01891nas a2200229   4500008004100000022001400041245014400055210006900199260007300268300001200341490000800353520100000361653002501361653002801386653002501414653001301439653001701452100002001469700002401489700001801513856013001531       2008                        eng d  a1387-181100aNew microporous MOF material based on Zn(II)-polycarboxylate coordination polymer synthesized with the aid of 1,6-diaminohexane as template0 aNew microporous MOF material based on ZnIIpolycarboxylate coordi  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcDEC  a204-2090 v1163 a<p>A new microporous metal-organic framework (MOF) material ZBTEC-1 has been synthesized by designing infinite coordination polymer network formed between Zn(II) and 1,2,4,5-benzenetetracarboxylic acid (BTEC) under solvothermal conditions in the presence of 1,6-diaminohexane (DAH) as a single molecule template. Powder XRD data demonstrate that the ZBTEC-1 material has a new MOF structure. N-2 sorption studies indicated moderately good surface area (306 m(2) g(-1)) with large size micropores (average pore diameter ca. 0.7 nm) and very high pore volume (1.93 ccg(-1)). C-13 solid state MAS-NMR, FT-IR and UV-visible spectroscopic studies showed the presence of BTEC moieties in the framework. TEM and FE-SEM analysis indicated 30-60 nm diameter size microporous spherical particles for the ZBTEC-1 crystallites. This novel MOF material showed good hydrogen adsorption capacity at 77 K, indicating its potential application in hydrogen storage. (C) 2008 Elsevier Inc. All rights reserved.</p>10aCoordination polymer10aMetal-organic framework10aMicroporous material10aporosity10aZinc complex1 aChandra, Debraj1 aKasture, Mahesh, W.1 aBhaumik, Asim  uhttps://library.ncl.res.in/content/new-microporous-mof-material-based-znii-polycarboxylate-coordination-polymer-synthesized-001886nas a2200229   4500008004100000245013800041210006900179260000800248300001200256490000800268520105100276653002801327653002801355653002501383653002701408653002201435100001601457700001901473700001701492700001501509856013201524       2017                        eng d00aSyntheses and single crystal X-ray diffraction studies of hydroxynicotinic acid based complexes involving supramolecular interactions0 aSyntheses and single crystal Xray diffraction studies of hydroxy  cSEP  a222-2300 v1333 aAqua-bridged coordination polymers of Cu(II) and Cd(II) and a mononuclear complex of Cu(II) were solvothermally synthesized with hydroxy-decorated ligands such as 2-hydroxynicotinic acid (2-OHNAH) and 6-hydroxynicotinic acid (6-OHNAH) in aqueous-nonaqueous mixed media. All these complexes were characterized by elemental analyses (C, H, N), FT-IR, thermogravimetric analysis (TGA), powder XRD and single crystal X-ray crystallography. They are formulated as [Cu(2-OHNA)2] 1, [Cu(6-OHNA)2(μ-H2O)2]n 2 and [Cd(6-OHNA)2(μ-H2O)2]n 3. Complex 1 is mononuclear 0D square planar complex which extends its dimensionality by weak supramolecular interactions such as π–π stacking interactions and intermolecular hydrogen bonding. Complexes 2 and 3 are polymeric aqua-bridged 1D infinite chain of Cu(II) and Cd(II), respectively. The central metal ions in these two complexes are in octahedral coordination environment. These two complexes are also assembled by π–π stacking interactions, inter- and intramolecular hydrogen bonding interactions. 10a2-Hydroxynicotinic Acid10a6-Hydroxynicotinic Acid10aCoordination polymer10aPolymeric Aqua-Bridged10aX-ray diffraction1 aSingh, S.K.1 aSrivastava, K.1 aBanerjee, R.1 aPrasad, J.  uhttps://library.ncl.res.in/content/syntheses-and-single-crystal-x-ray-diffraction-studies-hydroxynicotinic-acid-based-complexes01462nas a2200193   4500008004100000022001400041245007300055210006900128260000800197490000700205520082600212653002501038653002101063653002201084653002101106653002101127100001701148856010301165       2022                        eng d  a1040-727800aPolyoxometalate clusters: inorganic ligands for functional materials0 aPolyoxometalate clusters inorganic ligands for functional materi  cSEP0 v333 a<p>
	Research in polyoxometalates (POMs) is a diverse growing field with variations in application. POMs are consisting of metal ion and oxide. Peripheral oxides of POM can share spare electron pairs to behave as ligands. This property of POM was utilized for constructing coordination polymers (CPs), synthesizing transitional metal substituted POM for catalysis, synthesizing and stabilizing nano-particles, etc. POM connected structures have provided an opportunity of heterogenization of some homogeneous POM catalyst. Furthermore, diamagnetic POM ligands have been suitable for stabilizing and isolating magnetic ions inside clusters. The scope of this review is to summarize the role of POMs as ligands to prepare POM based CPs, synthesize and stabilize metal nano-particles and isolate magnetic ion or unit.</p>
10aCoordination polymer10aInorganic ligand10amaterials science10apolyoxometalates10asynthesis design1 aDey, Chandan  uhttps://library.ncl.res.in/content/polyoxometalate-clusters-inorganic-ligands-functional-materials