11923nas a2200217 45000080041000002450134000412100069001752600008002443000014002524900007002665201112300273100002311396700002411419700002411443700002511467700001811492700002311510700002111533700002411554856012711578 2025 eng d00aSynthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of silver nitrate with 2-amino-benzoxazole0 aSynthesis crystal structure and Hirshfeld surface analysis of a  cNOV a1182-11850 v813 a

The coordination complex of 2-amino-benzaxole (2AB) with silver(I), namely, bis(2-aminobenzoxazole-κN)silver(I) nitrate-bis(2-aminobenzoxazole (1/2), [Ag(C7H6N2O)2]NO3·2C7H6N2O or [Ag(2AB)2]NO3·(2AB)2, was synthesized from ethanol solutions of AgNO3 and 2AB. The asymmetric unit contains one mol-ecule of [Ag(2AB)2]NO3·(2AB)2, The central silver(I) atom is coordinated by two nitro-gen donor atoms from 2-amino-benzaxazole ligands in an N2 coordination set while another two 2-amino-benzaxazole ligands and one nitrate anion remain uncoordinated. The crystal structure features several intra-molecular N-H⋯O and N-H⋯N hydrogen-bonding inter-actions as well as C-H⋯π, Ag⋯π and π-π inter-actions between adjacent AB ligands. Hirshfeld surface analysis and two-dimensional fingerprint plots were used to investigate the inter-molecular inter-actions.

1 aRazzoqova, Surayyo1 aSadullayeva, Sojida1 aErkinov, Sirojiddin1 aTorambetov, Batirbay1 aAlieva, Guloy1 aYakhshieva, Zukhra1 aAshurov, Jamshid1 aKadirova, Shakhnoza uhttps://library.ncl.res.in/content/synthesis-crystal-structure-and-hirshfeld-surface-analysis-coordination-compound-silver