01631nas a2200229   4500008004100000022001400041245010700055210006900162260007300231300001200304490000800316520077600324653002701100653002101127653002301148653001301171653001201184100002601196700002201222700002901244856012801273       2005                        eng d  a1381-116900aHydroformylation of 1-hexene using Rh/TPPTS complex exchanged on anion exchange resin: kinetic studies0 aHydroformylation of 1hexene using RhTPPTS complex exchanged on a  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcMAY  a179-1860 v2323 a<p>The exchange of the Rh/Triphenylphosphine trisulfonate sodium [TPPTS] complex on to an anion exchange resin results in a stable heterogenized catalyst for the hydroformylation of alkenes. The kinetics of hydroformylation of 1-hexene using Rh/TPPTS complex exchanged on anion exchange resin to Amberlite IRA-93 has been investigated for the first time. The rate of the reaction was found to be dependent on the partial pressure of hydrogen and 1-hexene concentrations with a first order. A maximum in the rate with increasing partial pressure of carbon monoxide was observed. A rate model has been proposed which predicts the observed rate data within reasonable error. The activation energy was found to be 84.37 kJ/mol. (c) 2005 Elsevier B.V. All rights reserved.</p>10aheterogenized catalyst10aHydroformylation10aion-exchange resin10akinetics10aRhodium1 aDiwakar, Makarand, M.1 aDeshpande, R., M.1 aChaudhari, Raghunath, V.  uhttps://library.ncl.res.in/content/hydroformylation-1-hexene-using-rhtppts-complex-exchanged-anion-exchange-resin-kinetic-1