01618nas a2200193   4500008004100000022001400041245017500055210006900230260008000299300001400379490000700393520078000400100001901180700002101199700001901220700002501239700003301264856012701297       2007                        eng d  a0022-372700aFinite size effects on the electrical properties of sol-gel synthesized CoFe2O4 powders: deviation from Maxwell-Wagner theory and evidence of surface polarization effects0 aFinite size effects on the electrical properties of solgel synth  aDIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLANDbIOP PUBLISHING LTDcMAR  a1593-16020 v403 a<p>Fine particles of cobalt ferrite were synthesized by the sol-gel method. Subsequent heat treatment at different temperatures yielded cobalt ferrites having different grain sizes. X-ray diffraction studies were carried out to elucidate the structure of all the samples. Dielectric permittivity and ac conductivity of all the samples were evaluated as a function of frequency, temperature and grain size. The variation of permittivity and ac conductivity with frequency reveals that the dispersion is due to Maxwell-Wagner type interfacial polarization in general, with a noted variation from the expected behaviour for the cold synthesized samples. High permittivity and conductivity for small grains were explained on the basis of the correlated barrier-hopping model.</p>1 aGeorge, Mathew1 aNair, Swapna, S.1 aMalini, K., A.1 aJoy, Pattayil, Alias1 aAnantharaman, Maliemadom, R.  uhttps://library.ncl.res.in/content/finite-size-effects-electrical-properties-sol-gel-synthesized-cofe2o4-powders-deviation02159nas a2200229   4500008004100000022001400041245013600055210006900191260007300260300001400333490000800347520126000355653002701615100001901642700002101661700001901682700002501701700001801726700002201744700003301766856013001799       2009                        eng d  a0304-885300aImpact of zinc substitution on the structural and magnetic properties of chemically derived nanosized manganese zinc mixed ferrites0 aImpact of zinc substitution on the structural and magnetic prope  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcAPR  a1092-10990 v3213 a<p>Mn(1-x)Zn(x)Fe(2)O(4) nanoparticles (x = 0-1) were synthesized by wet chemical co-precipitation techniques. X-ray diffraction, transmission electron microscopy and high-resolution transmission electron microscopy were effectively utilized to investigate the different structural parameters. The elemental analysis was conducted using energy-dispersive spectrum and inductively coupled plasma analysis. The magnetic properties such as magnetization and coercivity were measured using vibrating sample magnetometer. The observed magnetization values of the nanoparticles were found to be lower compared to the bulk counterpart. The magnetization showed a gradual decrease with zinc substitution except for a small increase from x = 0.2 to 0.3. The Curie temperature was found to be enhanced in the case of ferrites in the nanoregime. The variation in lattice constant, reduced magnetization values, variation of magnetization with zinc substitution, the presence of a net magnetic moment for the zinc ferrite and the enhancement in Curie temperature in Mn(1-x)Zn(x)Fe(2)O(4) all provide evidence to the existence of a metastable cation distribution together with possible surface effects at the nanoregime. (C) 2008 Elsevier B.V. All rights reserved.</p>10aManganese zinc ferrite1 aGopalan, Veena1 aAl-Omari, I., A.1 aMalini, K., A.1 aJoy, Pattayil, Alias1 aKumar, Sakthi1 aYoshida, Yasuhiko1 aAnantharaman, Maliemadom, R.  uhttps://library.ncl.res.in/content/impact-zinc-substitution-structural-and-magnetic-properties-chemically-derived-nanosized-002649nas a2200301   4500008004100000022001400041245008800055210006900143260005700212300001200269490000600281520155900287653002501846653003301871653004201904653003801946653004001984100001902024700001902043700002202062700002202084700002502106700002102131700001802152700002202170700003302192856012202225       2010                        eng d  a1556-276X00aTemplate-assisted synthesis and characterization of passivated nickel nanoparticles0 aTemplateassisted synthesis and characterization of passivated ni  a233 SPRING ST, NEW YORK, NY 10013 USAbSPRINGERcMAY  a889-8970 v53 a<p>Potential applications of nickel nanoparticles demand the synthesis of self-protected nickel nanoparticles by different synthesis techniques. A novel and simple technique for the synthesis of self-protected nickel nanoparticles is realized by the inter-matrix synthesis of nickel nanoparticles by cation exchange reduction in two types of resins. Two different polymer templates namely strongly acidic cation exchange resins and weakly acidic cation exchange resins provided with cation exchange sites which can anchor metal cations by the ion exchange process are used. The nickel ions which are held at the cation exchange sites by ion fixation can be subsequently reduced to metal nanoparticles by using sodium borohydride as the reducing agent. The composites are cycled repeating the loading reduction cycle involved in the synthesis procedure. X-Ray Diffraction, Scanning Electron Microscopy, Transmission Electron microscopy, Energy Dispersive Spectrum, and Inductively Coupled Plasma Analysis are effectively utilized to investigate the different structural characteristics of the nanocomposites. The hysteresis loop parameters namely saturation magnetization and coercivity are measured using Vibrating Sample Magnetometer. The thermomagnetization study is also conducted to evaluate the Curie temperature values of the composites. The effect of cycling on the structural and magnetic characteristics of the two composites are dealt in detail. A comparison between the different characteristics of the two nanocomposites is also provided.</p>10aNickel nanoparticles10aPolymer-metal nanocomposites10aStrongly acidic cation exchange resin10aStuctural and magnetic properties10aWeakly acidic cation exchange resin1 aGopalan, Veena1 aMalini, K., A.1 aSanthoshkumar, G.1 aNarayanan, T., N.1 aJoy, Pattayil, Alias1 aAl-Omari, I., A.1 aKumar, Sakthi1 aYoshida, Yasuhiko1 aAnantharaman, Maliemadom, R.  uhttps://library.ncl.res.in/content/template-assisted-synthesis-and-characterization-passivated-nickel-nanoparticles-0