting an unusual amide tautomer using divalent cations’”</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Physical Chemistry B</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">125</style></volume><pages><style face="normal" font="default" size="100%">479–483</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;In our publication, we assigned the blue-shifted shoulder of&amp;nbsp;&lt;/span&gt;&lt;i style=&quot;outline: none; font-family: Roboto, arial, sans-serif; font-size: 17px; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;N&lt;/i&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;-methylacetamide (NMA) in the infrared (IR) spectrum (∼1645 cm&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; top: -0.5em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;–1&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;) to an iminolate tautomer stabilized in the presence of divalent metal cations (e.g., 5 M Ca&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; top: -0.5em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;2+&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;).&lt;/span&gt;&lt;a class=&quot;ref ref1&quot; style=&quot;outline: none; background-color: transparent; text-decoration-line: underline; color: rgb(26, 13, 171); transition: color 0.3s ease 0s; overflow-wrap: break-word; word-break: break-word; display: inline-block; font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;(1)&lt;/a&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;&amp;nbsp;Cremer and co-workers comment that this shoulder arises from the dehydration of the amide oxygen upon interaction with the metal cations.&lt;/span&gt;&lt;a class=&quot;ref ref1a ref2&quot; style=&quot;outline: none; background-color: transparent; text-decoration-line: underline; color: rgb(26, 13, 171); transition: color 0.3s ease 0s; overflow-wrap: break-word; word-break: break-word; display: inline-block; font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;(2,3)&lt;/a&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;&amp;nbsp;Their assignment is based on three interesting experimental observations: (1) the IR spectrum of&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; top: -0.5em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;15&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;N-isotope-labeled NMA does not show any considerable red-shift compared to that of NMA; (2) a new peak appears for NMA at 1680 cm&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; top: -0.5em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;–1&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;&amp;nbsp;in the presence of 1 M DCl, which shows a 17 cm&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; top: -0.5em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;–1&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;&amp;nbsp;red-shift for&amp;nbsp;&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; top: -0.5em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;15&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;N-labeled NMA; and (3) the IR spectrum of acetone C═O stretch also demonstrates a blue-shifted shoulder in the presence of a high concentration of CaCl&lt;/span&gt;&lt;span style=&quot;outline: none; font-size: 12.75px; line-height: 0; position: relative; bottom: -0.25em; font-family: Roboto, arial, sans-serif; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;2&lt;/span&gt;&lt;span style=&quot;font-family: Roboto, arial, sans-serif; font-size: 17px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 300;&quot;&gt;.&lt;/span&gt;&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;2.857&lt;/p&gt;</style></custom4></record></records></xml>