01261nas a2200181   4500008004100000022001400041245009600055210006900151260011000220300001600330490000700346520051300353100002000866700002600886700001500912700002900927856012300956       2011                        eng d  a1477-922600aChlorate ion mediated rutile to anatase reverse phase transformation in the TiO2 nanosystem0 aChlorate ion mediated rutile to anatase reverse phase transforma  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcSEP  a11374-113770 v403 a<p>Rutile TiO2 nanoneedles (8 nm x 100 nm) synthesized at room temperature by anodization in perchloric acid (pH &lt; 1) are shown to undergo an interesting reverse phase transformation to anatase nanoparticles (8 nm) at 300 degrees C only if the chlorate ions are maintained in the ambient medium. When chlorate ions are removed by multiple washing, the rutile phase and the needle morphology are maintained. The mechanism of formation of the ion-stabilized solid and its thermal evolution is discussed.</p>1 aBhosale, Reshma1 aHyam, Rajeshkumar, S.1 aDhanya, P.1 aOgale, Satishchandra, B.  uhttps://library.ncl.res.in/content/chlorate-ion-mediated-rutile-anatase-reverse-phase-transformation-tio2-nanosystem-0