02574nas a2200373 4500008004100000022001400041245014200055210006900197260000800266490000700274520138700281653001501668653001501683653002401698653001101722653001601733653002601749653001301775653001401788653001801802653002101820653001701841653002301858653002801881653002801909653001501937100002101952700001801973700002001991700002102011700001802032700001902050856013102069 2017 eng d a1350-417700aIntensification of extraction of curcumin from Curcuma amada using ultrasound assisted approach: Effect of different operating parameters0 aIntensification of extraction of curcumin from Curcuma amada usi cSEP0 v383 a

Curcumin, a dietary phytochemical, has been extracted from rhizomes of Curcuma amada using ultrasound assisted extraction (UAE) and the results compared with the conventional extraction approach to establish the process intensification benefits. The effect of operating parameters such as type of solvent, extraction time, extraction temperature, solid to solvent ratio, particle size and ultrasonic power on the extraction yield have been investigated in details for the approach UAE. The maximum extraction yield as 72% was obtained in 1 h under optimized conditions of 35 degrees C temperature, solid to solvent ratio of 1:25, particle size of 0.09 mm, ultrasonic power of 250 W and ultrasound frequency of 22 kHz with ethanol as the solvent. The obtained yield was significantly higher as compared to the batch extraction where only about 62% yield was achieved in 8 h of treatment. Peleg's model was used to describe the kinetics of UAE and the model showed a good agreement with the experimental results. Overall, ultrasound has been established to be a green process for extraction of curcumin with benefits of reduction in time as compared to batch extraction and the operating temperature as compared to Soxhlet extraction.

10aAcrylamide10aCavitation10aCurcumin Extraction10aDesign10aEnhancement10aFunctionalized Silica10akinetics10aMicrowave10aNanoparticles10aNatural-products10aOptimization10aPhenolic-compounds10aProcess Intensification10aSolid-liquid Extraction10aUltrasound1 aShirsath, S., R.1 aSable, S., S.1 aGaikwad, S., G.1 aSonawane, S., H.1 aSaini, D., R.1 aGogate, P., R. uhttps://library.ncl.res.in/content/intensification-extraction-curcumin-curcuma-amada-using-ultrasound-assisted-approach-effect02647nas a2200265 4500008004100000022001400041245012000055210006900175260000900244300001200253490000800265520177000273653001502043653001702058653001302075653001402088653002502102100001602127700002402143700002102167700002202188700002202210700002502232856012402257 2019 eng d a0301-479700aHydrodynamic cavitation using vortex diode: an efficient approach for elimination of pathogenic bacteria from water0 aHydrodynamic cavitation using vortex diode an efficient approach cJUL  a210-2190 v2423 a

The present study successfully demonstrates greener methodology of hydrodynamic cavitation using rotational flows for disinfection of water. Disinfection of two model microbial strains-gram-negative (Escherichia colt) and gram-positive (Staphylococcus aureus) using vortex diode was evaluated. The removal efficacy was quantified for two different cavitation reactors. Practically complete elimination of E. coli was achieved (99%) after 1 h of cavitation at a pressure drop of only 0.5 bar. However, elimination of S. aureus using vortex diode was observed to be lower in comparison to the removal of E. coli and only 60% disinfection could be achieved under similar conditions, which can be subsequently enhanced up to 98% by increasing pressure drop. The results were compared with another cavitating device that employs linear flow for cavitation, orifice. The reactor geometry has significant impact on the disinfection process and orifice was found to require significantly higher pressure drop (10 bar) conditions for disinfection and for eliminating grain-positive bacteria with high efficiency. A plausible mechanism for disinfection was proposed to elucidate the role of cavitation in cell destruction leading to death of cells through the rupture of cell wall, oxidative damage and possible DNA denaturation. Also, a cavitation model using per pass disinfection was developed that can provide meaningful physical description of the disinfection process as against the conventional first order reaction rate model. This study would provide meaningful insight into cavitation process based on hydrodynamic cavitation for the destruction of both gram-negative and gram-positive bacteria from various water sources, including industrial wastewaters.

