03557nas a2200253   4500008004100000022001400041245010900055210006900164260007500233300001400308490000700322520266100329653001702990653001903007653001603026653002503042653002403067653001403091653001203105653001803117100002603135700002203161856012003183       2009                        eng d  a1022-552800aSupported nano-gold catalysts for epoxidation of styrene and oxidation of benzyl alcohol to benzaldehyde0 aSupported nanogold catalysts for epoxidation of styrene and oxid  a233 SPRING ST, NEW YORK, NY 10013 USAbSPRINGER/PLENUM PUBLISHERScNOV  a1677-16870 v523 a<p>Nano-gold particles supported on different alkaline earth oxides (viz. MgO, CaO, BaO and SrO), Gr. IIIa metal oxides (viz. Al(2)O(3), Ga(2)O(3), In(2)O(3) and Tl(2)O(3)), transition metal oxides (viz. TiO(2), Cr(2)O(3), MnO(2), Fe(2)O(3), CoO(x), NiO, CuO, ZnO, Y(2)O(3) and ZrO(2)), rare earth metal oxides (viz. La(2)O(3), Ce(2)O(3), Nd(2)O(3), Sm(2)O(3), Eu(2)O(3), Tb(2)O(3), Er(2)O(3) and Yb(2)O(3)) and U(3)O(8) [all prepared by depositing gold on corresponding metal oxide support by deposition precipitation (DP) and/or homogeneous deposition precipitation (HDP) method] were evaluated for their catalytic performance in the liquid phase epoxidation of styrene by tert-butyl hydroperoxide (TBHP) to styrene oxide and also in the solvent-free benzyl alcohol-to-benzaldehyde oxidation (by molecular oxygen or TBHP) reactions. For the epoxidation, the catalytic performance (styrene oxide yield) of the most promising nano-gold catalysts prepared by the HDP method was in the following order: Au/MgO &gt; Au/Tl(2)O(3) &gt; Au/Yb(2)O(3) &gt; Au/Tb(2)O(3) &gt; Au/CaO (or TiO(2)). However, for the oxidation of benzyl alcohol to benzaldehyde by molecular oxygen, the order of choice for the most promising catalysts (based on benzaldehyde yield) was Au/U(3)O(8) &gt; Au/Al(2)O(3) &gt; Au/ZrO(2) &gt; Au/MgO. Whereas, when TBHP was used as an oxidizing agent for the benzyl alcohol oxidation, the order of choice for the most promising catalysts was Au/U(3)O(8) &gt; Au/MgO &gt; Au/TiO(2) &gt; Au/ZrO(2) &gt; Au/Al(2)O(3). The catalytic performance of a particular supported nano-gold catalyst was thus found to depend on the reaction catalysed by them. Moreover, it is strongly influenced by a number of catalyst parameters, such as the metal oxide support, the method of gold depositon on the support, the gold loading and also on the catalyst calcination temperature. Nano-gold particles-support interactions seem to play an important role in controlling the deposition of gold ( amount of gold deposited and size and morphology of gold particles), formation of different surface gold species (Au(0), Au(1+) and Au(3+)) and electronic properties of gold particles and, consequently, control the catalytic performance (both the activity and selectivity) of the supported nano-gold catalysts in the reactions. The nano-gold catalysts prepared by the HDP method showed much better catalytic performance than those prepared by the DP, coprecipitation or impregnation method; in general, the HDP method provided supported gold catalysts with much higher gold loading and/or smaller size gold particles than that achieved by the DP and other methods.</p>10aBenzaldehyde10aBenzyl alcohol10aepoxidation10aMetal oxide supports10aNano-gold catalysts10aOxidation10astyrene10aStyrene oxide1 aChoudhary, Vasant, R.1 aDumbre, Deepa, K.  uhttps://library.ncl.res.in/content/supported-nano-gold-catalysts-epoxidation-styrene-and-oxidation-benzyl-alcohol-0