<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Landge, Vinod G.</style></author><author><style face="normal" font="default" size="100%">Parveen, Ayisha</style></author><author><style face="normal" font="default" size="100%">Nandakumar, Avanashiappan</style></author><author><style face="normal" font="default" size="100%">Balaraman, Ekambaram</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Pd(II)-Catalyzed gamma-C(sp(3))-H alkynylation of amides: selective functionalization of R chains of amides (RC)-C-1(O)NHR</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Communications</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2018</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">54</style></volume><pages><style face="normal" font="default" size="100%">7483-7486</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The gamma C(sp(3))-H bond alkynylation of R chains of amides (RC)-C-1(O)NHR, a fundamental class of synthetic substrates, has not been accomplished to date. Here, the first example of palladium(ii)-catalyzed alkynylation of an unactivated gamma C(sp(3))-H bond of alkyl amides (cyclic, linear, and amino acids) is reported. The kinetic experiment shows that the rate of the reaction depends on the coupling partners and the amides. Late-stage diversification of alkynylated amides was developed by utilizing amine and alkyne functionalities.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">54</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">6.319</style></custom4></record></records></xml>