01611nas a2200229   4500008004100000022001400041245010300055210006900158260007300227300001000300490000700310520078700317653001801104653001801122653001201140653001101152653002801163100002001191700002101211700002801232856012101260       2008                        eng d  a1566-736700a[Ru(salen)(NO)] complex encapsulated in mesoporous SBA-16 as catalyst for hydrogenation of ketones0 aRusalenNO complex encapsulated in mesoporous SBA16 as catalyst f  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcOCT  a45-480 v103 a<p>SBA-16 mesoporous silica with cubic lm3m structure was synthesized using Pluronic F127 poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer (EO106PO70EO106) and it blends with Pluronic P123 triblock copolymer (EO20PO70EO20) as supramolecular templates. The resulting material was used for encapsulating [Ru(salen)(NO)] complex and used in the hydrogenation of ketones to the corresponding alcohols. The pore entrance size of SBA-16 was precisely tailored by silylation with diphenyldichlorosilane to trap [Ru(salen)(NO)] complex in the cage of SBA-16. Small angle XRD, N-2 sorption measurements, UV-Vis and FT-IR analysis evidences the structural integrity of mesoporous silica as well as the complex. (C) 2008 Elsevier B.V. All rights reserved.</p>10aEncapsulation10aHydrogenation10aKetones10aSBA-1610a[Ru(salen)(NO)] complex1 aBordoloi, Ankur1 aAmrute, Amol, P.1 aHalligudi, Shivaraj, B.  uhttps://library.ncl.res.in/content/rusalenno-complex-encapsulated-mesoporous-sba-16-catalyst-hydrogenation-ketones-002046nas a2200289   4500008004100000022001400041245010700055210006900162260009500231300001200326490000800338520104400346653001301390653001201403653001801415653002201433653001101455100001701466700001801483700001601501700002001517700002201537700001901559700002801578700002001606856013001626       2016                        eng d  a0021-951700aStudies of synergy between metal-support interfaces and selective hydrogenation of HMF to DMF in water0 aStudies of synergy between metalsupport interfaces and selective  a525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USAbACADEMIC PRESS INC ELSEVIER SCIENCEcAUG  a248-2600 v3403 a<p>Metal-support interfaces play a very important role in heterogeneous catalysis. The interfacial interactions not only are responsible for stabilizing the necessary oxidation state to facilitate the reaction but also enhance the stability of the catalyst system. Nano dispersion of Ni on mesoporous nitrogen-rich carbon material has been achieved using two different synthesis methods. It was observed that nickel (0) gets stabilized by strong interfacial interaction with the nitrogen atoms of the support material, and the material was found to be very economic and efficient for the conversion of HMF to DMF in aqueous medium. The material shows &gt;= 99% conversion to 5-(hydroxymethyl) furfural (HMF) within 6 h of reaction with 98.7% DMF selectivity. A unique correlation between synthesis methods and particle sizes with catalytic performance has been observed for these newly developed materials. Furthermore, a DFT calculation has been performed to predict the reaction mechanism. (C) 2016 Elsevier Inc. All rights reserved.</p>10abiofuels10aBiomass10aHydrogenation10amesoporous carbon10aNi-CNx1 aGoyal, Reena1 aSarkar, Bipul1 aBag, Arijit1 aSiddiqui, Nazia1 aDumbre, Deepa, K.1 aLucas, Nishita1 aBhargava, Suresh, Kumar1 aBordoloi, Ankur  uhttps://library.ncl.res.in/content/studies-synergy-between-metal-support-interfaces-and-selective-hydrogenation-hmf-dmf-water