01906nas a2200217   4500008004100000022001400041245009600055210006900151260007700220300001400297490000700311520110900318653002001427653001801447653001201465653002901477653002001506100001901526700001601545856012701561       2015                        eng d  a1439-423500aSynergistic effects and correlating polarity parameters in binary mixtures of ionic liquids0 aSynergistic effects and correlating polarity parameters in binar  aBOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcAPR  a1026-10340 v163 a<p>Understanding how a chemical reaction proceeds in solution requires precise knowledge of solute-solvent interactions. Certain issues involved in ionic liquid binary mixtures are still not clearly understood, including: 1) the effects of hydrogen-bond-acceptor basicity () of solvents on the synergistic effects found in ionic liquid-alcohol mixtures, 2) the interrelation between the polarity parameters in binary mixtures, and 3) the application of a model for the description of normalised electronic transition energy for all the binary mixtures. Here, a detailed analysis of polarity parameters in both hydrophilic and hydrophobic ionic liquids has been carried out. A three-parameter model developed by Roses et al. [J. Chem. Soc. Perkin Trans. 2 1997, 13411348] was found to be applicable to all the binary mixtures, and synergistic effects are generated as a result of high values of alcohols compared with those of the ionic liquids. A strong correlation was observed in the values and hydrophobicities of pure ionic liquids, suggesting that values can play a role in describing synergism.</p>10agreen chemistry10aionic liquids10aliquids10anoncovalent interactions10asolvent effects1 aBeniwal, Vijay1 aKumar, Anil  uhttps://library.ncl.res.in/content/synergistic-effects-and-correlating-polarity-parameters-binary-mixtures-ionic-liquids-1