01458nas a2200217   4500008004100000022001400041245013200055210006900187260007500256300001400331490000600345520063000351653001200981653002000993653002101013653001801034653001201052100002201064700002401086856013001110       2015                        eng d  a1867-388000aHighly regioselective isomerizing hydroformylation of long-chain internal olefins catalyzed by a rhodium bis(phosphite) complex0 aHighly regioselective isomerizing hydroformylation of longchain   aPOSTFACH 101161, 69451 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcNOV  a3468-34710 v73 a<p>The single-step synthesis, coordination behavior, and application of a bis(phosphite) ligand in the isomerizing hydroformylation of internal olefins was investigated. Interestingly, high-pressure NMR spectroscopy investigations revealed unexpected inequivalency of the two phosphorus nuclei, which display bisequatorial coordination of the bis(phosphite) ligand in a trigonal bipyramidal rhodium complex. Upon employment in the isomerizing hydroformylation of the exceedingly challenging plant oil derived substrate methyl oleate, the bis(phosphite) rhodium complex revealed an unprecedented linear selectivity of 75%.</p>10aalkenes10abis(phosphite)s10aHydroformylation10aisomerization10aRhodium1 aPandey, Swechchha1 aChikkali, Samir, H.  uhttps://library.ncl.res.in/content/highly-regioselective-isomerizing-hydroformylation-long-chain-internal-olefins-catalyzed-0