10aCavitation10aDisinfection10akinetics10apollution10aWastewater treatment1 aJain, Pooja1 aBhandari, Vinay, M.1 aBalapure, Kshama1 aJena, Jyotsnarani1 aRanade, Vivek, V.1 aKilledar, Deepak, J. uhttps://library.ncl.res.in/content/hydrodynamic-cavitation-using-vortex-diode-efficient-approach-elimination-pathogenic02959nas a2200241 4500008004100000022001400041245014000055210006900195260000800264300001100272490000700283520213400290653001702424653001502441653001702456653000802473653002002481100001902501700002402520700002102544700002202565856013002587 2020 eng d a1350-417700aDestroying antimicrobial resistant bacteria (AMR) and difficult, opportunistic pathogen using cavitation and natural oils/plant extract0 aDestroying antimicrobial resistant bacteria AMR and difficult op cDEC a1052720 v693 a

The present study reports, for the first time, a new and techno-economic strategy for effective removal of antimicrobial resistant bacteria (AMR) and difficult, opportunistic pathogen using cavitation and natural oils/plant extract. A hybrid methodology using natural oils of known health benefits has been discussed in combination with conventional physico-chemical method of hydrodynamic cavitation that not only provides efficient and effective water disinfection, but also eliminates harmful effects of conventional methods such as formation of disinfection by-products apart from reducing cost of treatment. A proof-of concept is demonstrated by achieving exceptionally high rates for practically complete removal of antimicrobial resistant (AMR) and relatively less researched, gram-negative opportunistic pathogen, Pseudomonas aeruginosa and gram-positive methicillin resistant, Staphylococcus aureus using a natural oil-Peppermint oil and two different cavitating reactors employing vortex flow (vortex diode) and linear flow (orifice) for hydrodynamic cavitation. > 99% disinfection could be obtained, typically in less than 10 min, using vortex diode with operating pressure drop of 1 bar and low dose of 0.1% peppermint oil as an additive, depicting very high rates of disinfection. The rate of disinfection can be further increased by using simple aeration which can result in significant lowering of oil dose. The conventional device, orifice requires relatively higher pressure drop of 2 bar and comparatively more time (similar to 20 min) for disinfection. The cost of the disinfection was also found to be significantly lower compared to most conventional processes indicating techno-economic feasibility in employing the developed hybrid method of disinfection for effectively eliminating bacteria including AMR bacteria from water. The developed approach not only highlights importance of going back to nature for not just conventional water disinfection, but also for eliminating hazardous AMR bacteria and may also find utility in many other applications for the removal of antimicrobial bacteria.

10aAMR bacteria10aCavitation10aDisinfection10aOil10aWater treatment1 aMane, Maya, B.1 aBhandari, Vinay, M.1 aBalapure, Kshama1 aRanade, Vivek, V. uhttps://library.ncl.res.in/content/destroying-antimicrobial-resistant-bacteria-amr-and-difficult-opportunistic-pathogen-using02964nas a2200241 4500008004100000022001400041245012700055210006900182260000800251300001100259490000700270520214700277653001802424653001502442653001702457653000802474653002502482100001902507700002402526700002102550700002202571856012902593 2020 eng d a1350-417700aNovel hybrid cavitation process for enhancing and altering rate of disinfection by use of natural oils derived from plants0 aNovel hybrid cavitation process for enhancing and altering rate  cMAR a1048200 v613 a

