<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tayade, Sakharam B.</style></author><author><style face="normal" font="default" size="100%">Bhat, Satish S.</style></author><author><style face="normal" font="default" size="100%">Illathvalappil, Rajith</style></author><author><style face="normal" font="default" size="100%">Dhavale, Vishal M.</style></author><author><style face="normal" font="default" size="100%">Kawade,Vitthal A.</style></author><author><style face="normal" font="default" size="100%">Kumbhar, Avinash S.</style></author><author><style face="normal" font="default" size="100%">Kurungot, Sreekumar</style></author><author><style face="normal" font="default" size="100%">Näther, Christian</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Water mediated proton conductance in a hydrogen-bonded Ni(II)-bipyridine-glycoluril chloride self-assembled framework</style></title><secondary-title><style face="normal" font="default" size="100%">CrystEngComm</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2018</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">20</style></volume><pages><style face="normal" font="default" size="100%">1094-1100</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;div class=&quot;capsule__text&quot; style=&quot;margin: 8px 0px; color: rgba(0, 0, 0, 0.79); font-family: museo_sans300, museo-sans; font-size: 16px; letter-spacing: -0.32px;&quot;&gt;&lt;p style=&quot;margin-top: 0px;&quot; xmlns=&quot;http://www.rsc.org/schema/rscart38&quot;&gt;Proton conducting properties have been investigated in a new Ni(&lt;small&gt;II&lt;/small&gt;)-based hydrogen-bonded porous framework synthesized using a urea-fused bipyridine-glycoluril (BPG) tecton. This hydrogen-bonded self-assembled structure encapsulates water molecules in the channels with hydrogen-bonding networks which exhibits a significant temperature dependent proton conductance of 1.5 &amp;times; 10&lt;small&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&amp;minus;4&lt;/span&gt;&lt;/small&gt;&amp;nbsp;S cm&lt;small&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; top: -0.4em;&quot;&gt;&amp;minus;1&lt;/span&gt;&lt;/small&gt;&amp;nbsp;at 95 &amp;deg;C and 95% RH with a low activation energy (&lt;em&gt;E&lt;/em&gt;&lt;small&gt;&lt;span style=&quot;vertical-align: baseline; position: relative; bottom: -0.4em;&quot;&gt;a&lt;/span&gt;&lt;/small&gt;) of 0.54 eV, implying a Grotthuss proton hopping mechanism mediated by hydrogen-bonded water molecules in the channels. In addition, this framework exhibited a very high water uptake under humid conditions. A continuous array of water molecules and chloride ions embedded in the highly hydrophilic porous channels of the hydrogen-bonded framework acts as the proton conducting medium.&lt;/p&gt;&lt;div&gt;&amp;nbsp;&lt;/div&gt;&lt;/div&gt;&lt;p&gt;&amp;nbsp;&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">8</style></issue><work-type><style face="normal" font="default" size="100%">Journal Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;3.474&lt;/p&gt;</style></custom4></record></records></xml>