01655nas a2200241   4500008004100000022001400041245017300055210006900228260011000297300001400407490000700421520067900428653002701107653001601134653002301150653001301173653001701186100001801203700002501221700001701246700001901263856013101282       2009                        eng d  a0376-471000aSelective binding of benzoquinone with a Pt-II-cyclophane constructed on the skeleton of N,N `-bis(salicylidene)-p-phenylenediamine: synthesis and spectroscopic studies0 aSelective binding of benzoquinone with a PtIIcyclophane construc  aDR K S KRISHNAN MARG, PUSA CAMPUS, NEW DELHI 110 012, INDIAbNATL INST SCIENCE COMMUNICATION-NISCAIRcDEC  a1644-16510 v483 a<p>The Schiff base NN'-bis(salicylidene)-p-phenylenediamine has been complexed with Pt(en)Cl-2 and the resulting Pt-II-cyclophane, [Pt(en)L](2)center dot 4PF(6), reacted with phenol, resorcinol, hydroquinone or benzoquinone in DMSO solution. Their binding has been monitored by the variation in the corresponding UV-visible and emission spectral patterns. The binding properties are compared with the earlier reported Zn-II-cyclophane [Zn(bpy)L](2) (bpy = 2,2'-bipyridine). A few solid adducts of phenol and benzoquinone with the Pt-II-cyclophane complex and hydroquinone as well as that of resorcinol with the Zn-cyclophane have also been synthesized and characterized.</p>10aCoordination chemistry10aCyclophanes10aMetallocyclophanes10aplatinum10aSchiff bases1 aKumari, Niraj1 aPrajapati, Rishikesh1 aDixit, Mudit1 aMishra, Lallan  uhttps://library.ncl.res.in/content/selective-binding-benzoquinone-pt-ii-cyclophane-constructed-skeleton-nn-bissalicylidene-p-001535nas a2200205   4500008004100000022001400041245009900055210006900154260007500223300001200298490000700310520074200317653002801059653002701087653002801114653001901142100001701161700002001178856013101198       2014                        eng d  a0369-820300aHigh charge carrier mobility in two dimensional indium (iii) isophthalic acid based frameworks0 aHigh charge carrier mobility in two dimensional indium iii isoph  a5 LAJPATRAI RD, ALLAHABAD 211002, INDIAbNATL ACAD SCIENCES INDIAcJUN  a331-3360 v843 a<p>The effect of dimensionality (1D to 2D) on charge carrier mobility have been studied thoroughly on three In(III)-isophthalate based MOFs [In-IA-1D, In-IA-2D-1 and -2]. In-IA-1D possess 1D nanotubular architecture with [(CH3)(2)NH2](+). In-IA-2D-1 have 2D layers containing only [(CH3)(2)NH2](+) cations. Whereas, In-IA-2D-2 have [(CH3)(2)NH2](+) cations as well as solvent DMF molecule inside the crystal structure. Due to presence of the pi-pi stacking arrangement among the phenyl rings of IA moieties facilitates the high charge carrier mobility (4.6 x 10(-3) cm(2) V-1 s(-1) at V-G = -40 V) in In-IA-2D-2. However, In-IA-1D and In-IA-2D-1 does not show any charge carrier mobility due to absence of pi-pi stacking arrangement.</p>10aCharge carrier mobility10aCoordination chemistry10ametal organic framework10api-pi stacking1 aPanda, Tamas1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/high-charge-carrier-mobility-two-dimensional-indium-iii-isophthalic-acid-based-frameworks-002646nas a2200289   4500008004100000022001400041245012500055210006900180260000800249300001600257490000700273520167000280653001201950653002501962653001401987653002702001653002102028653001902049100002202068700002602090700002202116700001802138700002902156700002402185700001902209856012802228       2021                        eng d  a2155-543500aSupported MoOx and WOx solid acids for biomass valorization: interplay of coordination chemistry, acidity, and catalysis0 aSupported MoOx and WOx solid acids for biomass valorization inte  cNOV  a13603-136480 v113 aSupported molybdenum oxide (MoOx) and tungsten oxide (WOx) materials are a vital class of solid acid catalysts for the chemical industry because of their nontoxic nature, strong acidity, remarkable stability in water, hydrogen, and oxygen atmospheres, and excellent reusability performance. These fascinating solid acids play a pivotal role in developing sustainable catalytic routes for renewable biomass processing to produce value-added fuels, chemicals, and platform molecules. The coordination chemistry of MoOx and WOx on the support materials (oxides, carbons, or zeolites) controls their acidic strength, active site accessibility, and catalytic activity. Hence, significant efforts have been made toward optimizing the conditions used for catalyst synthesis and biomass processing to tune the coordination chemistry of MoOx and WOx with the substrate molecules and, thus, their acid-activity/selectivity performance. This Review provides a comprehensive overview of supported MoOx and WOx solid acids for biomass valorization. The importance of the biomass and the role of solid acids for biomass valorization were emphasized, followed by a brief discussion of supported MoOx and WO(x )solid acids. Afterward, the interplay of coordination chemistry, acidic strength, and catalytic activity of supported MoOx and WOx solid acids was discussed. Finally, their catalytic applications for the valorization of several biomass substrates and their derivatives were summarized. This Review will provide valuable insights for developing advanced supported WOx and MoOx solid acids for catalytic biomass valorization and other challenging acid-catalyzed processes.10aAcidity10abiomass valorization10acatalysis10aCoordination chemistry10amolybdenum oxide10atungsten oxide1 aSudarsanam, Putla1 aGupta, Navneet, Kumar1 aMallesham, Baithy1 aSingh, Nittan1 aKalbande, Pavan, Narayan1 aReddy, Benjaram, M.1 aSels, Bert, F.  uhttps://library.ncl.res.in/content/supported-moox-and-wox-solid-acids-biomass-valorization-interplay-coordination-chemistry