<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Jancy, B.</style></author><author><style face="normal" font="default" size="100%">Asha, S. K.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hydrogen-bonding-induced conformational change from J to H aggregate in novel highly fluorescent liquid-crystalline perylenebisimides</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry of Materials</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2008</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">20</style></volume><pages><style face="normal" font="default" size="100%">169–181</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;A series of highly fluorescent liquid-crystalline perylenebisimide molecules having amide or ester linkage and end-capped by phenyl, monododecyloxy phenyl, or tridodecyloxy phenyl units have been synthesized and fully characterized. The amide-functionalized series self-organized to form H type aggregates regardless of their end-capping in organic solvents like tetrahydrofuran (THF), toluene, and dichloromethane. On the other hand, only the monododecyloxy phenyl end-capped molecule in the ester series showed a tendency to self-organize with a typical J type aggregation in toluene. In both series, the highest aggregation tendency was shown by the one having monododecyloxy phenyl end-capping, with the transition temperature from aggregated to molecularly dissolved species occurring at 60 °C for the amide and 50 °C for the ester molecule. At higher concentrations in toluene, the fluorescence spectra of the monododecyloxy phenyl and tridodecyloxy phenyl terminal-substituted amide derivatives showed the formation of a new peak corresponding to excimer emission at 670 nm. Thin drop cast films of the perylenebisimide ester and amide series gave only excimer emission ∼670 nm upon excitation. Thermal analysis using differential scanning calorimetry (DSC), polarized light microscopy (PLM), and powder X-ray diffraction measurements were utilized to study the liquid-crystalline (LC) characteristics of the molecules. Scanning electron micrograph (SEM) of thin drop-cast samples that were annealed in toluene showed the formation of supramolecular rods several micrometers in length, especially for the amide derivatives. The ester derivative, on the other hand, showed a leaflike morphology thus differentiating it from the amide series, which have both hydrogen bonding and π−π interactions to support self-organization.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom2><style face="normal" font="default" size="100%">&lt;p&gt;Council of Scientific &amp;amp; Industrial Research (CSIR) - India&lt;/p&gt;</style></custom2><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">9.407</style></custom4></record></records></xml>