01574nas a2200193   4500008004100000022001400041245012400055210006900179260011000248300001400358490000700372520077000379100002201149700002001171700002101191700002001212700001801232856013001250       2012                        eng d  a1477-922600aNitrogen-rich porous covalent imine network (CIN) material as an efficient catalytic support for C-C coupling reactions0 aNitrogenrich porous covalent imine network CIN material as an ef  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcDEC  a1304-13110 v413 a<p>In an effort to expand the realm of possibilities of nitrogen-rich porous materials that could be used in catalysis, herein we report the synthesis of a new highly nitrogen rich (ca. 45%) porous covalent imine network (CIN-1) material employing simple Schiff base chemistry and further grafting its surface with palladium. Pd-loaded CIN-1 support acts as a truly heterogeneous catalyst towards Suzuki C-C coupling reaction between aryl halides with arylboronic acids. High surface area and excellent accessibility of the catalytic sites make it very efficient for heterogeneous catalysis. The stability of the catalyst due to intimate contact between nitrogen-rich organic support and metal allows several reuses with only a minor loss in catalytic activity.</p>1 aBhunia, Manas, K.1 aDas, Swapan, K.1 aPachfule, Pradip1 aBanerjee, Rahul1 aBhaumik, Asim  uhttps://library.ncl.res.in/content/nitrogen-rich-porous-covalent-imine-network-cin-material-efficient-catalytic-support-c-c-0