The present study is an attempt to improvise the hydrodynamic cavitation methodology for effective disinfection of water and also to suggest prototype development for practical application. The enhancement in the disinfection efficiency was evaluated specifically for the effect of pressure, temperature, pH, microbial inoculum size and also on effect of different additives for the two model microbial strains, gram-negative (Escherichia coli) and gram-positive (Staphylococcus aureus). The efficacy of the hydrodynamic cavitation is evaluated for the two types of flows/cavitation devices - linear flow in the case of orifice and vortex flow for vortex diode. The vortex diode requires significantly lower pressures, 50% lower as compared to orifice for the similar extent of disinfection. While the bacterial disinfection at high temperature is known, the usefulness of hydrodynamic cavitation is especially evident at ambient conditions and the process is effective even at very high concentrations of bacteria, not reported so far. The reactor geometry also has significant effect on the disinfection. The present study, for the first time, reports possible use of different natural oils such as castor oil, cinnamon oil, eucalyptus oil and clove oil in conjunction with hydrodynamic cavitation. The nature of oil modifies the cavitation behavior and an order of magnitude enhancement in the cavitation rate was observed for the two oils, eucalyptus and clove oil for a very small concentration of 0.1%. The increased rates of disinfection, of the order of 2-4 folds, using oil can drastically reduce the time of operation and consequently reduce cost of disinfection. A possible mechanism is proposed for the effect of oil and hydrodynamic cavitation in cell destruction through the rupture of cell wall, oxidative damage and possible DNA denaturation. A cavitation model using per pass disinfection was used to correlate the data. The increased efficiency using oils and possible benefits of the developed process, where natural oils can be perceived as biocatalysts, can have significant advantages in practical applications.

10aAntimicrobial10aCavitation10aDisinfection10aOil10aWastewater treatment1 aMane, Maya, B.1 aBhandari, Vinay, M.1 aBalapure, Kshama1 aRanade, Vivek, V. uhttps://library.ncl.res.in/content/novel-hybrid-cavitation-process-enhancing-and-altering-rate-disinfection-use-natural-oils02683nas a2200229 4500008004100000022001400041245010700055210006900162260000800231300001100239490000700250520191300257653001702170653001502187653001402202653001402216653002502230100002202255700002402277700002202301856013002323 2021 eng d a1350-417700aImproving efficiency for removal of ammoniacal nitrogen from wastewaters using hydrodynamic cavitation0 aImproving efficiency for removal of ammoniacal nitrogen from was cJAN a1053060 v703 a

The present study reports significant improvements in the removal of ammoniacal nitrogen from wastewater which is an important problem for many industries such as dyes and pigment, distilleries and fisheries. Pilot plant studies (capacity, 1 m(3)/h) on synthetic wastewater using 4-amino phenol as model nitrogen containing organic compound and two real industrial effluents of high ammoniacal nitrogen content were carried out using hydrodynamic cavitation. Two reactor geometries were evaluated for increased efficiency in removal-orifice and vortex diode. Effect of initial concentration (100-500 mg/L), effect of pressure drop (0.5-5 bar) and nature of cavitating device (linear and vortex flow for cavitation) were evaluated along with effect of salt content, effect of hydrogen peroxide addition and aeration. Initial concentration was found to have significant impact on the extent of removal: similar to 5 g/m(3) removal for initial concentration of 100 mg/L and up to 12 g/m(3) removal at high concentration of 500 mg/L. Interestingly, significant improvement of the order of magnitude (up to 8 times) in removal of ammoniacal nitrogen could be obtained by sparging air or oxygen in hydrodynamic cavitation and a very high removal of above 80% could be achieved. The removal of ammoniacal nitrogen by vortex diode was also found to be effective in the industrial wastewaters and results on two different effluent samples of distillery industry indicated up to 75% removal, though with longer time of treatment compared to that of synthetic wastewater. The developed methodology of hydrodynamic cavitation technology with aeration and vortex diode as a cavitating device was found to be highly effective for improving the efficiency of the conventional cavitation methods and hence can be highly useful in industrial wastewater treatment, specifically for the removal of ammoniacal nitrogen.

