01396nas a2200205   4500008004100000022001400041245008900055210006900144260011000213300001400323490000600337520060100343100002000944700001800964700002600982700002301008700001801031700002001049856012101069       2015                        eng d  a2041-652000aSolid state organic amine detection in a photochromic porous metal organic framework0 aSolid state organic amine detection in a photochromic porous met  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcDEC  a1420-14250 v63 a<p>A new Mg(II) based photochromic porous metal-organic framework (MOF) has been synthesized bearing naphthalenediimide (NDI) chromophoric unit. This MOF (Mg-NDI) shows instant and reversible solvatochromic behavior in presence of solvents with different polarity. Mg-NDI also exhibits fast and reversible photochromism via radical formation. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state. The organic amine detection has been confirmed by photoluminescence quenching experiment and visual color change.</p>1 aMallick, Arijit1 aGarai, Bikash1 aAddicoat, Matthew, A.1 aPetkov, Petko, St.1 aHeine, Thomas1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/solid-state-organic-amine-detection-photochromic-porous-metal-organic-framework-0