02238nas a2200253   4500008004100000022001400041245012400055210006900179260010600248300001200354490000700366520128200373653002701655653001701682653001701699653001901716653001901735653002201754100002101776700002301797700001901820700001901839856012601858       2013                        eng d  a0360-544200aHBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane0 aHBGS hydrate based gas separation process for carbon dioxide cap  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDbPERGAMON-ELSEVIER SCIENCE LTDcDEC  a252-2590 v633 a<p>The effect of CP (cyclopentane) as a promoter/additive, in the HBGS (hydrate based gas separation) process for pre-combustion gas mixture was investigated by employing an unstirred reactor configuration. Gas uptake measurements were performed at two different temperatures (275.7 K and 285.7 K) and at an experimental pressure of 6.0 MPa to determine the kinetics of hydrate formation. Experiments were conducted with three different volumes (7.5, 15 and 22 ml) of CP and based on induction time and the rate of hydrate growth, 15 ml of CP was determined to be the optimal volume for carbon dioxide capture at 6.0 MPa and 275.7 K. In addition, the effect of a kinetic promoter, SDS (sodium dodecyl sulfate), was investigated. Surprisingly, no improvement in kinetic performance was observed at 6.0 MPa and 275.7 K in the presence of SDS and CP. From the study, it was found that at the optimal 15 ml CP (CP layer thickness of 1.8 mm), the average composition of carbon dioxide in the hydrate phase was 90.36 mol% with a separation factor of 17.82. Furthermore, the unstirred reactor also yielded better kinetic performance over the stirred tank reactor with the unstirred reactor having a 2.28 times higher average gas uptake. (C) 2013 Elsevier Ltd. All rights reserved.</p>10aCarbon dioxide capture10aCyclopentane10aGas hydrates10aGas separation10aPre-combustion10aUnstirred reactor1 aHo, Leong, Chuan1 aBabu, Ponnivalavan1 aKumar, Rajnish1 aLinga, Praveen  uhttps://library.ncl.res.in/content/hbgs-hydrate-based-gas-separation-process-carbon-dioxide-capture-employing-unstirred-0