02439nas a2200229   4500008004100000022001400041245014500055210006900200260000900269300001600278490000700294520156000301100001901861700002901880700001901909700002101928700003201949700003201981700003602013700003102049856012902080       2024                        eng d  a1477-922600aSynergistic effects of the substrate-ligand interaction in metal-organic complexes on the de-electronation kinetics of a vitamin C fuel cell0 aSynergistic effects of the substrateligand interaction in metalo  cAUG   a13384-133930 v533 a<p>
	The rising demand for portable energy conversion devices has spurred the advancement of direct liquid fuel cells (DLFCs) employing fuels such as alcohol, ammonia, hydrazine, and vitamin C. In these devices, various precious metal platforms have been explored to increase the de-electronation kinetics and reduce catalyst poisoning, but with substantial cost implications. We demonstrate the crucial role of ligands in non-precious organometallic complexes in influencing the de-electronation kinetics of fuel molecules through a unique substrate-ligand synergistic interaction. This unique chemistry imparts electron deficiency at the catalytic metal center while simultaneously populating the ligand with an extensive proton charge assembly. This distinct substrate-ligand interaction enhances the DLFC performance by coulombically dragging the substrate with a distinct amplification in its de-electronation kinetics. By integrating this approach with a ferricyanide/ferrocyanide half-cell reaction, a precious metal-free vitamin C fuel cell is developed, which is capable of generating an open circuit voltage of similar to 950 mV, a peak power density of similar to 97 mW cm-2 at a peak current density of similar to 215 mA cm-2 with the performance metrics nearly 1.7 times higher than a precious metal based DLFC. This highlights the potential of the substrate-ligand synergy in the design of efficient molecular catalysts for energy conversion applications. A precious metal-free biomass fuel cell through substrate-ligand interactions.</p>
1 aParmar, Muskan1 aMukhopadhyay, Sanchayita1 aMondal, Ritwik1 aNayak, Bhojkumar1 aDargily, Neethu, Christudas1 aKotresh, Harish, Makri Nimb1 aVinod, Chathakudath, Prabhakara1 aThotiyl, Musthafa, Ottakam  uhttps://library.ncl.res.in/content/synergistic-effects-substrate-ligand-interaction-metal-organic-complexes-de-electronation