01926nas a2200265   4500008004100000022001400041245012800055210006900183260007700252300001600329490000700345520092500352653002001277653003201297653002101329653002401350653001901374100001901393700003101412700002201443700002201465700002401487700002001511856012901531       2014                        eng d  a0947-653900aCovalent organic framework-cadmium sulfide hybrid as a prototype photocatalyst for visible-light-driven hydrogen production0 aCovalent organic frameworkcadmium sulfide hybrid as a prototype   aBOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcNOV  a15961-159650 v203 a<p>CdS nanoparticles were deposited on a highly stable, two-dimensional (2D) covalent organic framework (COF) matrix and the hybrid was tested for photocatalytic hydrogen production. The efficiency of CdS-COF hybrid was investigated by varying the COF content. On the introduction of just 1 wt% of COF, a dramatic tenfold increase in the overall photocatalytic activity of the hybrid was observed. Among the various hybrids synthesized, that with 10 wt% COF, named CdS-COF (90: 10), was found to exhibit a steep H2 production amounting to 3678 mmolh(-1) g(-1), which is significantly higher than that of bulk CdS particles (124 mmolh(-1)g(-1)). The presence of a p-conjugated backbone, high surface area, and occurrence of abundant 2D hetero-interface highlight the usage of COF as an effective support for stabilizing the generated photoelectrons, thereby resulting in an efficient and high photocatalytic activity.</p>10acharge transfer10acovalent organic frameworks10ahybrid materials10ahydrogen production10aPhotocatalysis1 aThote, Jayshri1 aAiyappa, Harshitha, Barike1 aDeshpande, Aparna1 aDiaz, David, Diaz1 aKurungot, Sreekumar1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/covalent-organic-framework-cadmium-sulfide-hybrid-prototype-photocatalyst-visible-light-0