02782nas a2200241   4500008004100000022001400041245012500055210006900180260007500249300001200324490000700336520186000343653001902203653003702222653001502259653003402274653002202308100002002330700002502350700002002375700001802395856012702413       2006                        eng d  a1566-254300aPhoto-bio-degradability of agro waste and ethylene-propylene copolymers composites under abiotic and biotic environments0 aPhotobiodegradability of agro waste and ethylenepropylene copoly  a233 SPRING ST, NEW YORK, NY 10013 USAbSPRINGER/PLENUM PUBLISHERScAPR  a203-2120 v143 a<p>Composites were prepared by two methods, (i) graft copolymerization (GFC) of isotactic polypropylene (PP) with maliec anhydride, (MAH) followed by esterification with coir fiber and (ii) by direct reactive mixing (DFC) of polypropylene (PP) and ethylene-propylene (EP) copolymers with MAH and peroxide with coir fiber. These composites, after molding in films (5 x 5 cm, - 100 mu m thickness) were examined for susceptibility to biological attack by measuring the percentage weight loss in compost upto 6 months, periodically, and fungal colonization on surface of the samples, when kept as sole carbon source for the growth of Aspergillus niger in culture medium upto 40 days. Photodegradation was evaluated by monitoring the variations in FT-IR spectrum and crack formation after successive treatment with UV light (&gt;= 290 nm) for 0, 20, 50 and 100 h at 60 C in the presence of air. Specimens of virgin PP were taken as a reference during all period of photo and biodegradation studies. Significant changes were observed depending on the preparation methods during photodegradation and biodisintegration of composites. DFCs samples were disintegrated faster than GFCs during the composting whereas, in culture, GFCs were covered highly in well uniform way by fungi. It was observed that photo-oxidative ageing directly enhanced the biodegradability of composites as the increase in fungal growth rate and decrease in weight during composting were found. It was concluded that extent of compatibilization had a profound effect on photo-oxidation and biodisintegration of composite material; consequently ester bonds were main units during fungal consumption. Composition of monomers in copolymers was also showing significant effect on the degradability which decreased with increasing content of ethylene in ethylene-propylene (EP) copolymers.</p>10aBiodegradation10abiodisintegration and composting10acomposites10aethylene-propylene copolymers10aphoto-degradation1 aKumar, Pratheep1 aPandey, Jitendra, K.1 aKumar, Bijendra1 aSingh, R., P.  uhttps://library.ncl.res.in/content/photo-bio-degradability-agro-waste-and-ethylene-propylene-copolymers-composites-under-0