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A. T.  Biju, Padmanaban, M., Wurz, N. E., and Glorius, F., ?N-Heterocyclic carbene catalyzed umpolung of michael acceptors for intermolecular reactions?, Angewandte Chemie-International Edition, vol. 50, no. 36, pp. 8412-8415, 2011.\par \par R. S.  Menon, Biju, A. T., and Nair, V., ?Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions?, Beilstein Journal of Organic Chemistry, vol. 12, pp. 444-461, 2016.\par \par H. R.  Chand and Bhattacharya, A. K., ?Hemiketal-keto tautomerism in 2-deoxy-delta-lactones mediated by 2-lithiothiazole in solution state: a formal synthesis of DAH, Kamusol and their C-5 Epimers?, Asian Journal of Organic Chemistry, 2019.\par \par T. Kanti Das, Ghosh, A., Balanna, K., Behera, P., Gonnade, R. G., Marelli, U. Kiran, Das, A. Kumar, and Biju, A. T., ?N-Heterocyclic carbene-catalyzed umpolung of imines for the enantioselective synthesis of dihydroquinoxalines?, ACS Catalysis, vol. 9, no. 5, pp. 4065-4071, 2019.\par \par M. H.  Shinde and Ramana, C. V., ?Apparent umpolung reactivity of indole through [Au]-catalysed cyclisation and lewis-acid-mediated allylation?, Chemistry-A European Journal, vol. 26, no. 71, pp. 17171-17175, 2020.\par \par }