01486nas a2200205   4500008004100000022001400041245012700055210006900182260007100251300001400322490000700336520067700343100002201020700001901042700001601061700002301077700002901100700002101129856013001150       2009                        eng d  a0021-956800aPhase behavior of hydrogenation of 2-tert-butylphenol over a charcoal-supported rhodium catalyst in carbon dioxide solvent0 aPhase behavior of hydrogenation of 2tertbutylphenol over a charc  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcMAY  a1610-16120 v543 a<p>Catalytic hydrogenation of 2-tert-butyl phenol over a charcoal-supported rhodium catalyst in carbon dioxide solvent at 313 K was studied in a batch reactor. To elucidate the effect of carbon dioxide pressure on the initial rate of reaction, the phase behavior of the ternary (2-tert-butylphenol-carbon dioxide-hydrogen) system was separately observed with a view cell, and the calculations of vapor-liquid equilibrium and compositions in the vapor and liquid phases inside the reactor were carried out using the Peng-Robinson equation of state. The hydrogenation behavior in the carbon dioxide solvent is discussed based on the phase behavior of the ternary system.</p>1 aHiyoshi, Norihito1 aMasuda, Yoshio1 aSato, Osamu1 aYamaguchi, Aritomo1 aRode, Chandrashekhar, V.1 aShirai, Masayuki  uhttps://library.ncl.res.in/content/phase-behavior-hydrogenation-2-tert-butylphenol-over-charcoal-supported-rhodium-catalyst-0