<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Foster, Jamie S.</style></author><author><style face="normal" font="default" size="100%">Zurek, Justyna M.</style></author><author><style face="normal" font="default" size="100%">Almeida, Nuno M. S.</style></author><author><style face="normal" font="default" size="100%">Hendriksen, Wouter E.</style></author><author><style face="normal" font="default" size="100%">le Sage, Vincent A. A.</style></author><author><style face="normal" font="default" size="100%">Lakshminarayanan, Vasudevan</style></author><author><style face="normal" font="default" size="100%">Thompson, Amber L.</style></author><author><style face="normal" font="default" size="100%">Banerjee, Rahul</style></author><author><style face="normal" font="default" size="100%">Eelkema, Rienk</style></author><author><style face="normal" font="default" size="100%">Mulvana, Helen</style></author><author><style face="normal" font="default" size="100%">Paterson, Martin J.</style></author><author><style face="normal" font="default" size="100%">van Esch, Jan H.</style></author><author><style face="normal" font="default" size="100%">Lloyd, Gareth O.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Gelation landscape engineering using a multi-reaction supramolecular hydrogelator system</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of the American Chemical Society</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">45</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">137</style></volume><pages><style face="normal" font="default" size="100%">14236-14239</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Simultaneous control of the kinetics and thermodynamics of two different types of covalent chemistry allows pathway selectivity in the formation of hydrogelating molecules from a complex reaction network. This can lead to a range of hydrogel materials with vastly different properties, starting from a set of simple starting compounds and reaction conditions. Chemical reaction between a trialdehyde and the tuberculosis drug isoniazid can form one, two, or three hydrazone connectivity products, meaning kinetic gelation pathways can be addressed. Simultaneously, thermodynamics control the formation of either a keto or an enol tautomer of the products, again resulting in vastly different materials. Overall, this shows that careful navigation of a reaction landscape using both kinetic and thermodynamic selectivity can be used to control material selection from a complex reaction network.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">45</style></issue><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">13.038</style></custom4></record></records></xml>