02026nas a2200265   4500008004100000022001400041245012700055210006900182260009900251300001200350490000800362520101400370653003301384653001901417653001301436653002301449653002801472653002301500100002201523700001701545700002201562700002401584700002901608856012301637       2014                        eng d  a0143-720800aSynthesis, structure, spectral, electrochemical and sensing properties of 3-amino boron-dipyrromethene and its derivatives0 aSynthesis structure spectral electrochemical and sensing propert  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLANDbELSEVIER SCI LTDcMAR  a218-2270 v1023 a<p>We report the synthesis of 3-amino boron-dipyrromethene (3-amino BODIPY) by treating 3-bromo boron-dipyrromethene (3-bromo BODIPY) initially with sodium azide in acetonitrile followed by tri-phenylphosphine(PPh3)/H2O in tetrahydrofuran in three steps under mild reaction conditions. In this reaction, 3-azido BODIPY which formed in the first step was not isolated but the 3-iminophosphorane BODIPY which formed in the second step was isolated and characterized crystallographically. The 3-amino BODIPY was characterized by various spectroscopic and X-ray analytical techniques. To test the reactivity of amine functionality on BODIPY core, we prepared 1-(meso-anisyl BODIPY)-3-phenyl urea/thiourea derivatives under simple reaction conditions. Our studies indicated that 1-(meso-anisyl BODIPY)-3-pheny thiourea can act as specific chemodosimetric sensor for Hg2+ ion and 1-(meso-anisyl BODIPY)-3-phenyl urea as colorimetric and ratiometric sensor for F- ion. (C) 2013 Elsevier Ltd. All rights reserved.</p>10a3-Amino boron dipyrromethene10aChemodosimeter10aF sensor10aFluorescent probes10aIminophosphorane BODIPY10aMercury(II) sensor1 aGanapathi, Emandi1 aMadhu, Sheri1 aChatterjee, Tamal1 aGonnade, Rajesh, G.1 aRavikanth, Mangalampalli  uhttps://library.ncl.res.in/content/synthesis-structure-spectral-electrochemical-and-sensing-properties-3-amino-boron-0