<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Motaleb, Abdul</style></author><author><style face="normal" font="default" size="100%">Rani, Soniya</style></author><author><style face="normal" font="default" size="100%">Das, Tamal</style></author><author><style face="normal" font="default" size="100%">Gonnade, Rajesh G.</style></author><author><style face="normal" font="default" size="100%">Maity, Pradip</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%"> Phosphite-Catalyzed C-H allylation of azaarenes via an enantioselective [2,3]-Aza-wittig rearrangement </style></title><secondary-title><style face="normal" font="default" size="100%">Angewandte Chemie-International Edition</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span class=&quot;hitHilite&quot;&gt;A&lt;/span&gt; phosphite-mediated [&lt;span class=&quot;hitHilite&quot;&gt;2,3]-aza-Wittig&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;rearrangement&lt;/span&gt; has been developed &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; regio- and &lt;span class=&quot;hitHilite&quot;&gt;enantioselective&lt;/span&gt; allylic alkylation &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; six-membered heteroaromatic compounds (&lt;span class=&quot;hitHilite&quot;&gt;azaarenes&lt;/span&gt;). &lt;span class=&quot;hitHilite&quot;&gt;The&lt;/span&gt; nucleophilic phosphite adducts &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; N-allyl salts undergo &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; stereoselective base-mediated aza-Wittig &lt;span class=&quot;hitHilite&quot;&gt;rearrangement&lt;/span&gt; and dissociation &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; chiral phosphite &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; overall &lt;span class=&quot;hitHilite&quot;&gt;C-H&lt;/span&gt; functionalization &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;azaarenes&lt;/span&gt;. This method provides efficient access &lt;span class=&quot;hitHilite&quot;&gt;to&lt;/span&gt; tertiary and quaternary chiral centers in isoquinoline, quinoline, and pyridine systems, tolerating &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; broad variety &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; substituents &lt;span class=&quot;hitHilite&quot;&gt;on&lt;/span&gt; both &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; allyl part and &lt;span class=&quot;hitHilite&quot;&gt;azaarenes&lt;/span&gt;. &lt;span class=&quot;hitHilite&quot;&gt;Catalysis&lt;/span&gt; with chiral phosphites is also demonstrated with synthetically useful yields and enantioselectivities.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span class=&quot;LrzXr kno-fv&quot;&gt;12.257&lt;/span&gt;&lt;/p&gt;
</style></custom4></record></records></xml>