01197nas a2200193   4500008004100000022001400041245011300055210006900168260011000237300001200347490000600359520041800365100001900783700001700802700001800819700001800837700001800855856013000873       2016                        eng d  a2044-475300aPhenylacetylene hydrogenation on Au@Ni bimetallic core-shell nanoparticles synthesized under mild conditions0 aPhenylacetylene hydrogenation on AuNi bimetallic coreshell nanop  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcJAN  a708-7120 v63 a<p>The synthesis of Au@Ni bimetallic core-shell nanoparticles through an energy efficient (lower temperature) route in oleylamine following a sequential reduction strategy is reported. The method is found to be useful for the synthesis of a very thin nickel shell (2 nm) over a gold core (15 nm). Synergistic effects are observed in catalyzing phenylacetylene hydrogenation under different solvent conditions.</p>1 aVysakh, A., B.1 aLazar, Anish1 aYadukiran, V.1 aSingh, A., P.1 aVinod, C., P.  uhttps://library.ncl.res.in/content/phenylacetylene-hydrogenation-auni-bimetallic-core-shell-nanoparticles-synthesized-under-001658nas a2200241   4500008004100000022001400041245013300055210006900188260000800257300001200265490000600277520079500283653002901078653001901107653002801126653002401154100002601178700001801204700001701222700002201239700002801261856012701289       2016                        eng d  a2365-654900aSynthesis of Au@Ni bimetallic core shell nanoparticle and nanochains in soyabean oil and their catalytic hydrogenation reactions0 aSynthesis of AuNi bimetallic core shell nanoparticle and nanocha  cFEB  a140-1460 v13 a<p>Synthesis of Au@Ni bimetallic core shell nanostructures using commercially available soya bean oil as the solvent through a sequential reduction strategy is reported. The energy efficiency and economic viability comes from the much milder temperatures and replacement of expensive and environmentally hazardous solvents like long chain organic amines and acids previously reported for synthesis. Thus, core shell nanoparticles having size regime of 10-15 nm with an excellent control over the nickel shell thickness (2 nm) over the gold core (8-10 nm) and Au@Ni nanochains is achieved. The synthesized materials are demonstrated to synergistically catalyze hydrogenation of nitro and C-C multiple bonds with much better efficiency as compared to individual nanoparticle counterparts.</p>10aBimetallic nanoparticles10aGold catalysis10ahydrogenation reactions10asynergistic effects1 aBharathan, Vysakh, A.1 aYadukiran, V.1 aLazar, Anish1 aSingh, Anand., P.1 aVinod, Chathakudath, P.  uhttps://library.ncl.res.in/content/synthesis-auni-bimetallic-core-shell-nanoparticle-and-nanochains-soyabean-oil-and-their