02361nas a2200289   4500008004100000022001400041245014100055210006900196260000800265300001100273490000800284520134700292653002501639653001401664653002601678653003001704653002701734653002001761653002601781100002201807700002201829700002001851700002101871700002201892700002801914856012901942       2025                        eng d  a1381-514800aMethoxyl-containing hyper-crosslinked polymer from largely bio-based biphenyl methyl ether and its application in lithium-sulfur battery0 aMethoxylcontaining hypercrosslinked polymer from largely biobase  cFEB  a1061390 v2073 a<p>
	A new biphenyl methyl ether viz 2,2 `,3,3 `-tetramethoxy-5,5 `-bis(methoxymethyl)-1,1 `-biphenyl (TBMB) was synthesized starting from vanillin via three-step reaction sequence. The self-polycondensation of TBMB by employing two Bronsted acid catalysts, viz, p- toluenesulfonic acid (PTSA) and trifluoromethanesulfonic acid (TFSA) led to the formation of organic hyper-crosslinked polymers (HCPs) containing built-in methoxyl groups. HCPs were characterized by FTIR, solid state 13 C NMR, XPS, XRD, TGA, BET, and FESEM analysis techniques. HCPs synthesized using PTSA (HCP-PTSA) and TFSA (HCP-TFSA) exhibited a Brunauer-Emmett-Teller (BET) surface area of 480 +/- 5 and 590 +/- 4 m2/g, respectively and consisted of hierarchical pore structures with both micropores and mesopores. HCP-TFSA was evaluated as an active coating layer on conventional polypropylene (PP) separator in lithium-sulfur batteries to suppress the polysulfide shuttling on account of the ability of methoxyl groups to anchor soluble polysulfide species via coordination. The significant polysulfide adsorption capacity and improved cycling stability with a capacity of 617.2 mAh g- 1 at 0.5C and 99% capacity retention highlighted the potential of porous HCP containing built-in methoxyl groups in the development of attractive lithium-sulfur battery systems.</p>
10aActive coating layer10abio-based10aBiphenyl methyl ether10aHyper-crosslinked polymer10alithium-sulfur battery10aMethoxyl groups10aSelf-polycondensation1 aWale, Apparav, K.1 aDas, Anoushka, K.1 aPatil, Nita, R.1 aShelke, Manjusha1 aAmbade, Ashootosh1 aWadgaonkar, Prakash, P.  uhttps://library.ncl.res.in/content/methoxyl-containing-hyper-crosslinked-polymer-largely-bio-based-biphenyl-methyl-ether-and