10aAmino phenol10aCavitation10aOxidation10apollution10aWastewater treatment1 aPatil, Pravin, B.1 aBhandari, Vinay, M.1 aRanade, Vivek, V. uhttps://library.ncl.res.in/content/improving-efficiency-removal-ammoniacal-nitrogen-wastewaters-using-hydrodynamic-cavitation02126nas a2200229 4500008004100000022001400041245011200055210006900167260000800236300001100244490000700255520135400262653001501616653001701631653001601648653001801664653002001682100001901702700002401721700002201745856012901767 2021 eng d a2214-714400aSafe water and technology initiative for water disinfection: application of natural plant derived materials0 aSafe water and technology initiative for water disinfection appl cOCT a1022800 v433 aSafe drinking water is the necessity of life. The present study reveals use of natural resources such as plant extracts and natural oils for water disinfection. Differences between oil and water soluble additives were highlighted for plant extracts and insoluble natural oils. A hybrid hydrodynamic cavitation process was quite effective in both the cases and high rates of disinfection were achieved. Studies were reported using oils (ginger, turmeric, lavender, tulsi) and rhizome derived plant extracts such as ginger, turmeric and mango ginger, as additives in process intensification (0.1% v/V). A vortex based cavitation device (vortex diode, nominal capacity 1 m3/h) was used with pressure drop of 1 bar. A high disinfection of 96% and 88% was obtained in 15 min for ginger oil and mango ginger extract respectively as compared to 44% using cavitation alone. Acoustic cavitation gave 94% and 30% disinfection with and without additive-mango ginger extract. The FTIR analyses before and after cavitation, with ginger additive, showed no by-products formation and indicated gingerol as active component in disinfection. The per-pass disinfection values were also higher, up to 5 times than cavitation alone. Hybrid hydrodynamic cavitation using natural plant derived materials can offer a promising technology alternative in water disinfection.10aCavitation10aDisinfection10aNatural oil10aPlant extract10aWater treatment1 aMane, Maya, B.1 aBhandari, Vinay, M.1 aRanade, Vivek, V. uhttps://library.ncl.res.in/content/safe-water-and-technology-initiative-water-disinfection-application-natural-plant-derived02227nas a2200253 4500008004100000022001400041245012500055210006900180260000800249300001100257490000800268520135000276653001501626653002201641653001301663653002001676653002201696653003501718100002501753700002101778700002601799700002201825856012601847 2021 eng d a0255-270100aUltrasound assisted curcumin recovery from Curcuma aromatica: understanding the effect of different operating parameters0 aUltrasound assisted curcumin recovery from Curcuma aromatica und cDEC a1086040 v1693 aThe present study deals with intensified extraction of curcumin from Curcuma aromatica by employing ultrasound-assisted extraction (UAE) approach also elucidating comparison with the conventional batch extraction to highlight the intensification benefits based on the usage of ultrasound. Understanding into the effect of operational parameters like type of solvent, extraction temperature, solid to solvent ratio and raw material size distribution as well as the equipment operating conditions as frequency and power on the extraction yield has been developed. Based on the results for extraction yield, the optimum conditions for UAE approach were 40 degrees C as temperature, 1:30 as solid to solvent ratio, 0.09 mm as the mean particle size, 240 W as ultrasonic power, 22 kHz as ultrasonic frequency and ethanol as the most suitable solvent. Under these optimum conditions, the highest extraction yield of 73.18% was achieved in 2 h whereas batch extraction for 14 h resulted in 52.31% yield clearly demonstrating the intensification due to ultrasound. Peleg's model was applied to explain the extraction kinetics of curcumin and the proposed model satisfactorily predicted the rates of extraction of cur cumin. Overall, UAE proved to be a better technique in terms of lesser time, lesser heating requirement and additional extraction yield.10aCavitation10aCurcuma aromatica10acurcumin10aIntensification10aKinetic modelling10aUltrasound assisted extraction1 aShirsath, Sachin, R.1 aSable, Sunil, S.1 aGaikwad, Shashank, G.1 aGogate, Parag, R. uhttps://library.ncl.res.in/content/ultrasound-assisted-curcumin-recovery-curcuma-aromatica-understanding-effect-different02117nas a2200229 4500008004100000022001400041245011100055210006900166260000800235300001100243490000800254520135200262653001501614653001301629653002101642653001401663653001401677100002201691700002401713700002201737856012801759 2021 eng d a0255-270100aWastewater treatment and process intensification for degradation of solvents using hydrodynamic cavitation0 aWastewater treatment and process intensification for degradation cSEP a1084850 v1663 aIndustrial wastewater treatment for removal of small concentrations of harmful solvents is pertinent issue in many chemical and pharmaceutical industries. The present work evaluates removal of three common solvents by hydrodynamic cavitation (nominal capacity, 1m(3)/h). Solvent degradation of three solvents viz. octanol, dimethyl formamide and cyclohexanol was studied in the concentration range of 50-200 mg/L and for the pressure drop range of 0.5-5 bar. The vortex based cavitation device (vortex diode) was compared with that of linear flow based device (orifice). Process intensification in the form of aeration and addition oxidizing agent-hydrogen peroxide was also evaluated for synergistic effect. The vortex diode required lower pressure drop and is superior to orifice and process intensification using aeration is most effective. A reduction in TOC to the extent of 74% could be achieved for octanol (200 ppm) using aeration with cavitational yield of 1202x10(-4) mg/J for vortex diode, yield similar to 10 times of orifice. The degradation depends on the nature of solvent and it was revealed that low values of dielectric constant (epsilon<10) favour degradation. The kinetics was evaluated using rate model based on per-pass degradation factor. The process techno-economic feasibility is useful in industrial wastewater treatment.10aCavitation10aEffluent10aOrganics removal10aOxidation10apollution1 aPatil, Pravin, B.1 aBhandari, Vinay, M.1 aRanade, Vivek, V. uhttps://library.ncl.res.in/content/wastewater-treatment-and-process-intensification-degradation-solvents-using-hydrodynamic02050nas a2200217 4500008004100000022001400041245007300055210006900128260000800197490000800205520137000213653001501583653001401598653001401612653001501626653002501641100001701666700002001683700002401703856010501727 2023 eng d a0255-270100aEnhanced degradation of metformin using surface-coated vortex diodes0 aEnhanced degradation of metformin using surfacecoated vortex dio cNOV0 v1933 a

