<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Vijayakanth, Thangavel</style></author><author><style face="normal" font="default" size="100%">Ram, Farsa</style></author><author><style face="normal" font="default" size="100%">Praveenkumar, Balu</style></author><author><style face="normal" font="default" size="100%">Shanmuganathan, Kadhiravan</style></author><author><style face="normal" font="default" size="100%">Boomishankar, Ramamoorthy</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">All-organic composites of ferro- and piezoelectric phosphonium salts for mechanical energy harvesting application</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry of Materials</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">31</style></volume><pages><style face="normal" font="default" size="100%"> 5964-5972</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Molecular ferroelectrics owing to their lightweight, flexibility, and phase stability are drawing attention in the fields &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; flexible electronics, optical devices, and &lt;span class=&quot;hitHilite&quot;&gt;energy&lt;/span&gt; materials. In this paper, we report a series &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; binary organoamino &lt;span class=&quot;hitHilite&quot;&gt;phosphonium&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;salts&lt;/span&gt; containing triphenyl isopropylaminophosphonium (TPAP), diphenyl diisopropylaminophosphonium (DPDP), phenyl triisopropylaminophosphonium (PTAP), and tetraisopropylaminophosphonium (TIAP) cations supported by lower symmetric tetrahedral BF4-, ClO4-, and IO4- anions. The P-E hysteresis loop measurements on these polar organic &lt;span class=&quot;hitHilite&quot;&gt;salts&lt;/span&gt; gave high remnant polarization (P-r) values &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; 35.36, 21.83, and 21.12 mu C cm(-2) &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; the DPDP center dot BF4, DPDP center dot ClO4, and DPDP center dot IO4 &lt;span class=&quot;hitHilite&quot;&gt;salts&lt;/span&gt;, respectively, having 1D hydrogen-bonded chain structures built from strong N-H center dot center dot center dot X (X = F or 0) interactions. &lt;span class=&quot;hitHilite&quot;&gt;For&lt;/span&gt; the first time, highly flexible composite devices have been prepared &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; the &lt;span class=&quot;hitHilite&quot;&gt;piezoelectric&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;salts&lt;/span&gt; TPAP center dot BF4, DPDP center dot BF4, and TIAR center dot BF4 using thermoplastic polyurethane (TPU) as the matrix. The observed maximum peak-to-peak output voltages (V-pp) &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; the 10 wt % composite devices &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; TPAP center dot BF4/TPU, DPDP center dot BF4/TPU, and TIAP center dot BF4/TPU are found to be 7.37, 8.95, and 4.75 V, respectively. These composite devices exhibit excellent durability, cycling stability, and viscoelastic properties. They also show the capacitor charging capabilities reaching their maximum charging points within 60 s.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">15</style></issue><work-type><style face="normal" font="default" size="100%">A</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span class=&quot;jhHeader_impact&quot;&gt;10.159&lt;/span&gt;&lt;/p&gt;
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