14697nas a2200205 45000080041000002450135000412100069001762600008002453000012002534900007002655201393900272100002314211700002014234700001914254700002514273700002014298700002114318700002414339856012814363 2025 eng d00aSynthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-amino-benzoxazole0 aSynthesis crystal structure and Hirshfeld surface analysis of a  cJUN a482-4850 v813 a

A coordination complex of cadmium nitrate [Cd(NO3)2] with 2-amino-benzaxole (2AB; C7H6N2O), namely, tetra-kis-(2-amino-benzoxazole-κN 1)bis-(nitrato-κO)cadmium(II), [Cd(NO3)2(2AB)4], has been synthesized from ethanol solutions of Cd(NO3)2·H2O and 2AB. The asymmetric unit comprises half a mol-ecule of [Cd(NO3)2(2AB)4], with the CdII atom positioned on a twofold rotation axis. In the completed mol-ecular complex, four 2AB ligands and two nitrate anions each coordinate monodentately to the CdII atom, leading to a distorted octa-hedral coordination environment. The crystal structure of [Cd(NO3)2(2AB)4] exhibits several N-H⋯O inter-actions, resulting in the formation of a layered assembly parallel to (001). Hishfeld surface analysis was used to qu-antify the inter-molecular inter-actions.

1 aRazzoqova, Surayyo1 aRuzimov, Yodgor1 aToshov, Akobir1 aTorambetov, Batirbay1 aIbragimov, Aziz1 aAshurov, Jamshid1 aKadirova, Shakhnoza uhttps://library.ncl.res.in/content/synthesis-crystal-structure-and-hirshfeld-surface-analysis-coordination-compound-cadmium