The present work successfully demonstrates, for the first time, complete degradation of metformin using newer surface-coated vortex diode (SCVD) with copper and nickel coating to provide catalytic activity in the conventional hydrodynamic cavitation (HC) for significantly enhanced degradation efficiency. The SCVDs have dual functionality and the efficacy of catalytic cavitation reactors get enhanced using process intensifications of the type H2O2 addition, pH modification, and combined approach of HC+ pH+ H2O2 apart from the advantage of low pressure drop for the vortex flow based cavitation in vortex diode (Delta P of 1 bar). Complete, 100%, degradation of metformin (MTF) was achieved within 5 min with integration of optimized H2O2 dose and exceptionally high synergistic index value over 300, indicating extraordinary synergy for both Cu and Ni-SCVD. Acidic condition promote degradation and a complete degradation with a high 43-48% mineralization was observed using HC+ pH 4+ (1:200) H2O2 with less intermediates formation. The SCVDs reveal remarkable enhancement of similar to 9800% in per-pass degradation and 1400-3400% in cavitational yield as compared to conventional cavitation process under similar conditions. The newer SCVDs with catalytic activity can provide more cost-effective solutions for industrial and real-life applications.

10aCavitation10aOxidation10apollution10aTechnology10aWastewater treatment1 aDixit, Divya1 aThanekar, Pooja1 aBhandari, Vinay, M. uhttps://library.ncl.res.in/content/enhanced-degradation-metformin-using-surface-coated-vortex-diodes